scholarly journals Adsorption of CO<sub>2</sub> and H<sub>2</sub> on Cu and Zn Micro-Cluster Surfaces Studied by Quantum Chemistry and Theory of Absolute Reaction Rates

2011 ◽  
Vol 01 (03) ◽  
pp. 109-117 ◽  
Author(s):  
Hiroaki Kuze ◽  
Shin’ichiro Okude
Keyword(s):  
Quantum Chemistry ◽  
Reaction Rates ◽  
Adsorption Of Co ◽  
Absolute Reaction ◽  
Cu And Zn

The Theory of Absolute Reaction Rates and the Polymerization of Ethylene

1939 ◽  
Vol 61 (4) ◽  
pp. 798-800 ◽  
Author(s):  
Francis P. Jahn
Keyword(s):  
Reaction Rates ◽  
Absolute Reaction

Application of the Theory of Absolute Reaction Rates to Overvoltage

1939 ◽  
Vol 7 (11) ◽  
pp. 1053-1065 ◽  
Author(s):  
H. Eyring ◽  
S. Glasstone ◽  
K. J. Laidler
Keyword(s):  
Reaction Rates ◽  
Absolute Reaction

A Quantitative Investigation of the Ozonolysis Reaction. XVIII. A Kinetic Study of the Ozone Attack on Phenylethylenes

1973 ◽  
Vol 51 (20) ◽  
pp. 3398-3402 ◽  
Author(s):  
H. Henry ◽  
M. Zador ◽  
S. Fliszár
Keyword(s):  
Liquid Phase ◽  
Solvent Effect ◽  
Kinetic Study ◽  
Temperature Effect ◽  
Reaction Rates ◽  
Quantitative Investigation ◽  
Polar Solvents ◽  
Absolute Reaction

Absolute reaction rates for the ozonolysis of phenylethylenes in the liquid phase indicate: (i) a Hammett dependence, with [Formula: see text], for the ring-substituted trans stilbenes, (ii) a solvent effect, whereby the ozone attack is promoted by polar solvents, and (iii) no temperature effect between 15 and 35 °C, thus indicating [Formula: see text].

Viscosity of binary and ternary liquid nonelectrolyte mixtures. Derivation of correlation equations

1981 ◽  
Vol 46 (2) ◽  
pp. 329-339 ◽  
Author(s):  
Pavol Škubla
Keyword(s):  
Kinetic Theory ◽  
Reaction Rates ◽  
Ternary Mixtures ◽  
Kinetic Theory Of Gases ◽  
Correlation Equations ◽  
Binary And Ternary Mixtures ◽  
Model Equations ◽  
Molecule Model ◽  
Eyring's Theory ◽  
Absolute Reaction

Equations for the correlation of viscosity of liquid binary and ternary mixtures were derived from the Eyring's theory of absolute reaction rates and from the three-molecule model of viscosity interactions. Another equation for the correlation of viscosity of binary mixtures was derived from the same theory and from the four-molecule model. Equations for the correlation of viscosity of binary and ternary mixtures were further derived from the quasi-crystalline model of liquids with the use of some relations of the kinetic theory of gases. The derived equations involve the same number of coefficients as the corresponding equations of McAllister or Chandramouli and Laddha and moreover are linear with respect to these coefficients.

Nanoparticles Size in Fe73.5Cu1Mo3Si13.5B9 Melt

2020 ◽  
Vol 861 ◽  
pp. 107-112
Author(s):  
Vladimir S. Tsepelev ◽  
Yuri N. Starodubtsev ◽  
Kai Ming Wu ◽  
Yekaterina A. Kochetkova
Keyword(s):  
Experimental Data ◽  
Diffusion Coefficient ◽  
Critical Temperature ◽  
Temperature Dependence ◽  
Kinematic Viscosity ◽  
Arrhenius Equation ◽  
Reaction Rates ◽  
Mechanical Theory ◽  
Statistical Mechanical ◽  
Absolute Reaction

The size of the nanoparticles participating in the viscous flow and the diffusion coefficient were calculated using statistical mechanical theory of absolute reaction rates and the Arrhenius equation. As experimental data, temperature dependence of the kinematic viscosity and density of Fe73.5Cu1Mo3Si13.5B9 melt was used. At a temperature of 1600 K, after the melt is overheated above the critical temperature Tk = 1770 K, the nanoparticles size decreases from 0.92 to 0.47 nm, and the diffusion coefficient increases from 2.4·10-10 to 4.5·10-10 m2·s-1.

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