scholarly journals Assessing Urban Methane Emissions using Column Observing Portable FTIR Spectrometers and a Novel Bayesian Inversion Framework

2021 ◽  
Author(s):  
Taylor S. Jones ◽  
Jonathan E. Franklin ◽  
Jia Chen ◽  
Florian Dietrich ◽  
Kristian D. Hajny ◽  
...  

Abstract. Cities represent a large and concentrated portion of global greenhouse gas emissions, including methane. Quantifying methane emissions from urban areas is difficult, and inventories made using bottom-up accounting methods often differ greatly from top-down estimates generated from atmospheric observations. Emissions from leaks in natural gas infrastructure are difficult to predict, and are therefore poorly constrained in bottom-up inventories. Natural gas infrastructure leaks and emissions from end uses can be spread throughout the city, and this diffuse source can represent a significant fraction of a city's total emissions. We investigated diffuse methane emissions of the city of Indianapolis, USA during a field campaign in May of 2016. A network of five portable solar-tracking Fourier transform infrared (FTIR) spectrometers was deployed throughout the city. These instruments measure the mole fraction of methane in a total column of air, giving them sensitivity to larger areas of the city than in situ sensors at the surface. We present an innovative inversion method to link these total column concentrations to surface fluxes. This method combines a Lagrangian transport model with a Bayesian inversion framework to estimate surface emissions and their uncertainties, together with determining the concentrations of methane in the air flowing into the city. Variations exceeding 10 ppb were observed in the inflowing air on a typical day, somewhat larger than the enhancements due to urban emissions (

2021 ◽  
Vol 21 (17) ◽  
pp. 13131-13147
Author(s):  
Taylor S. Jones ◽  
Jonathan E. Franklin ◽  
Jia Chen ◽  
Florian Dietrich ◽  
Kristian D. Hajny ◽  
...  

Abstract. Cities represent a large and concentrated portion of global greenhouse gas emissions, including methane. Quantifying methane emissions from urban areas is difficult, and inventories made using bottom-up accounting methods often differ greatly from top-down estimates generated from atmospheric observations. Emissions from leaks in natural gas infrastructure are difficult to predict and are therefore poorly constrained in bottom-up inventories. Natural gas infrastructure leaks and emissions from end uses can be spread throughout the city, and this diffuse source can represent a significant fraction of a city's total emissions. We investigated diffuse methane emissions of the city of Indianapolis, USA, during a field campaign in May 2016. A network of five portable solar-tracking Fourier transform infrared (FTIR) spectrometers was deployed throughout the city. These instruments measure the mole fraction of methane in a total column of air, giving them sensitivity to larger areas of the city than in situ sensors at the surface. We present an innovative inversion method to link these total column concentrations to surface fluxes. This method combines a Lagrangian transport model with a Bayesian inversion framework to estimate surface emissions and their uncertainties, together with determining the concentrations of methane in the air flowing into the city. Variations exceeding 10 ppb were observed in the inflowing air on a typical day, which is somewhat larger than the enhancements due to urban emissions (<5 ppb downwind of the city). We found diffuse methane emissions of 73(±22) mol s−1, which is about 50 % of the urban total and 68 % higher than estimated from bottom-up methods, although it is somewhat smaller than estimates from studies using tower and aircraft observations. The measurement and model techniques developed here address many of the challenges present when quantifying urban greenhouse gas emissions and will help in the design of future measurement schemes in other cities.


2016 ◽  
Vol 16 (6) ◽  
pp. 3683-3710 ◽  
Author(s):  
Stephan Henne ◽  
Dominik Brunner ◽  
Brian Oney ◽  
Markus Leuenberger ◽  
Werner Eugster ◽  
...  

Abstract. Atmospheric inverse modelling has the potential to provide observation-based estimates of greenhouse gas emissions at the country scale, thereby allowing for an independent validation of national emission inventories. Here, we present a regional-scale inverse modelling study to quantify the emissions of methane (CH4) from Switzerland, making use of the newly established CarboCount-CH measurement network and a high-resolution Lagrangian transport model. In our reference inversion, prior emissions were taken from the "bottom-up" Swiss Greenhouse Gas Inventory (SGHGI) as published by the Swiss Federal Office for the Environment in 2014 for the year 2012. Overall we estimate national CH4 emissions to be 196 ± 18 Gg yr−1 for the year 2013 (1σ uncertainty). This result is in close agreement with the recently revised SGHGI estimate of 206 ± 33 Gg yr−1 as reported in 2015 for the year 2012. Results from sensitivity inversions using alternative prior emissions, uncertainty covariance settings, large-scale background mole fractions, two different inverse algorithms (Bayesian and extended Kalman filter), and two different transport models confirm the robustness and independent character of our estimate. According to the latest SGHGI estimate the main CH4 source categories in Switzerland are agriculture (78 %), waste handling (15 %) and natural gas distribution and combustion (6 %). The spatial distribution and seasonal variability of our posterior emissions suggest an overestimation of agricultural CH4 emissions by 10 to 20 % in the most recent SGHGI, which is likely due to an overestimation of emissions from manure handling. Urban areas do not appear as emission hotspots in our posterior results, suggesting that leakages from natural gas distribution are only a minor source of CH4 in Switzerland. This is consistent with rather low emissions of 8.4 Gg yr−1 reported by the SGHGI but inconsistent with the much higher value of 32 Gg yr−1 implied by the EDGARv4.2 inventory for this sector. Increased CH4 emissions (up to 30 % compared to the prior) were deduced for the north-eastern parts of Switzerland. This feature was common to most sensitivity inversions, which is a strong indicator that it is a real feature and not an artefact of the transport model and the inversion system. However, it was not possible to assign an unambiguous source process to the region. The observations of the CarboCount-CH network provided invaluable and independent information for the validation of the national bottom-up inventory. Similar systems need to be sustained to provide independent monitoring of future climate agreements.


2015 ◽  
Vol 15 (24) ◽  
pp. 35417-35484
Author(s):  
S. Henne ◽  
D. Brunner ◽  
B. Oney ◽  
M. Leuenberger ◽  
W. Eugster ◽  
...  

Abstract. Atmospheric inverse modelling has the potential to provide observation-based estimates of greenhouse gas emissions at the country scale, thereby allowing for an independent validation of national emission inventories. Here, we present a regional scale inverse modelling study to quantify the emissions of methane (CH4) from Switzerland, making use of the newly established CarboCount-CH measurement network and a high resolution Lagrangian transport model. Overall we estimate national CH4 emissions to be 196 ± 18 Gg yr−1 for the year 2013 (1σ uncertainty). This result is in close agreement with the recently revised "bottom-up" estimate of 206 ± 33 Gg yr−1 published by the Swiss Federal Office for the Environment as part of the Swiss Greenhouse Gas Inventory (SGHGI). Results from sensitivity inversions using alternative prior emissions, covariance settings, baseline treatments, two different inverse algorithms (Bayesian and extended Kalman Filter), and two different transport models confirms the robustness and independent character of our estimate. According to the latest "bottom-up" inventory the main CH4 source categories in Switzerland are agriculture (78 %), waste handling (15 %) and natural gas distribution and combustion (6 %). The spatial distribution and seasonal variability of our posterior emissions suggest an overestimation of agricultural CH4 emissions by 10 to 20 % in the most recent national inventory, which is likely due to an overestimation of emissions from manure handling. Urban areas do not appear as emission hotspots in our posterior results suggesting that leakages from natural gas disribution are only a minor source of CH4 in Switzerland. This is consistent with rather low emissions of 8.4 Gg yr−1 reported by the SGHGI but inconsistent with the much higher value of 32 Gg yr−1 implied by the EDGARv4.2 inventory for this sector. Increased CH4 emissions (up to 30 % compared to the prior) were deduced for the north-eastern parts of Switzerland. This feature was common to most sensitivity inversions, which rules out an artefact of the transport model and the inversion system. However, it was not possible to assign an unambiguous source process to the region. The observations of the CarboCount-CH network provided invaluable and independent information for the validation of the national bottom-up inventory. Similar systems need to be sustained to provide independent monitoring of future climate agreements.


2021 ◽  
Vol 118 (44) ◽  
pp. e2105804118
Author(s):  
Maryann R. Sargent ◽  
Cody Floerchinger ◽  
Kathryn McKain ◽  
John Budney ◽  
Elaine W. Gottlieb ◽  
...  

Across many cities, estimates of methane emissions from natural gas (NG) distribution and end use based on atmospheric measurements have generally been more than double bottom-up estimates. We present a top-down study of NG methane emissions from the Boston urban region spanning 8 y (2012 to 2020) to assess total emissions, their seasonality, and trends. We used methane and ethane observations from five sites in and around Boston, combined with a high-resolution transport model, to calculate methane emissions of 76 ± 18 Gg/yr, with 49 ± 9 Gg/yr attributed to NG losses. We found no significant trend in the NG loss rate over 8 y, despite efforts from the city and state to increase the rate of repairing NG pipeline leaks. We estimate that 2.5 ± 0.5% of the gas entering the urban region is lost, approximately three times higher than bottom-up estimates. We saw a strong correlation between top-down NG emissions and NG consumed on a seasonal basis. This suggests that consumption-driven losses, such as in transmission or end-use, may be a large component of emissions that is missing from inventories, and require future policy action. We also compared top-down NG emission estimates from six US cities, all of which indicate significant missing sources in bottom-up inventories. Across these cities, we estimate NG losses from distribution and end use amount to 20 to 36% of all losses from the US NG supply chain, with a total loss rate of 3.3 to 4.7% of NG from well pad to urban consumer, notably larger than the current Environmental Protection Agency estimate of 1.4% [R. A. Alvarez et al., Science 361, 186–188 (2018)].


Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1171 ◽  
Author(s):  
Mitja Janža ◽  
Joerg Prestor ◽  
Simona Pestotnik ◽  
Brigita Jamnik

The assurance of drinking water supply is one of the biggest emerging global challenges, especially in urban areas. In this respect, groundwater and its management in the urban environment are gaining importance. This paper presents the modeling of nitrogen load from the leaky sewer system and from agriculture and the impact of this pressure on the groundwater quality (nitrate concentration) in the urban aquifer located beneath the City of Ljubljana. The estimated total nitrogen load in the model area of 58 km2 is 334 ton/year, 38% arising from the leaky sewer system and 62% from agriculture. This load was used as input into the groundwater solute transport model to simulate the distribution of nitrate concentration in the aquifer. The modeled nitrate concentrations at the observation locations were found to be on average slightly lower (2.7 mg/L) than observed, and in general reflected the observed contamination pattern. The ability of the presented model to relate and quantify the impact of pressures from different contamination sources on groundwater quality can be beneficially used for the planning and optimization of groundwater management measures for the improvement of groundwater quality.


2020 ◽  
Author(s):  
Jinghui Lian ◽  
François-Marie Bréon ◽  
Grégoire Broquet ◽  
Bo Zheng ◽  
Michel Ramonet ◽  
...  

Abstract. The top-down atmospheric inversion method that couples atmospheric CO2 observations with an atmospheric transport model has been used extensively to quantify CO2 emissions from cities. However, the potential of the method is limited by several sources of misfits between the measured and modeled CO2 that are of different origins than the targeted CO2 emissions. This study investigates the critical sources of errors that can compromise the estimates of the city-scale emissions and identifies the signal of emissions that has to be filtered when doing inversions. A set of one-year forward simulations is carried out using the WRF-Chem model at a horizontal resolution of 1 km focusing on the Paris area with different anthropogenic emission inventories, physical parameterizations and CO2 boundary conditions. The simulated CO2 concentrations are compared with in situ observations from six continuous monitoring stations located within Paris and its vicinity. Results highlight large nighttime observation-model misfits, especially in winter within the city, which are attributed to large uncertainties in the diurnal profile of anthropogenic emissions as well as to errors in the vertical mixing near the surface in the WRF-Chem model. The nighttime biogenic respiration to the CO2 concentration is a significant source of modeling errors during the growing season outside the city. When winds are from continental Europe and the CO2 concentration of incoming air masses is influenced by remote emissions and large-scale biogenic fluxes, differences in the simulated CO2 induced by the two different boundary conditions (CAMS and CarbonTracker) can be of up to 5 ppm. Our results suggest three selection criteria for the CO2 data to be assimilated for the inversion of CO2 emissions from Paris (i) discard data that appear as statistical outliers in the model-data misfits which are interpreted as model's deficiencies under complex meteorological conditions; (ii) use only afternoon urban measurements in winter and suburban ones in summer; (iii) test the influence of different boundary conditions in inversions. If possible, using additional observations to constrain the boundary inflow, or using CO2 gradients of upwind-downwind stations, rather than absolute CO2 concentration, as atmospheric inversion inputs.


2020 ◽  
Author(s):  
Julianne Fernandez ◽  
James France ◽  
Malika Menoud ◽  
Hossein Maazallahi ◽  
Marius-Paul Corbu ◽  
...  

&lt;p&gt;Romania has a complex geological history resulting in a very hydrocarbon rich region that is heavily exploited and utilised. Romania&amp;#8217;s Fourth Biennial Report under the UNFCCC states that methane (CH&lt;sub&gt;4&lt;/sub&gt;) emissions have decreased by 61% between 1989 and 2017, which is a result of decreases in fugitive fossil fuel and livestock emissions. Although there is a decreasing trend of CH&lt;sub&gt;4&lt;/sub&gt; levels in most of Europe, we still see an overall increase in atmospheric CH&lt;sub&gt;4&lt;/sub&gt; concentrations. As atmospheric CH&lt;sub&gt;4&lt;/sub&gt; continues to increase and the mitigation of greenhouse gases becomes more of a concern, it is important to address CH&lt;sub&gt;4&lt;/sub&gt; emissions from large cities.&amp;#160; Here we ask the question: What are the major sources of urban methane emissions in Romania&amp;#8217;s city capital, Bucharest? Together, street level continuous measurements of CH&lt;sub&gt;4&lt;/sub&gt; and ethane (C&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;6&lt;/sub&gt;), and &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C-CH&lt;sub&gt;4&lt;/sub&gt; &amp; &amp;#948;&lt;sup&gt;2&lt;/sup&gt;H-CH&lt;sub&gt;4&lt;/sub&gt; of high concentration plumes assist in the identification of emissions, both for major point sources and small leaks from the natural gas distribution system.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Urban focused surveys were conducted in Bucharest during August of 2019. Three continuously-measuring instruments were used, including an LGR Ultraportable CH&lt;sub&gt;4&lt;/sub&gt;/C&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;6&lt;/sub&gt; analyzer, allowing for the separation of natural gas leaks from other source category emissions. CH&lt;sub&gt;4&lt;/sub&gt; and C&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;6&lt;/sub&gt; have been mapped to find locations of elevated mixing ratios above background. Air samples were collected from an inlet on the vehicle bumper (60 cm above ground) that is connected to a bag pump, filling 3L Flexfoil bags.&amp;#160; Samples were then analyzed for &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C-CH&lt;sub&gt;4&lt;/sub&gt; &amp; &amp;#948;&lt;sup&gt;2&lt;/sup&gt;H-CH&lt;sub&gt;4&lt;/sub&gt; using an IsoPrime Trace Gas continuous flow gas chromatograph isotope ratio mass spectrometer (CF GC-IRMS) at Royal Holloway, University of London and a Thermo Fisher Delta Plus XP, at Utrecht University. Background baselines of CH&lt;sub&gt;4&lt;/sub&gt; and isotopic ratios were statistically determined while traveling and distinguished from the various plumes of high concentrations. Point source signatures were then calculated using Keeling plot analysis. C&lt;sub&gt;2&lt;/sub&gt;:C&lt;sub&gt;1&lt;/sub&gt; ratios from specific emissions types were compared with the correlated &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C&lt;sub&gt;CH4&lt;/sub&gt; values.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Detailed urban methane mapping and the use of high precision isotopic source signature measurements provide an efficient approach to identifying and sourcing small gas leaks in urban cities. These results will be useful in future government regulation of greenhouse gas emissions in urban areas as the EU continues to work on the reduction of greenhouse gases.&lt;/p&gt;


2003 ◽  
Vol 3 (1) ◽  
pp. 73-88 ◽  
Author(s):  
F. Dentener ◽  
M. van Weele ◽  
M. Krol ◽  
S. Houweling ◽  
P. van Velthoven

Abstract. The trend and interannual variability of methane sources are derived from multi-annual simulations of tropospheric photochemistry using a 3-D global chemistry-transport model. Our semi-inverse analysis uses the fifteen years (1979--1993) re-analysis of ECMWF meteorological data and annually varying emissions including photo-chemistry, in conjunction with observed CH4 concentration distributions and trends derived from the NOAA-CMDL surface stations. Dividing the world in four zonal regions (45--90 N, 0--45 N, 0--45 S, 45--90 S) we find good agreement in each region between (top-down) calculated emission trends from model simulations and (bottom-up) estimated anthropogenic emission trends based on the EDGAR global anthropogenic emission database, which amounts for the period 1979--1993 2.7 Tg CH4 yr-1. Also the top-down determined total global methane emission compares well with the total of the bottom-up estimates. We use the difference between the bottom-up and top-down determined emission trends to calculate residual emissions. These residual emissions represent the inter-annual variability of the methane emissions. Simulations have been performed in which the year-to-year meteorology, the emissions of ozone precursor gases, and the stratospheric ozone column distribution are either varied, or kept constant. In studies of methane trends it is most important to include the trends and variability of the oxidant fields. The analyses reveals that the variability of the emissions is of the order of 8Tg CH4 yr-1, and likely related to wetland emissions and/or biomass burning.


2016 ◽  
Vol 38 ◽  
pp. 84
Author(s):  
Mateus Dias Nunes ◽  
Éricka Voss Chagas Mariano ◽  
Glauber Lopes Mariano

Air pollution is a major environmental problem of today's world. The sulfur dioxide gas (SO2), a pollutant studied both in remote areas as in urban areas, and can be emitted into the atmosphere through natural sources and also by human activities, and its study of great relevance for monitoring problems caused to health of the population, agriculture and economic problems mainly to the population centers of large and medium size. The objective of this study was to determine the variability of the total column of sulfur dioxide into the region of the city of Santiago in Chile using data from the sensor OMI (Ozone Monitoring Instrument) which operates within the range of UV / VIS for the period 2005-2012. Using the daily maximum values of total SO2 column, it was determined the annual and seasonal variability of the total column of sulfur dioxide into the region of Santiago in Chile. The Moving Average for 30 days (MM30) was not a particular seasonality for the period 2005-2012. It was observed increasing values of trend line in the dispersion of the data of the Santiago region.


2020 ◽  
Author(s):  
Michel Ramonet ◽  
Noémie Taquet ◽  
Michel Grutter ◽  

&lt;p&gt;Mexico City (MC) is the home of 21.2M people, 19% of the country's population. The MC urban area has intense emissions of pollutants and greenhouse gases, which accumulate in the overlying air-shed due to the location of the city in a high-altitude basin surrounded by mountains. Local and national authorities have engaged into aggressive emission reduction strategies. The Mexican-French collaborative project, MERCI-CO2, aims to develop atmospheric CO2 measurements that will enable, with the support of atmospheric inversion, to verify the effectiveness of CO2 emission reductions taken by the city authorities. The MERCI-CO2 combines high-precision analysers and low-cost sensors for surface measurements with total column observations up- and down-wind of MC. In addition to the long-term infrastructure currently deployed, an intensive campaign in the spring 2020 will produce an unprecedented data set. For this campaign we will deploy during one month six EM27 spectrometers for total column CO2, CH4 and CO observations; two high-precision analyzer at fixed position and one on board a car for transect measurements; and ten low-cost CO2 sensors which will be setup at air quality stations from the local city network measuring CO, NOx and O3. The dense network will be deployed before, during and after the Eastern vacation period in early April. During this week the traffic, which represents about 70% of CO2 emissions, will be significantly reduced. The atmosphere will be analyzed with a high-resolution transport model to infer the reduction of the surface emissions. This result will be compared to the reduction of the traffic inferred from car counting statistics, and bottom-up estimates. The EM27 instruments will be moved around a large landfill, in order to measure the CH4 enhancement due to this installation, and estimate its emission. The waste sector represent by far the largest CH4 contributor (about 90%) in Mexico, and remains subject to large uncertainties.&lt;/p&gt;


Sign in / Sign up

Export Citation Format

Share Document