scholarly journals Comparative Assessment of Hydrocarbon Generation Potential of Organic Matter from Shale Sediments along Isugwuato – Okigwe Axis, Anambra Basin, SE Nigeria

2021 ◽  
Vol 25 (3) ◽  
pp. 353-362
Author(s):  
M.U. Uzoegbu ◽  
C.U. Ugwueze

TRACT: The Cretaceous sediments in the Anambra Basin (SE Nigeria) consist of a cyclic succession of coals, carbonaceous shales, silty shales and siltstones  interpreted as deltaic deposits. The objective of this study is to compare the hydrocarbon generation potential of organic matter from shale sediments along Isugwuato-Okigwe axis in the Anambra Basin, Nigeria. Data obtained indicates the presence of Type III kerogen with Tmax values are between 424 and 441ºC indicating that the shales are thermally immature to marginally mature with respect to petroleum generation. Hydrogen Index (HI) values range from 14 to 388.9mgHC/gTOC while S1 + S2 yields values ranging from 0.2 to 1.0mgHC/g rock, suggesting that the shale have gas generating potential. The TOC values rangesfrom 1.3 to 3.0%, an indication of a good source rock of terrestrially derived organic matter. The high oxygen index (OI) (16.3 mgCO2g-1TOC), TS (1.35) and TOC/TS (1.5) suggest deposition in a shallow marine environment. Based on the kerogen type, shales from the studied area will equally generate oil and gas if its organic matter attained sufficient thermal temperature. Keywords: Shale, kerogen type, maturity, oil generation.

2019 ◽  
Vol 11 (1) ◽  
pp. 77-88 ◽  
Author(s):  
Wrya J. Mamaseni ◽  
Srood F Naqshabandi ◽  
Falah Kh. Al-Jaboury

Abstract In this study collected samples of Chia Gara Formation in Atrush, Shaikhan and Sarsang oilfields are used to geochemical characteristics of organic matter in this formation. This determination was based on Rock-Eval pyrolysis and Biomarker analyses. The Chia Gara Formation can be considered as good to excellent source rock; it’s TOC content ranges from 1.14-8.5wt% with an average of 1.85%, 3.91%, and 6.94% in Atush-1, Mangesh-1 and Shaikhan-8 wells respectively. The samples of Chia Gara Formation contain kerogen type II. These properties are considered optimal for oil generation. The low oxygen index (OI) and pristane/phytane (Pr/Ph) ratios (Average 20.73, 0.61 respectively) and high hydrogen index (HI) (average 637.6) indicate that the formation was deposited under anoxic condition. According to regular sterane (C27%, C28%, C29%) and terpanes ratios (C29/C30, C31/C30 hopane), the formation was deposited in marine environment. The average value of the Carbon Preference Index (CPI) is one with Tmax values of more than 430 ºC; these indicate peak oil window for the selected samples. Overall, the 20S/(20S+20R), ββ/(ββ+αα)C29 steranes and 22R/(22R+22S)C32homohopane, with Ts/ (Ts+Tm), and moretane/ hopane ratios point to a mature organic matter and to the ability of the formation to generate oil.


2016 ◽  
Author(s):  
Samuel Salufu ◽  
Rita Onolemhemhen ◽  
Sunday Isehunwa

ABSTRACT This paper sought to use information from outcrop sections to characterize the source and reservoir rocks in a basin in order to give indication(s) for hydrocarbon generation potential in a basin in minimizing uncertainty and risk that are allied with exploration and field development of oil and gas, using subsurface data from well logs, well sections, seismic and core. The methods of study includes detailed geological, stratigraphical, geochemical, structural,, petro-graphical, and sedimentological studies of rock units from outcrop sections within two basins; Anambra Basin and Abakaliki Basin were used as case studies. Thirty eight samples of shale were collected from these Basins; geochemical analysis (rockeval) was performed on the samples to determine the total organic content (TOC) and to assess the oil generating window. The results were analyzed using Rock wares, Origin, and Surfer software in order to properly characterize the potential source rock(s) and reservoir rock(s) in the basins, and factor(s) that can favour hydrocarbon traps. The results of the geological, stratigraphical, sedimentological, geochemical, and structural, were used to developed a new model for hydrocarbon generation in the Basins. The result of the geochemical analysis of shale samples from the Anambra Basin shows that the TOC values are ≥ 1wt%, Tmax ≥ 431°C, Vitrinite reflectance values are ≥ 0.6%, and S1+S2 values are > 2.5mg/g for Mamu Formation while shale samples from other formations within Anambra Basin fall out of these ranges. The shale unit in the Mamu Formation is the major source rock for oil generation in the Anambra Basin while others have potential for gas generation with very little oil generation. The shale samples from Abakaliki Basin shows that S1+S2 values range from< 1 – 20mg/g, TOC values range from 0.31-4.55wt%, vitrinite reflectance ranges from 0.41-1.24% and Tmax ranges from423°C – 466°C. This result also shows that there is no source rock for oil generation in Abakaliki Basin; it is either gas or graphite. This observation indicates that all the source rocks within Abakaliki Basin have exceeded petroleum generating stage due to high geothermal heat resulting from deep depth or the shale units have not attained catagenesis stage as a result of S1+S2 values lesser than 2.5mg/g despite TOC values of ≥ 0.5wt% and vitrinite reflectance values of ≥ 0.6%. The novelty of this study is that the study has been able to show that here there is much more oil than the previous authors claimed, and the distribution of this oil and gas in the basins is controlled by two major factors; the pattern of distribution of the materials of the source rock prior to subsidence and during the subsidence period in the basin, and the pattern and the rate of tectonic activities, and heat flow in the basin. If these factors are known, it would help to reduce the uncertainties associated with exploration for oil and gas in the two basins.


2018 ◽  
Vol 36 (3) ◽  
pp. 388-413 ◽  
Author(s):  
Fanghao Xu ◽  
Jiaju Liang ◽  
Guosheng Xu ◽  
Haifeng Yuan ◽  
Yong Liu

The Bohai Bay region is a primary accumulation area of oil and gas in offshore China, in which overpressure commonly occurs in the Paleogene strata; the analysis on distribution characteristics and genetic mechanisms of the overpressure would provide geologic evidences for making plans of well drilling and logging as well as oil and gas exploitation; additionally, it could lay the geological foundation for studying how overpressure controlled hydrocarbon accumulation. Based on research, the overpressure of the study area starts from the second member of the Dongying Formation and ends in the third member of the Shahejie Formation. The distribution of overpressure is mainly controlled by the sag–salient tectonic framework within the basin, which means overpressure mainly develops in sags or slopes; however, high areas stay normal pressured. In the study area, pressure develops around Bozhong Sag and in northern Liaodong Bay reaches the peak. The genetic mechanisms of overpressures in the Paleogene reservoirs are mainly disequilibrium compaction, hydrocarbon generation of the organic matter, fluid charging, and transmission or the superimposition of the former two. Different strata have different genetic mechanisms of overpressure. The chief genetic mechanisms for the generation of overpressure of the Dongying Formation are disequilibrium compaction while the genesis of the formation of overpressure in the Shahejie Formation is more complicated in some extent. The first member of the Shahejie Formation dominated by disequilibrium compaction and hydrocarbon generation of the organic matter plays a supplemental role, while the second member of the Shahejie Formation, as the primary reservoir strata, is dominated by fluid charging and transmission, and the third member of the Shahejie Formation is the main source rock interval; its overpressure is closely related to hydrocarbon generation. Each contribution ratio for overpressure forming by different genetic mechanisms has been judged and figured out quantitatively according to geological, geophysical, and geochemical characteristics of the target strata.


2018 ◽  
Vol 36 (5) ◽  
pp. 1157-1171
Author(s):  
Agostinho Mussa ◽  
Deolinda Flores ◽  
Joana Ribeiro ◽  
Ana MP Mizusaki ◽  
Mónica Chamussa ◽  
...  

The Mozambique Basin, which occurs onshore and offshore in the central and southern parts of Mozambique, contains a thick sequence of volcanic and sedimentary rocks that range in age from the Jurassic to Cenozoic. This basin, along with the Rovuma basin to the north, has been the main target for hydrocarbon exploration; however, published data on hydrocarbon occurrences do not exist. In this context, the present study aims to contribute to the understanding of the nature of the organic matter of a sedimentary sequence intercepted by the Nemo-1X exploration well located in the offshore area of the Mozambique Basin. The well reached a depth of 4127 m, and 33 samples were collected from a depth of 2219–3676 m ranging in age from early to Late Cretaceous. In this study, petrographic and geochemical analytical methods were applied to assess the level of vitrinite reflectance and the organic matter type as well as the total organic carbon, total sulfur, and CaCO3 contents. The results show that the total organic carbon content ranges from 0.41 to 1.34 wt%, with the highest values determined in the samples from the Lower Domo Shale and Sena Formations, which may be related to the presence of the solid bitumens that occur in the carbonate fraction of those samples. The vitrinite random reflectances range from 0.65 to 0.86%Rrandom, suggesting that the organic matter in all of the samples is in the peak phase of the “oil generation window” (0.65–0.9%Rrandom). The organic matter is mainly composed of vitrinite and inertinite macerals, with a minor contribution of sporinite from the liptinite group, which is typical of kerogen type III. Although all of the samples have vitrinite reflectances corresponding to the oil window, the formation of liquid hydrocarbons is rather limited because the organic matter is dominated by gas-prone kerogen type III.


1970 ◽  
Vol 10 (1) ◽  
pp. 35 ◽  
Author(s):  
J. D. Brooks

Petroleum hydrocarbons are not normal constituents of recent sediments but only appear when a certain stage of diagenesis is reached, through deeper burial. An investigation of the mechanism of formation of oil and gas has shown that an indication of the generation of oil in a sedimentary basin can be obtained by an examination of coals or coaly material encountered during drilling.Coals form a continuous diagenetic and metamorphic series beginning with peat and ending with graphite. Peat and brown coal contain the same type of hydrocarbons as are present in land plants but the composition of coal hydrocarbons changes abruptly in the sub-bituminous to high-volatile bituminous coal range. This is because petroleum-type hydrocarbons are formed at this stage from precursors which are components of waxy leaf cuticles, pollen and spore coatings, by chemical reactions in which oxygen groups are removed from long-chain acids, alcohols and ester waxes. Most Australian oil occurrences are associated with coal-bearing sediments and it appears likely that they are formed at the same stage of alteration, from such land plant residues, finely disseminated in shales and siltstones.The diagenetic changes in coal composition are caused by the increasing temperature accompanying deeper burial, and the composition of a coal, whatever its present depth, is an indication of the maximum temperature to which it has been subjected. The determination of carbon content, reflectivity and other properties of coal samples provided by a number of oil companies, together with laboratory experiments in which petroleum-type hydrocarbons were generated by artificial diagenesis of coal components, indicated that hydrocarbon generation takes place only when the carbon content of the coals approaches 80 percent. In sedimentary basins in Australia the petroleum generation zone occurs at depths varying from 5,500 to greater than 11,000ft., depending upon present or past geothermal gradient.In addition to this lower limit of diagenesis, it has long been maintained that a relation exists (the Carbon Ratio theory) between the likely occurrence of oil and gas reservoirs in a sedimentary basin and the degree of metamorphism of coal if present. The theory sets an upper limit of alteration of organic matter, and states that oil reservoirs are unlikely to occur in areas or at depths in a basin where the 'fixed-carbon' of the coals is greater than about 65 percent (equivalent to a coal of about 85 percent total carbon — dry, mineral-matter free). The Gid-gealpa-Moomba area appears to be a part of the Cooper Basin in which the organic matter is close to this upper limit of metamorphism. The carbon content of the coal at Gidgealpa, associated with gas and light hydrocarbons, is 85-86 percent whereas that at Moomba, associated with dry gas, is higher at approximately 89 percent.Ihus the properties of coal samples encountered during drilling can provide valuable clues for the petroleum geologist in the search for further oil and gas reserves.


2012 ◽  
Vol 616-618 ◽  
pp. 1042-1047
Author(s):  
Zhong Hong Chen

To investigate hydrocarbon potential of the evaporites, some deep wells such as Haoke-1 well and Fengshen-2 well were intensively cored, tested by TOC, Rock-Eval, and chromatography and mass spectrometry and evaluated using geochemistry of biomarker and hydrocarbon generation. High content of gammacerane and low Pr/Ph was exhibited in the evaporite system compared to the non-evaporite system. Different response of biomarkers parameters for the different sedimentary systems was exhibited, such as C19/(C19+C23) terpanes, C29/(C27+C28+C29) steranes, C24/C23 and C22/C21 tricyclic terpane. The evaporites and mud stones have the capacity to generate and expel hydrocarbons. The tested samples were mostly typeⅠand typeⅡ1 of organic matter, and their original generating capacity can reach 40 mg/g rock and 20 mg/g rock respectively. The efficiency of hydrocarbon expulsion reached 60%, but the distribution of organic matter and its generative potential was highly variable. In general, the mudstones show greater generative potential than the evaporites. High maturity severely reduced the capacity of their rocks to generate and expel petroleum.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Olumuyiwa Adedotun Odundun

Organic geochemical studies and fossil molecules distribution results have been employed in characterizing subsurface sediments from some sections of Anambra Basin, southeastern Nigeria. The total organic carbon (TOC) and soluble organic matter (SOM) are in the range of 1.61 to 69.51 wt% and 250.1 to 4095.2 ppm, respectively, implying that the source rocks are moderately to fairly rich in organic matter. Based on data of the paper, the organic matter is interpreted as Type III (gas prone) with little oil. The geochemical fossils and chemical compositions suggest immature to marginally mature status for the sediments, with methyl phenanthrene index (MPI-1) and methyl dibenzothiopene ratio (MDR) showing ranges of 0.14–0.76 and 0.99–4.21, respectively. The abundance of 1,2,5-TMN (Trimethyl naphthalene) in the sediments suggests a significant land plant contribution to the organic matter. The pristane/phytane ratio values of 7.2–8.9 also point to terrestrial organic input under oxic conditions. However, the presence of C27 to C29 steranes and diasteranes indicates mixed sources—marine and terrigenous—with prospects to generate both oil and gas.


2016 ◽  
Vol 53 (10) ◽  
pp. 1053-1072 ◽  
Author(s):  
Mohammed Hail Hakimi ◽  
Abdulghani F. Ahmed

Late Jurassic – Early Cretaceous shales of the Naifa, Safer, and Madbi formations were studied to evaluate source rock characterization. The results of the source rock were then incorporated into basin modeling to understand the timing of hydrocarbon (HC) generation and expulsion. The Late Jurassic – Early Cretaceous shales have low to high organic matter, with total organic carbon (TOC) values in the range of 0.50%–28.01%, indicating fair to excellent source rock potential. Main oil and gas are anticipated to be generated from the Naifa, Safer, and Lam shale samples with types I and (or) II and types II–III kerogens. In contrast, the Meem samples are dominated by type III kerogen (hydrogen index, HI < 200 mg HC / g TOC), and are thus considered to be gas prone. The Late Jurassic – Early Cretaceous shale samples have temperatures of maximum pyrolysis yield (Tmax) in the range of 337–515 °C, consistent with immature to post-mature stages. The Tmax data also indicate that the Safer and Madbi shale samples have sufficient thermal maturity, i.e., peak–mature oil and gas window. The basin models indicate that the Naifa Formation is early–mature, and the onset oil generation began during the Early Miocene. The models also indicate that the main phase of oil generation in the Safer source rock began during the Late Eocene. In contrast, the Madbi source rock units had passed the peak oil generation window, and the oil was converted to gas during the Late Cretaceous to Late Eocene. The modeled HC expulsion history reveals that most oils are contributed by both Madbi units, with significant amounts of gas originating from the Meem unit.


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