scholarly journals Anaerobic Degradation of Dairy Wastewater in Intermittent UASB Reactors: Influence of Effluent Recirculation

2021 ◽  
Vol 15 ◽  
pp. 35-40
Author(s):  
A. Silva ◽  
I. Capela ◽  
L. Arroja ◽  
H. Nadais

This work studied the influence of effluent recirculation upon the kinetics of anaerobic degradation of dairy wastewater in intermittent UASB (Upflow Anaerobic Sludge Bed) reactors. Several laboratory-scale tests were performed with different organic loads in a UASB reactor inoculated with flocculent sludge from an industrial wastewater treatment plant. The data obtained were used for determination of specific substrate removal rates and specific methane production rates and adjusted to kinetic models. A high initial substrate removal was observed in all tests due to adsorption of organic matter onto the anaerobic biomass which was not accompanied by biological substrate degradation as measured by methane production. Initial methane production was about 45% of initial soluble and colloidal substrate removal rate. This discrepancy was observed mainly in the first day of all experiments and was attenuated in the second day. Effluent recirculation raised significantly the rate of removal of soluble and colloidal substrate and methane productivity as compared to literature results for batch assays without recirculation.

Author(s):  
A. Silva ◽  
C. Couras ◽  
I. Capela ◽  
L. Arroja ◽  
H. Nadais

This work studied the influence of effluent recirculation upon the kinetics of anaerobic degradation of dairy wastewater in intermittent UASB (Upflow Anaerobic Sludge Bed) reactors. Several laboratory-scale tests were performed with different organic loads in a UASB reactor inoculated with flocculent sludge from an industrial wastewater treatment plant. The data obtained were used for determination of specific substrate removal rates and specific methane production rates and adjusted to kinetic models. A high initial substrate removal was observed in all tests due to adsorption of organic matter onto the anaerobic biomass which was not accompanied by biological substrate degradation as measured by methane production. Initial methane production was about 45% of initial soluble and colloidal substrate removal rate. This discrepancy was observed mainly in the first day of all experiments and was attenuated in the second day. Effluent recirculation raised significantly the rate of removal of soluble and colloidal substrate and methane productivity as compared to literature results for batch assays without recirculation.


2014 ◽  
Vol 69 (12) ◽  
pp. 2562-2569 ◽  
Author(s):  
Orkun I. Davutluoglu ◽  
Galip Seckin

The anaerobic degradation of terephthalic acid (TA) as the sole organic carbon source was studied in an upflow anaerobic filter (UAF) reactor. The reactor was seeded with biomass obtained from a full-scale upflow anaerobic sludge bed (UASB) reactor and was used to treat wastewater from a petrochemical facility producing dimethyl terephthalate. The UAF reactor was operated for 252 d with a constant hydraulic retention time of 24 h, and the organic loading rate (OLR) was gradually increased from 1 to 10 g-chemical oxygen demand (COD)/L d. After a lag period of approximately 40 d, the COD removal efficiency increased exponentially and high removal rate values (≈90%) were obtained, except for at highest OLR (10 g-COD/L d). The high removal rates and the robustness of the reactor performance could be attributed to the formation of biofilm as well as granular sludge. The methane production rates (0.22 to 2.15 L/d) correlated well with the removed OLRs (0.3 to 6.8 g-COD/L d) during the various phases of treatment, indicating that the main mechanism of TA degradation occurs via methanogenic reactions. The average methane content of the produced biogas was 70.3%. The modified Stover–Kincannon model was found to be applicable for the anaerobic degradation of TA in UAFs (Umax = 64.5, KB = 69.1 g-COD/L d and Ymax = 0.27 L-CH4/g-CODremoved). These results suggest that UAF reactors are among the most effective reactor configurations for the anaerobic degradation of TA.


2020 ◽  

<p>Microbial kinetics of a hybrid upflow anaerobic sludge blanket (UASB) reactor were investigated when treating chemical synthesis–based pharmaceutical wastewater. Monod, Grau first-order, Grau second-order, Stover-Kincannon, Chen &amp; Hashimoto kinetic models were applied to the hybrid reactor. The second-order model was found to be the most appropriate model for the hybrid reactor (R2 = 0.99) and offers the best description of the process. The substrate removal rate constant (k2S) was found to be 4.91 d-1.</p>


Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 512
Author(s):  
Jeremiah Chimhundi ◽  
Carla Hörstmann ◽  
Evans M. N. Chirwa ◽  
Hendrik G. Brink

The main objective of this study was to achieve the continuous biorecovery and bioreduction of Pb(II) using an industrially obtained consortia as a biocatalyst. An upflow anaerobic sludge blanket reactor was used in the treatment process. The bioremediation technique that was applied made use of a yeast extract as the microbial substrate and Pb(NO3)2 as the source of Pb(II). The UASB reactor exhibited removal efficiencies of between 90 and 100% for the inlet Pb concentrations from 80 to 2000 ppm and a maximum removal rate of 1948.4 mg/(L·d) was measured. XRD and XPS analyses of the precipitate revealed the presence of Pb0, PbO, PbS and PbSO4. Supporting experimental work carried out included growth measurements, pH, oxidation–reduction potentials and nitrate levels.


2016 ◽  
Vol 78 (5-6) ◽  
Author(s):  
Sunwanee Jijai ◽  
Chairat Siripatana ◽  
Sompong O-Thong ◽  
Norli Ismail

The three identical lab-scale upflow anaerobic sludge blanket (UASB) reactors were operated continuously for treating cannery seafood wastewater at seven hydraulic retention times (HRTs) of 5, 4, 3, 2, 1, 0.5 and 0.25 days. The different of granule sizes from three sources: a cassava factory (CS), a seafood factory (SS), and a palm oil mill (PS), average sizes in the range 1.5-1.7, 0.7-1.0 and 0.1-0.2 mm respectively were used as inocula for anaerobic digestion. The UASB-R1 used only granules from seafood factory (R1-SS), the UASB-R2 used mixed granules from seafood with cassava factory (R2-SS+CS) and the UASB-R3 used mixed granules from seafood factory with palm oil mill (R3-SS+PS). In this study selected mathematical models including Monod, Contois, Grau second-order and modified Stover-Kicannon kinetic models were applied to determine the substrate removal kinetics of UASB reactor. Kinetic parameters were determined through linear regression using experimental data obtained from the steady-state experiment and subsequently used to predict effluent COD. The results showed that Grau second-order and modified Stover-Kicannon kinetic models were more suitable than that of others for predicting the effluent COD, with high the correlation coefficient (R2). In addition, the UASB-R2 from mixed granules with cassava factory (SS+CS) gave the best performance and highest coefficient value.


2021 ◽  
Vol 26 (1) ◽  
pp. 25
Author(s):  
Zulkarnaini Zulkarnaini ◽  
Puti Sri Komala ◽  
Arief Almi

The anaerobic ammonium oxidation (anammox) biofilm process commonly uses various inorganic carriers to enhance nitrogen removal under anaerobic conditions. This study aims to analyze the performance of nitrogen removal in anammox process using sugarcane bagasse as an organic carrier. The experiment was carried out by using an up‐flow anaerobic sludge blanket (UASB) reactor for treating artificial wastewater at room temperature. The reactor was fed with ammonium and nitrite with the concentrations of 70‐150 mg–N/L and variations in the hydraulic retention time of 24 and 12 h. The granular anammox belongs to the genus Candidatus Brocadia sinica that was added as an inoculum of the reactor operation. The experimental stoichiometric of anammox for ΔNO2‐–N: ΔNH4+–N and ΔNO3‐: ΔNH4+ were 1.24 and 0.18, respectively, which is similar to anammox stoichiometry. The maximum Nitrogen Removal Rate (NRR) has achieved 0.29 kg–N/m3.d at Nitrogen Loading Rate (NLR) 0.6 kg–N/m3.d. The highest ammonium conversion efficiency (ACE) and nitrogen removal efficiency (NRE) were 88% and 85%, respectively. Based on this results, it indicated that sugarcane bagasse as organic carriers could increase the amount of total nitrogen removal by provided of denitrification process but inhibited the anammox process at a certain COD concentration.


1997 ◽  
Vol 36 (2-3) ◽  
pp. 237-248 ◽  
Author(s):  
Robbert Kleerebezem ◽  
Joost Mortier ◽  
Look W. Hulshoff Pol ◽  
Gatze Lettinga

During petrochemical production of purified terephthalic acid (PTA, 1,4-benzene dicarboxylic acid), a large quantity of concentrated effluent is produced. Main polluting compounds in this wastewater are terephthalic acid, acetic acid and benzoic acid in decreasing order of concentration. Acetic acid and benzoic acid are known to be rapidly degraded in high rate anaerobic treatment systems, such as Upflow Anaerobic Sludge Bed (UASB) reactors. Concerning the kinetics of anaerobic mineralization of terephthalic acid, however, no information is available in literuature. Therefore our work focused on the anaerobic degradation of neutralized terephthalic acid (disodium terephthalate) in laboratory scale UASB-reactors and batch reactors. It was found that high rate anaerobic treatment of terephthalate was difficult to obtain due to the low growth rate (μ ≈ 0.04 day−1) of the terephthalate mineralizing mixed culture. The maximum removal capacity of a lab-scale UASB-reactor was found to be 3.9 g COD.1−1 .day−1 at a loading rate of 4.5 g COD.1−1 .day−1 and a hydraulic retention time of 24 hours. Terephthalate was used as sole carbon source during these experiments. Addition of small amounts of sucrose (co-substrate) to the influent, as a source of reducing equivalents, was found to have a negative influence on the anaerobic degradation of terephthalate. Also benzoate was found to inhibit the mineralization of terephthalate. Batch-toxicity experiments showed that terephthalate is not toxic to any of the species involved in its mineralization. Based on these observations, a staged anaerobic reactor system is suggested for the anaerobic pre-treatment of PTA-wastewater.


2013 ◽  
Vol 67 (5) ◽  
pp. 968-975 ◽  
Author(s):  
C. G. Casagrande ◽  
A. Kunz ◽  
M. C. De Prá ◽  
C. R. Bressan ◽  
H. M. Soares

The anaerobic ammonium oxidation (ANAMMOX) is a chemolithoautotrophic process, which converts NH4+ to N2 using nitrite (NO2−) as the electron acceptor. This process has very high nitrogen removal rates (NRRs) and is an alternative to classical nitrification/denitrification wastewater treatment. In the present work, a strategy for nitrogen removal using ANAMMOX process was tested evaluating their performance when submitted to high loading rates and very short hydraulic retention times (HRTs). An up-flow ANAMMOX column reactor was inoculated with 30% biomass (v v−1) fed from 100 to 200 mg L−1 of total N (NO2−-N + NH4+-N) at 35 °C. After start-up and process stability the maximum NRR in the up-flow anaerobic sludge blanket (UASB) reactor was 18.3 g-N L−1 d−1 operated at 0.2 h of HRT. FISH (fluorescence in situ hybridization) analysis and process stoichiometry confirmed that ANAMMOX was the prevalent process for nitrogen removal during the experiments. The results point out that high NRRs can be obtained at very short HRTs using up-flow ANAMMOX column reactor configuration.


2004 ◽  
Vol 31 (3) ◽  
pp. 420-431 ◽  
Author(s):  
S K Patidar ◽  
Vinod Tare

The effect of micro-nutrients, such as Fe, Ni, Zn, Co, and Mo, on anaerobic degradation of sulfate laden organics was investigated using bench-scale models of upflow anaerobic sludge blanket (UASB) reactor, anaerobic baffled reactor (ABR), and hybrid anaerobic baffled reactor (HABR), operating in varying conditions in ten phases (organic loading of 1.9–5.75 kg COD/(m3·d), sulfate loading of 0.54–1.88 kg SO42–/(m3·d), chemical oxygen demand (COD):SO42–ratio of 2.0–8.6). In the initial phase, no nutrient limitation was observed with COD removal of more than 94% in all three systems. Subsequently, increase in sulfate loading resulted in Ni and Co limitation and their supplementation restored COD removal in UASB system. However, baffled systems did not recover because of severe inhibition by sulfide. Results indicate that precipitation of nutrients could seriously deteriorate process performance, leading to failure even before sulfide concentration attains toxic level. The limitation of Fe coupled with high sulfate loading (1.88 kg SO42–/(m3·d)) resulted in growth of low-density, fragile, hollow, and granular biomass in UASB that washed out and caused process instability. Supplementation of Fe with other nutrients stabilized UASB process and also improved COD removal.Key words: anaerobic degradation, nutrients, UASB, ABR, HABR, sulfide toxicity, sulfate laden organics.


2019 ◽  
Vol 14 (4) ◽  
pp. 908-920 ◽  
Author(s):  
Oliver Saavedra ◽  
Ramiro Escalera ◽  
Gustavo Heredia ◽  
Renato Montoya ◽  
Ivette Echeverría ◽  
...  

Abstract This study aims to determine the seasonal variability in the performance of a medium size population wastewater treatment plant (WWTP) in Bolivia. The semi-arid area where the WWTP is located is characterized as agricultural land, with an annual rainfall of 500 mm and a mean temperature of 17 °C. The WWTP is built up of five modules, each one comprising two treatment trains composed of an upflow anaerobic sludge blanket (UASB) reactor and horizontal gravel filter. The performance of the full process has been determined based on water quantity and quality. Seven monitoring campaigns of chemical and physical wastewater characteristics were performed from March to December 2017. The measured effluent showed average removal efficiencies of 83 ± 8% and 37 ± 60% for total chemical oxygen demand (COD) and total suspended solids (TSS), respectively. The treatment system has proven to be efficient to remove organic matter and TSS, despite the occurrence of high COD and total solids (TS) influent concentrations, the accumulation of solids at all the processes and the variability of flow and temperature inside the UASB reactors. In order to improve further this efficiency, it is recommended to implement a primary sedimentation unit as a pretreatment for the UASB system that would help to homogenize both the flow and the quality of the influent.


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