Variations of ground-level O<sub>3</sub> and its precursors in Beijing in summertime between 2005 and 2011
Abstract. Increased levels of ground-level ozone (O3), reflecting the oxidative capacity of the atmosphere, are of increasing concern. High levels of total oxidants (Ox = O3 + NO2) have been persistently observed as a feature of Beijing's air pollution. Beijing is a typical global mega-city requiring the enforcement of stringent air quality controls as rapid economic growth continues. To evaluate the effect of air quality controls in recent years, ground-based on-line measurements at an urban site were conducted in summer and the variations in O3 with simultaneous changes in NOx and volatile organic compounds (VOCs) between 2005 and 2011 were analyzed. Both NOx and anthropogenic VOCs in Beijing decreased over the study period, 1.4 ppbv yr−1 and 1.6 ppbv yr−1 respectively, the VOCs reactivity, in term of OH loss rate showed an indistinct statistical trend due to the large contribution from naturally emitted isoprene. Meanwhile, the daytime average O3 concentrations increased significantly at an annual rate 2.6 ppbv yr−1, around 5% yr−1 between 2005 and 2011. Considering the influence of NO titration effect and the increasing in regional background in the North China Plain (NCP), the main reason for such an increase in oxidants was local photochemistry. A simplified model was used to evaluate the effect of changes in the levels of ozone precursors on ozone production, we found that between 2001 and 2006, the production rate of total oxidants, P(Ox) increased rapidly due to increased VOC levels and decreasing of NO2, while from 2006 to2011, P(Ox) remained high though, decreased slightly as a~consequence of the decrease in both VOC reactivity (5% yr−1) and NOx (4% yr−1). Measurements have shown that the air pollution control efforts of Beijing city were effective in cutting ozone precursors, but even led to higher ground-level ozone. Therefore, putting ozone as the target for air quality, a faster reduction of VOCs, especially the reactive VOCs, will be needed to go together with NOx emission control programs.