scholarly journals The impact of temperature changes on summer time ozone and its precursors in the Eastern Mediterranean

2011 ◽  
Vol 11 (8) ◽  
pp. 3847-3864 ◽  
Author(s):  
U. Im ◽  
K. Markakis ◽  
A. Poupkou ◽  
D. Melas ◽  
A. Unal ◽  
...  

Abstract. Changes in temperature due to variability in meteorology and climate change are expected to significantly impact atmospheric composition. The Mediterranean is a climate sensitive region and includes megacities like Istanbul and large urban agglomerations such as Athens. The effect of temperature changes on gaseous air pollutant levels and the atmospheric processes that are controlling them in the Eastern Mediterranean are here investigated. The WRF/CMAQ mesoscale modeling system is used, coupled with the MEGAN model for the processing of biogenic volatile organic compound emissions. A set of temperature perturbations (spanning from 1 to 5 K) is applied on a base case simulation corresponding to July 2004. The results indicate that the Eastern Mediterranean basin acts as a reservoir of pollutants and their precursor emissions from large urban agglomerations. During summer, chemistry is a major sink at these urban areas near the surface, and a minor contributor at downwind areas. On average, the atmospheric processes are more effective within the first 1000 m above ground. Temperature increases lead to increases in biogenic emissions by 9±3% K−1. Ozone mixing ratios increase almost linearly with the increases in ambient temperatures by 1±0.1 ppb O3 K−1 for all studied urban and receptor stations except for Istanbul, where a 0.4±0.1 ppb O3 K−1 increase is calculated, which is about half of the domain-averaged increase of 0.9±0.1 ppb O3 K−1. The computed changes in atmospheric processes are also linearly related with temperature changes.

2011 ◽  
Vol 11 (2) ◽  
pp. 4355-4398
Author(s):  
U. Im ◽  
K. Markakis ◽  
A. Poupkou ◽  
D. Melas ◽  
A. Unal ◽  
...  

Abstract. Changes in temperature due to variability in meteorology and climate change are expected to significantly impact atmospheric composition. The Mediterranean is a climate sensitive region and includes megacities like Istanbul and large urban agglomerations such as Athens. The effect of temperature changes on gaseous air pollutant levels and the atmospheric processes that are controlling them in the Eastern Mediterranean are here investigated. The WRF/CMAQ mesoscale modeling system is used, coupled with the MEGAN model for the processing of biogenic volatile organic compound emissions. A set of temperature perturbations (spanning from 1 to 5 K) is applied on a base case simulation corresponding to July 2004. The results indicate that the Eastern Mediterranean basin acts as a reservoir of pollutants and their precursor emissions from large urban agglomerations. During summer, chemistry is a major sink at these urban areas near the surface, and a minor contributor at downwind areas. On average, the atmospheric processes are more effective within the first 1000 m. The response rate of biogenic emissions to temperature changes is calculated to be 9±3% K−1. Ozone concentrations respond almost linearly to the changes in the ambient temperature with rates of 1±0.1 ppb O3 K−1 for all studied urban and receptor stations except for Istanbul, where a 0.4±0.1 ppb O3 K−1 change rate is calculated, which is almost half of the domain-averaged increase of 0.9±0.1 ppb O3 K−1. The computed changes in atmospheric processes are also linearly related with temperature changes.


2020 ◽  
Vol 15 ◽  
pp. 65
Author(s):  
Salisu M. Garba ◽  
Usman A. Danbaba

In this study, a non-autonomous (temperature dependent) and autonomous (temperature independent) models for the transmission dynamics of malaria in a population are designed and rigorously analysed. The models are used to assess the impact of temperature changes on various control strategies. The autonomous model is shown to exhibit the phenomenon of backward bifurcation, where an asymptotically-stable disease-free equilibrium (DFE) co-exists with an asymptotically-stable endemic equilibrium when the associated reproduction number is less than unity. This phenomenon is shown to arise due to the presence of imperfect vaccines and disease-induced mortality rate. Threshold quantities (such as the basic offspring number, vaccination and host type reproduction numbers) and their interpretations for the models are presented. Conditions for local asymptotic stability of the disease-free solutions are computed. Sensitivity analysis using temperature data obtained from Kwazulu Natal Province of South Africa [K. Okuneye and A.B. Gumel. Mathematical Biosciences 287 (2017) 72–92] is used to assess the parameters that have the most influence on malaria transmission. The effect of various control strategies (bed nets, adulticides and vaccination) were assessed via numerical simulations.


2020 ◽  
Author(s):  
Yumi Kim

<p><span><span>Along with the development of new cities, the construction of LNG cogeneration plant in urban areas is being promoted, and the facility has been pointed out as one of the major air pollution sources along with many vehicles in urban areas. For example, the construction of a new administrative city in Korea has led to the relocation of major government buildings and the influx of more than 300,000 people. The city has a 530 MW power plant + 391 Gcal/h district heating facility. The facility released 294,835 kg and 325,381 kg of NOx annually in 2017 and 2018, respectively. When examining the impact, we analyzed the impact of air pollutants (PM<sub>2.5</sub>, O<sub>3</sub>, NO<sub>2</sub>, etc.) through CMAQ modeling. In addition, the impact prediction using AERMOD related to the release of carcinogenic air pollutants is estimated to be no more than 10<sup>-5</sup> (risk level), but measurement and verification are required. In addition to concentration-based risk assessments, health impact assessments are needed that consider the number of populations exposed. In this study, QGIS was used to calculate population. In conclusion, even if the same LNG power plant is constructed, the LNG cogeneration plant located adjacent to a large residential facility requires air pollutant management measures according to the exposure population by radius of influence</span></span></p><p> </p>


2009 ◽  
Vol 9 (3) ◽  
pp. 865-878 ◽  
Author(s):  
K.-J. Liao ◽  
E. Tagaris ◽  
K. Manomaiphiboon ◽  
C. Wang ◽  
J.-H. Woo ◽  
...  

Abstract. Uncertainties in calculated impacts of climate forecasts on future regional air quality are investigated using downscaled MM5 meteorological fields from the NASA GISS and MIT IGSM global models and the CMAQ model in 2050 in the continental US. Differences between three future scenarios: high-extreme, low-extreme and base case, are used for quantifying effects of climate uncertainty on regional air quality. GISS, with the IPCC A1B scenario, is used for the base case simulations. IGSM results, in the form of probabilistic distributions, are used to perturb the base case climate to provide the high- and low-extreme scenarios. Impacts of the extreme climate scenarios on concentrations of summertime fourth-highest daily maximum 8-h average ozone are predicted to be up to 10 ppbV (about one-seventh of the current US ozone standard of 75 ppbV) in urban areas of the Northeast, Midwest and Texas due to impacts of meteorological changes, especially temperature and humidity, on the photochemistry of tropospheric ozone formation and increases in biogenic VOC emissions, though the differences in average peak ozone concentrations are about 1–2 ppbV on a regional basis. Differences between the extreme and base scenarios in annualized PM2.5 levels are very location dependent and predicted to range between −1.0 and +1.5 μg m−3. Future annualized PM2.5 is less sensitive to the extreme climate scenarios than summertime peak ozone since precipitation scavenging is only slightly affected by the extreme climate scenarios examined. Relative abundances of biogenic VOC and anthropogenic NOx lead to the areas that are most responsive to climate change. Overall, planned controls for decreasing regional ozone and PM2.5 levels will continue to be effective in the future under the extreme climate scenarios. However, the impact of climate uncertainties may be substantial in some urban areas and should be included in assessing future regional air quality and emission control requirements.


2007 ◽  
Vol 46 (2) ◽  
pp. 241-247 ◽  
Author(s):  
Tomohiko Tomita ◽  
Hiroyuki Kusaka ◽  
Ryo Akiyoshi ◽  
Yoshiyuki Imasato

Abstract Gradual cooling in the evening forms a wintertime nocturnal urban heat island. This work, with a mesoscale model involving urban canopy physics, is an examination of how four thermal and geometric controls—anthropogenic heat QF, heat capacity C, thermal conductivity k, and sky-view factor ψs—modify the rate of surface air temperature changes ΔT/Δt. In particular, the time dependence is diagnosed through numerical experiments. The controls QF and k are major agents in the evening, when QF changes the evening ΔT/Δt linearly and k is logarithmic. The effects of C and ψs are large in the morning and in the afternoon with those of k. The impact of QF is, however, substantial only in the evening. Because the time dependence of C and k is different, the thermal inertia used as a parameter in the urban climate studies should be divided into two parameters: C and k. To improve the thermal environment in urban areas, the modification of QF and k could be effective.


Atmosphere ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 504
Author(s):  
Said Munir ◽  
Gulnur Coskuner ◽  
Majeed Jassim ◽  
Yusuf Aina ◽  
Asad Ali ◽  
...  

The COVID-19 pandemic triggered catastrophic impacts on human life, but at the same time demonstrated positive impacts on air quality. In this study, the impact of COVID-19 lockdown interventions on five major air pollutants during the pre-lockdown, lockdown, and post-lockdown periods is analysed in three urban areas in Northern England: Leeds, Sheffield, and Manchester. A Generalised Additive Model (GAM) was implemented to eliminate the effects of meteorological factors from air quality to understand the variations in air pollutant levels exclusively caused by reductions in emissions. Comparison of lockdown with pre-lockdown period exhibited noticeable reductions in concentrations of NO (56.68–74.16%), NO2 (18.06–47.15%), and NOx (35.81–56.52%) for measured data. However, PM10 and PM2.5 levels demonstrated positive gain during lockdown ranging from 21.96–62.00% and 36.24–80.31%, respectively. Comparison of lockdown period with the equivalent period in 2019 also showed reductions in air pollutant concentrations, ranging 43.31–69.75% for NO, 41.52–62.99% for NOx, 37.13–55.54% for NO2, 2.36–19.02% for PM10, and 29.93–40.26% for PM2.5. Back trajectory analysis was performed to show the air mass origin during the pre-lockdown and lockdown periods. Further, the analysis showed a positive association of mobility data with gaseous pollutants and a negative correlation with particulate matter.


2021 ◽  
Author(s):  
Jean-Eudes Petit ◽  
Jean-Charles Dupont ◽  
Olivier Favez ◽  
Valérie Gros ◽  
Yunjiang Zhang ◽  
...  

Abstract. Since early 2020, the COVID-19 pandemic has led to lockdowns at national scales. These lockdowns resulted in large cuts of atmospheric pollutant emissions, notably related to the vehicular traffic source where daily commuting of light-duty vehicles was almost completely stopped in numerous urban areas worldwide, especially during Spring 2020. As a result, air quality changed in manners that are still currently under investigation. Long-term in-situ monitoring of atmospheric composition provides, to this perspective, essential information. However, a robust quantitative assessment of the impact of lockdown measures on ambient concentrations is hindered by weather variability. Basic comparisons with previous years may thus be flawed, especially regarding secondary pollutants, whose concentrations strongly depends on meteorological conditions. In order to circumvent this difficulty, an innovative methodology has been developed. The Analog Application for Air Quality (A3Q) method is based on the comparison of each day of lockdown to a group of analog days having similar meteorological conditions. The A3Q method has been successfully evaluated and applied to a comprehensive in-situ dataset of primary and secondary pollutants obtained at the SIRTA observatory, a suburban background site of the Paris megacity (France). The overall slight decrease of PM1 concentrations (−14 %) compared to business-as-usual conditions conceals contrasting behaviours. Primary traffic tracers (NOx and traffic-related carbonaceous aerosols) dropped by 42–66 % during the lockdown period. Further, the A3Q method enabled us to characterize of changes triggered by NOx decreases. Particulate nitrate and secondary organic aerosols (SOA), two of the main springtime aerosol components in North-Western Europe, decreased by −45 % and −25 %, respectively. A NOx-relationship emphasizes the interest of NOx mitigation policies at the regional (i.e. city) scale, although long-range pollution advection sporadically overcompensated regional decreases. Variations of the oxidation state of SOA suggests discrepancies in SOA formation processes. At the same time, the expected ozone increase (+20 %) underlines the negative feedback of NO titration. These results provide a quasi-comprehensive observation-based insight on mitigation policies regarding air quality in future low-carbon urban areas.


2021 ◽  
Vol 21 (11) ◽  
pp. 8693-8708
Author(s):  
Zhe Jiang ◽  
Hongrong Shi ◽  
Bin Zhao ◽  
Yu Gu ◽  
Yifang Zhu ◽  
...  

Abstract. In response to the coronavirus disease of 2019 (COVID-19), California issued statewide stay-at-home orders, bringing about abrupt and dramatic reductions in air pollutant emissions. This crisis offers us an unprecedented opportunity to evaluate the effectiveness of emission reductions in terms of air quality. Here we use the Weather Research and Forecasting model with Chemistry (WRF-Chem) in combination with surface observations to study the impact of the COVID-19 lockdown measures on air quality in southern California. Based on activity level statistics and satellite observations, we estimate the sectoral emission changes during the lockdown. Due to the reduced emissions, the population-weighted concentrations of fine particulate matter (PM2.5) decrease by 15 % in southern California. The emission reductions contribute 68 % of the PM2.5 concentration decrease before and after the lockdown, while meteorology variations contribute the remaining 32 %. Among all chemical compositions, the PM2.5 concentration decrease due to emission reductions is dominated by nitrate and primary components. For O3 concentrations, the emission reductions cause a decrease in rural areas but an increase in urban areas; the increase can be offset by a 70 % emission reduction in anthropogenic volatile organic compounds (VOCs). These findings suggest that a strengthened control on primary PM2.5 emissions and a well-balanced control on nitrogen oxides and VOC emissions are needed to effectively and sustainably alleviate PM2.5 and O3 pollution in southern California.


2018 ◽  
Vol 373 (1760) ◽  
pp. 20170307 ◽  
Author(s):  
Narcisa Nechita-Banda ◽  
Maarten Krol ◽  
Guido R. van der Werf ◽  
Johannes W. Kaiser ◽  
Sudhanshu Pandey ◽  
...  

Southeast Asia, in particular Indonesia, has periodically struggled with intense fire events. These events convert substantial amounts of carbon stored as peat to atmospheric carbon dioxide (CO 2 ) and significantly affect atmospheric composition on a regional to global scale. During the recent 2015 El Niño event, peat fires led to strong enhancements of carbon monoxide (CO), an air pollutant and well-known tracer for biomass burning. These enhancements were clearly observed from space by the Infrared Atmospheric Sounding Interferometer (IASI) and the Measurements of Pollution in the Troposphere (MOPITT) instruments. We use these satellite observations to estimate CO fire emissions within an inverse modelling framework. We find that the derived CO emissions for each sub-region of Indonesia and Papua are substantially different from emission inventories, highlighting uncertainties in bottom-up estimates. CO fire emissions based on either MOPITT or IASI have a similar spatial pattern and evolution in time, and a 10% uncertainty based on a set of sensitivity tests we performed. Thus, CO satellite data have a high potential to complement existing operational fire emission estimates based on satellite observations of fire counts, fire radiative power and burned area, in better constraining fire occurrence and the associated conversion of peat carbon to atmospheric CO 2 . A total carbon release to the atmosphere of 0.35–0.60 Pg C can be estimated based on our results. This article is part of a discussion meeting issue ‘The impact of the 2015/2016 El Niño on the terrestrial tropical carbon cycle: patterns, mechanisms and implications'.


Atmosphere ◽  
2018 ◽  
Vol 9 (9) ◽  
pp. 345 ◽  
Author(s):  
Shangfei Hai ◽  
Yucong Miao ◽  
Lifang Sheng ◽  
Linbo Wei ◽  
Qing Chen

During the past few decades, rapid economic development occurred in Qingdao. Inevitably, human activities have caused great changes to the underlying surface, including urbanization and coastal change. Coastal change mainly refers to the expansion of the coastline to increase coastal land area. Sea-land breeze (SLB) is important for local weather and the transport of air pollutant. However, the impact of human activities on the SLB over Qingdao is not yet clear. Thus, the weather research and forecasting (WRF) model is applied to study the effect of urbanization and coastal change on SLB. The study shows that urbanization strengthens the urban heat island (UHI) effect. Due to the expansions of urban area during past decades, sea breeze is strengthened before it passes through the urban areas. When it penetrates into the city, the inland progress of sea breeze is slowed down due to the UHI effect and stronger frictional force. Besides, the expansions of coastline can delay the SLB conversion time, lead to the changes in the sea breeze penetration path and the weakening of SLB intensity.


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