scholarly journals Direct observation of two dimensional trace gas distribution with an airborne Imaging DOAS instrument

2008 ◽  
Vol 8 (3) ◽  
pp. 11879-11907 ◽  
Author(s):  
K.-P. Heue ◽  
T. Wagner ◽  
S. P. Broccardo ◽  
D. Walter ◽  
S. J. Piketh ◽  
...  
Keyword(s):  
Power Plants ◽  
Trace Gases ◽  
Tropospheric Chemistry ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Small Scale ◽  
Two Dimensional ◽  
Gas Distribution ◽  
Dimensional Distribution ◽  
Airborne Imaging

Abstract. In many investigations of tropospheric chemistry information about the two dimensional distribution of trace gases on a small scale (e.g. tens to hundreds of meters) is highly desirable. An airborne instrument based on imaging Differential Optical Absorption Spectroscopy has been built to map the 2-D distribution of a series of relevant trace gases including NO2, HCHO, C2H2O2, H2O, O4, SO2, and BrO on a scale of 100 m. Here we report on the first tests of the novel aircraft instrument over the industrialised South African Highveld, where large variations in NO2 column densities in the immediate vicinity of several sources e.g. power plants or steel works, were measured. The observed patterns in the trace gas distribution are interpreted with respect to flux estimates, and it is seen that the fine resolution of the measurements allows separate sources in close proximity to one another to be distinguished.

scholarly journals Direct observation of two dimensional trace gas distributions with an airborne Imaging DOAS instrument

2008 ◽  
Vol 8 (22) ◽  
pp. 6707-6717 ◽  
Author(s):  
K.-P. Heue ◽  
T. Wagner ◽  
S. P. Broccardo ◽  
D. Walter ◽  
S. J. Piketh ◽  
...  
Keyword(s):  
Power Plants ◽  
Trace Gases ◽  
Tropospheric Chemistry ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Small Scale ◽  
Two Dimensional ◽  
Dimensional Distribution ◽  
Airborne Imaging ◽  
Fine Resolution

Abstract. In many investigations of tropospheric chemistry information about the two dimensional distribution of trace gases on a small scale (e.g. tens to hundreds of metres) is highly desirable. An airborne instrument based on imaging Differential Optical Absorption Spectroscopy has been built to map the two dimensional distribution of a series of relevant trace gases including NO2, HCHO, C2H2O2, H2O, O4, SO2, and BrO on a scale of 100 m. Here we report on the first tests of the novel aircraft instrument over the industrialised South African Highveld, where large variations in NO2 column densities in the immediate vicinity of several sources e.g. power plants or steel works, were measured. The observed patterns in the trace gas distribution are interpreted with respect to flux estimates, and it is seen that the fine resolution of the measurements allows separate sources in close proximity to one another to be distinguished.

3D Remote Sensing of Trace Gas Distributions with HAIDI (Heidelberg Airborne Imaging DOAS Instrument) - Power Plant and Ship Emissions observed during the EMeRGe Campaigns

2021 ◽  
Author(s):  
Katja Bigge ◽  
Udo Frieß ◽  
Denis Pöhler ◽  
Ulrich Platt
Keyword(s):  
Remote Sensing ◽  
Radiative Transfer ◽  
Power Plants ◽  
Trace Gases ◽  
Trace Gas ◽  
Radiative Transfer Model ◽  
Optical Absorption Spectroscopy ◽  
Transfer Model ◽  
Flight Altitude ◽  
Airborne Imaging

<p><span>Compared to ground-based or satellite measurements, atmospheric observations based on aircraft missions have many advantages, such as the potential to observe a large atmospheric volume using remote sensing measurements, among which Differential Optical Absorption Spectroscopy (DOAS) is a well established method for the observation of integrated trace gas concentrations along the light path. However, the interpretation of remote spectroscopic measurements using scattered sunlight is complicated due to the lack of prior knowledge on the light paths between sun and detector, and thus on the observed air volume. Using radiative transfer calculations, quantities commonly derived from DOAS measurements are integrated vertical columns of various trace gases, providing no information about their vertical distribution.</span></p><p><span>On the ground, tomographic approaches have been used to reconstruct the spatial distribution of trace gases by using multiple viewing directions and detectors. <!-- Bislang eigentlich höchstens 2D (Pöhler et al) oder 1D (MAX-DOAS Profil-retrieval) -->HAIDI, the Heidelberg Airborne Imaging DOAS Instrument, was designed to transfer this concept to the air. In addition to its excellent temporal and spatial resolution (40 m x 40 m at 1.5 km flight altitude, 266 m x 266 m at 10 km flight altitude, at 10 ms temporal resolution), HAIDI uses three separate scanning telescopes aimed at +/-45° forward- and backward looking angles and the nadir direction. In combination with a 3D radiative transfer model, this allows a reconstruction of the 3D distribution of the detected trace gases in the vicinity of the flight track.</span></p><p><span>HAIDI joined the EMerGe (Effect of Megacities on the Transport and transformation of Pollutants on the Regional to Global Scales) missions on HALO, the High Altitude and LOng range research aircraft based at DLR (German Aerospace Center) in Oberpfaffenhofen, Germany. The EMerGe missions targeted the emission outflows of megacities to investigate their compositions and the atmospheric impact of urban pollution in Europe (July 2017) and Asia (March 2018). HAIDI observed a number of trace gases such as NO<sub>2,</sub> SO<sub>2</sub> and HCHO. For NO<sub>2</sub> and SO<sub>2</sub> in particular, strong plumes originating from power plants and ships were found, which were then used for inversion of the 3D distribution of the plume and emission estimation. Here we present the method and results of the HAIDI measurements during the EMeRGe missions.</span></p>

scholarly journals The Heidelberg Airborne Imaging DOAS Instrument (HAIDI) – a novel imaging DOAS device for 2-D and 3-D imaging of trace gases and aerosols

2014 ◽  
Vol 7 (10) ◽  
pp. 3459-3485 ◽  
Author(s):  
S. General ◽  
D. Pöhler ◽  
H. Sihler ◽  
N. Bobrowski ◽  
U. Frieß ◽  
...  
Keyword(s):  
Trace Gases ◽  
Tropospheric Chemistry ◽  
Optical Absorption Spectroscopy ◽  
Sources And Sinks ◽  
Volcanic Plumes ◽  
New Instrument ◽  
First Results ◽  
Mt Etna ◽  
Airborne Imaging ◽  
Ccd Detectors

Abstract. Many relevant processes in tropospheric chemistry take place on rather small scales (e.g., tens to hundreds of meters) but often influence areas of several square kilometer. Thus, measurements of the involved trace gases with high spatial resolution are of great scientific interest. In order to identify individual sources and sinks and ultimately to improve chemical transport models, we developed a new airborne instrument, which is based on the well established Differential Optical Absorption Spectroscopy (DOAS) method. The Heidelberg Airborne Imaging DOAS Instrument (HAIDI) is a passive imaging DOAS spectrometer, which is capable of recording horizontal and vertical trace gas distributions with a resolution of better than 100 m. Observable species include NO2, HCHO, C2H2O2, H2O, O3, O4, SO2, IO, OClO and BrO. Here we give a technical description of the instrument including its custom-built spectrographs and CCD detectors. Also first results from measurements with the new instrument are presented. These comprise spatial resolved SO2 and BrO in volcanic plumes, mapped at Mt. Etna (Sicily, Italy), NO2 emissions in the metropolitan area of Indianapolis (Indiana, USA) as well as BrO and NO2 distributions measured during arctic springtime in context of the BRomine, Ozone, and Mercury EXperiment (BROMEX) campaign, which was performed 2012 in Barrow (Alaska, USA).

scholarly journals A wide field-of-view imaging DOAS instrument for two-dimensional trace gas mapping from aircraft

2015 ◽  
Vol 8 (12) ◽  
pp. 5113-5131 ◽  
Author(s):  
A. Schönhardt ◽  
P. Altube ◽  
K. Gerilowski ◽  
S. Krautwurst ◽  
J. Hartmann ◽  
...  
Keyword(s):  
Spatial Resolution ◽  
Point Sources ◽  
West Germany ◽  
Field Of View ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Small Scale ◽  
Wide Field ◽  
Flight Altitude ◽  
Good Imaging

Abstract. The Airborne imaging differential optical absorption spectroscopy (DOAS) instrument for Measurements of Atmospheric Pollution (AirMAP) has been developed for the purpose of trace gas measurements and pollution mapping. The instrument has been characterized and successfully operated from aircraft. Nitrogen dioxide (NO2) columns were retrieved from the AirMAP observations. A major benefit of the push-broom imaging instrument is the spatially continuous, gap-free measurement sequence independent of flight altitude, a valuable characteristic for mapping purposes. This is made possible by the use of a charge coupled device (CCD) frame-transfer detector. A broad field of view across track of around 48° is achieved with wide-angle entrance optics. This leads to a swath width of about the same size as the flight altitude. The use of fibre coupled light intake optics with sorted light fibres allows flexible instrument positioning within the aircraft and retains the very good imaging capabilities. The measurements yield ground spatial resolutions below 100 m depending on flight altitude. The number of viewing directions is chosen from a maximum of 35 individual viewing directions (lines of sight, LOS) represented by 35 individual fibres. The selection is adapted to each situation by averaging according to signal-to-noise or spatial resolution requirements. Observations at 30 m spatial resolution are obtained when flying at 1000 m altitude and making use of all 35 viewing directions. This makes the instrument a suitable tool for mapping trace gas point sources and small-scale variability. The position and aircraft attitude are taken into account for accurate spatial mapping using the Attitude and Heading Reference System of the aircraft. A first demonstration mission using AirMAP was undertaken in June 2011. AirMAP was operated on the AWI Polar-5 aircraft in the framework of the AIRMETH-2011 campaign. During a flight above a medium-sized coal-fired power plant in north-west Germany, AirMAP clearly detected the emission plume downwind from the exhaust stack, with NO2 vertical columns around 2 × 1016 molecules cm−2 in the plume centre. NOx emissions estimated from the AirMAP observations are consistent with reports in the European Pollutant Release and Transfer Register. Strong spatial gradients and variability in NO2 amounts across and along flight direction are observed, and small-scale enhancements of NO2 above a motorway are detected.

scholarly journals MAX-DOAS measurements of NO<sub>2</sub>, SO<sub>2</sub>, HCHO, and BrO at the Mt. Waliguan WMO GAW global baseline station in the Tibetan Plateau

2020 ◽  
Vol 20 (11) ◽  
pp. 6973-6990 ◽  
Author(s):  
Jianzhong Ma ◽  
Steffen Dörner ◽  
Sebastian Donner ◽  
Junli Jin ◽  
Siyang Cheng ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Trace Gases ◽  
Elevation Angle ◽  
Lower Troposphere ◽  
Statistical Error ◽  
Tropospheric Chemistry ◽  
Ozone Production ◽  
Optical Absorption Spectroscopy ◽  
The Tibetan Plateau ◽  
Mixing Ratios

Abstract. Mt. Waliguan Observatory (WLG) is a World Meteorological Organization (WMO) Global Atmosphere Watch (GAW) global baseline station in China. WLG is located at the northeastern part of the Tibetan Plateau (36∘17′ N, 100∘54′ E, 3816 m a.s.l.) and is representative of the pristine atmosphere over the Eurasian continent. We made long-term ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements at WLG during the period 2012–2015. In this study, we retrieve the differential slant column densities (dSCDs) and estimate the tropospheric background mixing ratios of different trace gases, including NO2, SO2, HCHO, and BrO, using the measured spectra at WLG. Averaging of 10 original spectra is found to be an “optimum option” for reducing both the statistical error of the spectral retrieval and systematic errors in the analysis. The dSCDs of NO2, SO2, HCHO, and BrO under clear-sky and low-aerosol-load conditions are extracted from measured spectra at different elevation angles at WLG. By performing radiative transfer simulations with the model TRACY-2, we establish approximate relationships between the trace gas dSCDs at 1∘ elevation angle and the corresponding average tropospheric background volume mixing ratios. Mixing ratios of these trace gases in the lower troposphere over WLG are estimated to be in a range of about 7 ppt (January) to 100 ppt (May) for NO2, below 0.5 ppb for SO2, between 0.4 and 0.9 ppb for HCHO, and lower than 0.3 ppt for BrO. The chemical box model simulations constrained by the NO2 concentration from our MAX-DOAS measurements show that there is a little net ozone loss (−0.8 ppb d−1) for the free-tropospheric conditions and a little net ozone production (0.3 ppb d−1) for the boundary layer conditions over WLG during summertime. Our study provides valuable information and data sets for further investigating tropospheric chemistry in the background atmosphere and its links to anthropogenic activities.

scholarly journals Determination of an effective trace gas mixing height by differential optical absorption spectroscopy (DOAS)

2009 ◽  
Vol 2 (4) ◽  
pp. 1663-1692 ◽  
Author(s):  
B. Zhou ◽  
S. N. Yang ◽  
S. S. Wang ◽  
T. Wagner
Keyword(s):  
Trace Gases ◽  
Mixing Layer ◽  
Correlation Coefficients ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Gas Mixing ◽  
Mixing Height ◽  
Free Atmosphere ◽  
Layer Height

Abstract. A new method for the determination of the Mixing layer Height (MH) by the DOAS technique is proposed in this article. The MH can be retrieved by a combination of active DOAS and passive DOAS observations of atmospheric trace gases; here we focus on observations of NO2. Because our observations are sensitive to the vertical distribution of trace gases, we refer to the retrieved layer height as an ''effective trace gas mixing height'' (ETMH). By analyzing trace gas observations in Shanghai over one year (1017 hourly means in 93 days in 2007), the retrieved ETMH was found to range between 0.1 km and 2.8 km (average is 0.78 km); more than 90% of the measurements yield an ETMH between 0.2 km and 2.0 km. The seasonal and diurnal variation of the ETMH shows good agreement with mixing layer heights derived from meteorological observations. We investigated the relationship of the derived ETMH to temperature and wind speed and found correlation coefficients of 0.65 and 0.37, respectively. Also the wind direction has an impact on the measurement to some extent. Especially in cases when the air flow comes from highly polluted areas and the atmospheric lifetime of NO2 is long (e.g. in winter), the NO2 concentration at high altitudes over the measurement site can be enhanced, which leads to an overestimation of the ETMH. Enhanced NO2 concentrations in the free atmosphere and heterogeneity within the mixing layer can cause additional uncertainties. Our method could be easily extended to other species like e.g. SO2, HCHO or Glyoxal. Simultaneous studies of these molecules could yield valuable information on their respective atmospheric lifetimes.

scholarly journals Detection of O<sub>4</sub> absorption around 328 nm and 419 nm in measured atmospheric absorption spectra

2017 ◽  
Author(s):  
Johannes Lampel ◽  
Johannes Zielcke ◽  
Stefan Schmitt ◽  
Denis Pöhler ◽  
Udo Frieß ◽  
...  
Keyword(s):  
Optical Absorption ◽  
Spectral Data ◽  
Cross Section ◽  
Cross Sections ◽  
Trace Gases ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Absorption Cross ◽  
Peak Absorption ◽  
Spectrally Resolved

Abstract. Retrieving the column of an absorbing trace gas from spectral data requires that all absorbers in the corresponding wavelength range are sufficiently well known. This is especially important for the retrieval of weak absorbers, whose absorptions are often in the 10-4 range. Previous publications on the absorptions of the oxygen dimer O2-O2 (or short: O4) list absorption peaks at 328 nm and 419 nm, for which no spectrally resolved literature cross-sections are available. As these absorptions potentially influence the spectral retrieval of various trace gases, such as HCHO, BrO, OClO and IO, their shape and magnitude needs to be quantified. We assume that the shape of the absorption peaks at 328 nm and 419 nm can be approximated by their respective neighboring absorption peaks. Using this approach we obtain estimates for the wavelength of the absorption and its magnitude. Using Longpath Differential Optical Absorption Spectroscopy (LP-DOAS) observations and Multi-Axis (MAX)-DOAS observations, we estimate the peak absorption cross-sections of O4 to be (1.7 ± 0.2) x 10-47 cm5 molec-2 and determine the wavelength of its maximum at 328.51 ± 0.15 nm. For the absorption at 419.0 ± 0.4 nm a peak O4 cross-section value is determined as (3.7 ± 2.7) x 10-48 cm5 molec-2.

Long-term MAX-DOAS measurements of formaldehyde in the suburban area of London 

2021 ◽  
Author(s):  
Sebastian Donner ◽  
Steffen Dörner ◽  
Joelle Buxmann ◽  
Steffen Beirle ◽  
David Campbell ◽  
...  
Keyword(s):  
Trace Gases ◽  
Lower Troposphere ◽  
Anthropogenic Pollution ◽  
Tropospheric Chemistry ◽  
Atmospheric Composition ◽  
Optical Absorption Spectroscopy ◽  
Vertical Column ◽  
Pollution Levels ◽  
Measurement Site ◽  
Prevailing Wind Direction

&lt;p&gt;Multi-AXis (MAX)-Differential Optical Absorption Spectroscopy (DOAS) instruments record spectra of scattered sun light under different elevation angles. From such measurements tropospheric vertical column densities (VCDs) and vertical profiles of different atmospheric trace gases and aerosols can be determined for the lower troposphere. These measurements allow a simultaneous observation of multiple trace gases, e.g. formaldehyde (HCHO), glyoxal (CHOCHO) and nitrogen dioxide (NO&lt;sub&gt;2&lt;/sub&gt;), with the same measurement setup. Since November 2018, a MAX-DOAS instrument has been operating at Bayfordbury Observatory, which is located approximately 30 km north of London. This measurement site is operated by the University of Hertfordshire and equipped with an AERONET station, a LIDAR and multiple instruments to measure meteorological quantities and solar radiation. Depending on the prevailing wind direction the air masses at the measurement site can be dominated by the pollution of London (SE to SW winds) or rather pristine air (northerly winds).&lt;/p&gt;&lt;p&gt;First results already showed that the highest formaldehyde and glyoxal columns are observed for southerly to southeasterly winds indicating the influence of the anthropogenic emissions of London. However, the detailed patterns of the different trace gases were found to be more complex. Therefore, this measurement site is well suited to study the influence of anthropogenic pollution on the atmospheric composition and chemistry at a rather pristine location in the vicinity of London, a major European capital with about 10 million inhabitants and 4 major international airports.&lt;/p&gt;&lt;p&gt;In this study, trace gas and aerosol profiles are retrieved using the MAinz Profile Algorithm (MAPA) with a focus on tropospheric HCHO which plays an important role in tropospheric chemistry. The HCHO results are combined with the results of other trace species such as NO&lt;sub&gt;2&lt;/sub&gt;, CHOCHO and aerosols in order to identify pollution levels, emission sources and different chemical regimes.&lt;/p&gt;

scholarly journals Detection of O<sub>4</sub> absorption around 328 and 419 nm in measured atmospheric absorption spectra

2018 ◽  
Vol 18 (3) ◽  
pp. 1671-1683 ◽  
Author(s):  
Johannes Lampel ◽  
Johannes Zielcke ◽  
Stefan Schmitt ◽  
Denis Pöhler ◽  
Udo Frieß ◽  
...  
Keyword(s):  
Optical Absorption ◽  
Spectral Data ◽  
Cross Section ◽  
Cross Sections ◽  
Trace Gases ◽  
Trace Gas ◽  
Optical Absorption Spectroscopy ◽  
Absorption Cross ◽  
Peak Absorption ◽  
Spectrally Resolved

Abstract. Retrieving the column of an absorbing trace gas from spectral data requires that all absorbers in the corresponding wavelength range are sufficiently well known. This is especially important for the retrieval of weak absorbers, whose absorptions are often in the 10−4 range. Previous publications on the absorptions of the oxygen dimer O2–O2 (or short: O4) list absorption peaks at 328 and 419 nm, for which no spectrally resolved literature cross sections are available. As these absorptions potentially influence the spectral retrieval of various trace gases, such as HCHO, BrO, OClO and IO, their shape and magnitude need to be quantified. We assume that the shape of the absorption peaks at 328 and 419 nm can be approximated by their respective neighbouring absorption peaks. Using this approach we obtain estimates for the wavelength of the absorption and its magnitude. Using long-path differential optical absorption spectroscopy (LP-DOAS) observations and multi-axis DOAS (MAX-DOAS) observations, we estimate the peak absorption cross sections of O4 to be (1.96  ±  0.20) × 10−47 cm5 molec−2 and determine the wavelength of its maximum at 328.59  ±  0.15 nm. For the absorption at 419.13  ±  0.42 nm a peak O4 cross-section value is determined to be (5.0  ±  3.5) × 10−48 cm5 molec−2.

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