scholarly journals Utilization of Calcined Gypsum in Water and Wastewater Treatment: Removal of Ibuprofen

2018 ◽  
Vol 1 (2) ◽  
pp. 78-83
Author(s):  
Aiman Al-Rawajfeh
Keyword(s):  
Setting Time ◽  
Polluted Water ◽  
Water And Wastewater Treatment ◽  
First Order ◽  
First Order Kinetics ◽  
Study Results ◽  
Water And Wastewater ◽  
Percentage Removal ◽  
Calcined Gypsum ◽  
Micro Pollutants

Adsorption is a widely used technique for the removal of pharmaceutical organic micro-pollutants. In this article, calcined gypsum (CaSO4.0.5H2O) was utilized for the removal of ibuprofen medicine from polluted water. Several factors including the adsorbent dose, contact time, and temperature were studied. The influence of the ions in the solution on the precipitation of gypsum and its setting time was investigated because it significantly affects the percentage removal. The fast the setting time gypsum, the lower the percentage removal precipitate. From thermodynamic parameters, the negative values of ΔGo indicated a spontaneous and physisorption of ibuprofen onto the calcined gypsum surface. Kinetic study results showed that the adsorption of ibuprofen on gypsum follows pseudo-first-order kinetics.

scholarly journals Utilization of Calcined Gypsum in Water and Wastewater Treatment: Removal of Phenol

2019 ◽  
Vol 20 (7) ◽  
pp. 1-10 ◽  
Author(s):  
Chinenye Igwegbe ◽  
Aiman Al-Rawajfeh ◽  
H.I. Al-Itawi ◽  
S. Sharadqah ◽  
Shahd Al-Qazaqi ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Water And Wastewater Treatment ◽  
Water And Wastewater ◽  
Calcined Gypsum

Adsorption Studies of Trimethoprim Antibiotic on Powdered and Granular Activated Carbon in Distilled and Natural Water

2018 ◽  
pp. 223-230
Author(s):  
Michael A. Opanga ◽  
Vincent O. Madadi ◽  
Shem O. Wandiga ◽  
Holiness M. Nose ◽  
Charles W. Mirikau ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Natural Water ◽  
Granular Activated Carbon ◽  
Batch Process ◽  
Distilled Water ◽  
Negative Effects ◽  
Water And Wastewater Treatment ◽  
Significant Difference ◽  
Water And Wastewater ◽  
Micro Pollutants

Contamination of drinking water sources by Pharmaceuticals and Personal Care Products (PPCPs) has raised concerns due to associated negative effects on the ecosystem, which include reproductive and hormonal malfunctions in some living organisms. In addition, occurrence of antibiotics in aquatic environment has been associated with development of antimicrobial resistance. However, the conventional water and wastewater treatment technologies are not effective at removing such organic micro-pollutants from the source waters, hence most of such contaminants find their way through the systems with minimal restrain. Hence accelerated effort to find technologies to enhance removal of recalcitrant organic micro-pollutants from the water and wastewater. The objective of this study was to investigate the removal of Trimethoprim (TMP) from natural water using Powdered Activated Carbon (PAC) and Granular Activated Carbon (GAC). Adsorption experiments were conducted following batch process using natural water and distilled water. We also investigated the effect of pH changes on adsorption of TMP from the water. We obtained better performance for PAC in the removal of TMP compared to GAC. The removal efficiency decreased as a function of TMP concentrations in the aqueous solution. The optimal pH for adsorption was found to be 7, whereas pH values below or above 7 exhibited decreased adsorption of the antibiotic. There was no significant difference in the adsorption of TMP in both natural water and distilled water, which was attributed to limited organic matter in the natural water that was used.

Photo-catalytic degradation of gaseous pollutants in paper mills of southern China

TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 167-178 ◽  
Author(s):  
Xin Tong ◽  
Jiao Li ◽  
Jun Ma ◽  
Xiaoquan Chen ◽  
Wenhao Shen
Keyword(s):  
Degradation Rate ◽  
Southern China ◽  
Catalytic Degradation ◽  
Pulp And Paper ◽  
Gaseous Pollutants ◽  
Pulp And Paper Mills ◽  
Paper Mills ◽  
Initial Concentration ◽  
First Order ◽  
First Order Kinetics

Studies were undertaken to evaluate gaseous pollutants in workplace air within pulp and paper mills and to consider the effectiveness of photo-catalytic treatment of this air. Ambient air at 30 sampling sites in five pulp and paper mills of southern China were sampled and analyzed. The results revealed that formaldehyde and various benzene-based molecules were the main gaseous pollutants at these five mills. A photo-catalytic reactor system with titanium dioxide (TiO2) was developed and evaluated for degradation of formaldehyde, benzene and their mixtures. The experimental results demonstrated that both formaldehyde and benzene in their pure forms could be completely photo-catalytic degraded, though the degradation of benzene was much more difficult than that for formaldehyde. Study of the photo-catalytic degradation kinetics revealed that the degradation rate of formaldehyde increased with initial concentration fitting a first-order kinetics reaction. In contrast, the degradation rate of benzene had no relationship with initial concentration and degradation did not conform to first-order kinetics. The photo-catalytic degradation of formaldehyde-benzene mixtures indicated that formaldehyde behaved differently than when treated in its pure form. The degradation time was two times longer and the kinetics did not reflect a first-order reaction. The degradation of benzene was similar in both pure form and when mixed with formaldehyde.

Kinetic of oxidation of methyl orange by vanadium(V) under conditions VO2+ and decavanadates coexist: Catalysis by Triton X-100 micellar medium

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Methyl Orange ◽  
Solution Ph ◽  
Vanadium Concentration ◽  
Limiting Behavior ◽  
First Order ◽  
First Order Kinetics ◽  
Ph Range ◽  
Kinetic Pattern ◽  
Triton X ◽  
Kinetics Of

The kinetics of oxidation of methyl orange by vanadium(V) {V(V)} has been investigated in the pH range 2.3-3.79. In this pH range V(V) exists both in the form of decavanadates and VO2+. The kinetic results are distinctly different from the results obtained for the same reaction in highly acidic solution (pH < 1) where V(V) exists only in the form of VO2+. The reaction obeys first order kinetics with respect to methyl orange but the rate has very little dependence on total vanadium concentration. The reaction is accelerated by H+ ion but the dependence of rate on [H+] is less than that corresponding to first order dependence. The equilibrium between decavanadates and VO2+ explains the different kinetic pattern observed in this pH range. The reaction is markedly accelerated by Triton X-100 micelles. The rate-[surfactant] profile shows a limiting behavior indicative of a unimolecular pathway in the micellar pseudophase.

Chemical Water and Wastewater Treatment VIII

2015 ◽  
Vol 4 (0) ◽  
pp. 9781780402840-9781780402840
Author(s):  
H. Hahn ◽  
E. Hoffman ◽  
H. Odegaard
Keyword(s):  
Wastewater Treatment ◽  
Water And Wastewater Treatment ◽  
Water And Wastewater ◽  
Chemical Water

Water and Wastewater Treatment for a Small Island Resort

1989 ◽  
Vol 21 (2) ◽  
pp. 189-193 ◽  
Author(s):  
B. Rigden
Keyword(s):  
Wastewater Treatment ◽  
Reverse Osmosis ◽  
Small Island ◽  
Rotating Biological Contactor ◽  
Water And Wastewater Treatment ◽  
Water And Wastewater ◽  
Operational Data ◽  
Reverse Osmosis Desalination

The design of a reverse osmosis desalination unit and a rotating biological contactor for water and wastewater treatment for a small island resort is described. Some operational data are presented and recommendations for design flows and loadings are made.

Biodegradation rates of aromatic contaminants in biofilm reactors

1995 ◽  
Vol 31 (1) ◽  
pp. 117-128 ◽  
Author(s):  
Jean-Pierre Arcangeli ◽  
Erik Arvin
Keyword(s):  
Aromatic Hydrocarbons ◽  
Competitive Inhibition ◽  
Removal Rate ◽  
First Order ◽  
Biofilm Reactors ◽  
First Order Kinetics ◽  
Reducing Conditions ◽  
Low Concentrations ◽  
Degradation Rates ◽  
Order Surface

This study has shown that microorganisms can adapt to degrade mixtures of aromatic pollutants at relatively high rates in the μg/l concentration range. The biodegradation rates of the following compounds were investigated in biofilm systems: aromatic hydrocarbons, phenol, methylphenols, chlorophenols, nitrophenol, chlorobenzenes and aromatic nitrogen-, sulphur- or oxygen-containing heterocyclic compounds (NSO-compounds). Furthermore, a comparison with degradation rates observed for easily degradable organics is also presented. At concentrations below 20-100 μg/l the degradation of the aromatic compounds was typically controlled by first order kinetics. The first-order surface removal rate constants were surprisingly similar, ranging from 2 to 4 m/d. It appears that NSO-compounds inhibit the degradation of aromatic hydrocarbons, even at very low concentrations of NSO-compounds. Under nitrate-reducing conditions, toluene was easily biodegraded. The xylenes and ethylbenzene were degraded cometabolically if toluene was used as a primary carbon source; their removal was influenced by competitive inhibition with toluene. These interaction phenomena are discussed in this paper and a kinetic model taking into account cometabolism and competitive inhibition is proposed.

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