scholarly journals Accurate measurements of atmospheric carbon dioxide and methane mole fractions at the Siberian coastal site Ambarchik

2019 ◽  
Vol 12 (11) ◽  
pp. 5717-5740
Author(s):  
Friedemann Reum ◽  
Mathias Göckede ◽  
Jost V. Lavric ◽  
Olaf Kolle ◽  
Sergey Zimov ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Arctic Ocean ◽  
Atmospheric Carbon Dioxide ◽  
Monitoring Network ◽  
The Arctic ◽  
Data Quality Control ◽  
In Situ Data ◽  
The Arctic Ocean ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2

Abstract. Sparse data coverage in the Arctic hampers our understanding of its carbon cycle dynamics and our predictions of the fate of its vast carbon reservoirs in a changing climate. In this paper, we present accurate measurements of atmospheric carbon dioxide (CO2) and methane (CH4) dry air mole fractions at the new atmospheric carbon observation station Ambarchik, which closes a large gap in the atmospheric trace gas monitoring network in northeastern Siberia. The site, which has been operational since August 2014, is located near the delta of the Kolyma River at the coast of the Arctic Ocean. Data quality control of CO2 and CH4 measurements includes frequent calibrations traced to World Meteorological Organization (WMO) scales, employment of a novel water vapor correction, an algorithm to detect the influence of local polluters, and meteorological measurements that enable data selection. The available CO2 and CH4 record was characterized in comparison with in situ data from Barrow, Alaska. A footprint analysis reveals that the station is sensitive to signals from the East Siberian Sea, as well as the northeast Siberian tundra and taiga regions. This makes data from Ambarchik highly valuable for inverse modeling studies aimed at constraining carbon budgets within the pan-Arctic domain, as well as for regional studies focusing on Siberia and the adjacent shelf areas of the Arctic Ocean.

scholarly journals Accurate measurements of atmospheric carbon dioxide and methane mole fractions at the Siberian coastal site Ambarchik

2018 ◽  
Author(s):  
Friedemann Reum ◽  
Mathias Göckede ◽  
Jost V. Lavric ◽  
Olaf Kolle ◽  
Sergey Zimov ◽  
...  
Keyword(s):  
Arctic Ocean ◽  
Atmospheric Carbon Dioxide ◽  
Monitoring Network ◽  
The Arctic ◽  
Data Quality Control ◽  
In Situ Data ◽  
Northeastern Siberia ◽  
East Siberian Sea ◽  
The Arctic Ocean ◽  
Atmospheric Carbon

Abstract. Sparse data coverage in the Arctic hampers our understanding of its carbon cycle dynamics and our predictions of the fate of its vast carbon reservoirs in a changing climate. In this paper, we present accurate measurements of atmospheric CO2 and CH4 dry air mole fractions at the new atmospheric carbon observation station Ambarchik, which closes a large gap in the atmospheric trace gas monitoring network in northeastern Siberia. The site, operational since August 2014, is located near the delta of the Kolyma River at the coast of the Arctic Ocean. Data quality control of CO2 and CH4 measurements includes frequent calibrations traced to WMO scales, employment of a novel water vapor correction, an algorithm to detect influence of local polluters, and meteorological measurements that enable data selection. The available CO2 and CH4 record was characterized in comparison with in situ data from Barrow, Alaska. A footprint analysis reveals that the station is sensitive to signals from the East Siberian Sea, as well as northeast Siberian tundra and taiga regions. This makes data from Ambarchik highly valuable for inverse modeling studies aimed at constraining carbon budgets within the pan-Arctic domain, as well as for regional studies focusing on Siberia and the adjacent shelf areas of the Arctic Ocean.

scholarly journals Using airborne HIAPER Pole-to-Pole Observations (HIPPO) to evaluate model and remote sensing estimates of atmospheric carbon dioxide

2016 ◽  
Author(s):  
C. Frankenberg ◽  
S. S. Kulawik ◽  
S. Wofsy ◽  
F. Chevallier ◽  
B. Daube ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Atmospheric Carbon Dioxide ◽  
Correlation Coefficients ◽  
Added Value ◽  
Total Carbon ◽  
Accuracy And Precision ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2 ◽  
Global Carbon ◽  
Comparable Quality

Abstract. In recent years, space-borne observations of atmospheric carbon-dioxide (CO2) have become increasingly used in global carbon-cycle studies. In order to obtain added value from space-borne measurements, they have to suffice stringent accuracy and precision requirements, with the latter being less crucial as it can be reduced by just enhanced sample size. Validation of CO2 column averaged dry air mole fractions (XCO2) heavily relies on measurements of the Total Carbon Column Observing Network TCCON. Owing to the sparseness of the network and the requirements imposed on space-based measurements, independent additional validation is highly valuable. Here, we use observations from the HIAPER Pole-to-Pole Observations (HIPPO) flights from January 2009 through September 2011 to validate CO2 measurements from satellites (GOSAT, TES, AIRS) and atmospheric inversion models (CarbonTracker CT2013B, MACC v13r1). We find that the atmospheric models capture the XCO2 variability observed in HIPPO flights very well, with correlation coefficients (r2) of 0.93 and 0.95 for CT2013B and MACC, respectively. Some larger discrepancies can be observed in profile comparisons at higher latitudes, esp. at 300 hPa during the peaks of either carbon uptake or release. These deviations can be up to 4 ppm and hint at misrepresentation of vertical transport. Comparisons with the GOSAT satellite are of comparable quality, with an r2 of 0.85, a mean bias μ of −0.06 ppm and a standard deviation σ of 0.45 ppm. TES exhibits an r2 of 0.75, μ of 0.34 ppm and σ of 1.13 ppm. For AIRS, we find an r2 of 0.37, μ of 1.11 ppm and σ of 1.46 ppm, with latitude-dependent biases. For these comparisons at least 6, 20 and 50 atmospheric soundings have been averaged for GOSAT, TES and AIRS, respectively. Overall, we find that GOSAT soundings over the remote pacific ocean mostly meet the stringent accuracy requirements of about 0.5 ppm for space-based CO2 observations.

scholarly journals Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

2014 ◽  
Vol 7 (8) ◽  
pp. 8101-8123
Author(s):  
B. Xiang ◽  
D. D. Nelson ◽  
J. B. McManus ◽  
M. S. Zahniser ◽  
R. Wehr ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Field Test ◽  
Atmospheric Carbon Dioxide ◽  
Field Measurements ◽  
Field Testing ◽  
Thermal Control ◽  
Long Term Ecological Research ◽  
Calibration Protocol ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2

Abstract. We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermal control of the optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for eight months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of another commercially available cavity ring-down CO2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of calibration cylinders.

scholarly journals Assessment of recent advances in measurement techniques for atmospheric carbon dioxide and methane observations

2016 ◽  
Vol 9 (9) ◽  
pp. 4737-4757 ◽  
Author(s):  
Christoph Zellweger ◽  
Lukas Emmenegger ◽  
Mohd Firdaus ◽  
Juha Hatakka ◽  
Martin Heimann ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Atmospheric Carbon Dioxide ◽  
Measurement Techniques ◽  
Spectroscopic Techniques ◽  
Cavity Output ◽  
The World ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2 ◽  
Improved Accuracy ◽  
Flame Ionisation

Abstract. Until recently, atmospheric carbon dioxide (CO2) and methane (CH4) measurements were made almost exclusively using nondispersive infrared (NDIR) absorption and gas chromatography with flame ionisation detection (GC/FID) techniques, respectively. Recently, commercially available instruments based on spectroscopic techniques such as cavity ring-down spectroscopy (CRDS), off-axis integrated cavity output spectroscopy (OA-ICOS) and Fourier transform infrared (FTIR) spectroscopy have become more widely available and affordable. This resulted in a widespread use of these techniques at many measurement stations. This paper is focused on the comparison between a CRDS "travelling instrument" that has been used during performance audits within the Global Atmosphere Watch (GAW) programme of the World Meteorological Organization (WMO) with instruments incorporating other, more traditional techniques for measuring CO2 and CH4 (NDIR and GC/FID). We demonstrate that CRDS instruments and likely other spectroscopic techniques are suitable for WMO/GAW stations and allow a smooth continuation of historic CO2 and CH4 time series. Moreover, the analysis of the audit results indicates that the spectroscopic techniques have a number of advantages over the traditional methods which will lead to the improved accuracy of atmospheric CO2 and CH4 measurements.

scholarly journals Preservation of terrestrial organic carbon in marine sediments off shore Taiwan: mountain building and atmospheric carbon dioxide sequestration

2013 ◽  
Vol 1 (1) ◽  
pp. 177-206
Author(s):  
S.-J. Kao ◽  
R. G. Hilton ◽  
K. Selvaraj ◽  
M. Dai ◽  
F. Zehetner ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Organic Carbon ◽  
Marine Sediments ◽  
Atmospheric Carbon Dioxide ◽  
Climatic Variability ◽  
Deep Ocean ◽  
Sediment Traps ◽  
Terrestrial Biosphere ◽  
Atmospheric Carbon ◽  
Carbon Dioxide Co2

Abstract. Geological sequestration of atmospheric carbon dioxide (CO2) can be achieved by the erosion of organic carbon (OC) from the terrestrial biosphere and its burial in long-lived marine sediments. Rivers on mountain islands of Oceania in the western Pacific have very high rates of OC export to the ocean, yet its preservation offshore remains poorly constrained. Here we use the OC content (Corg, %), radiocarbon (Δ14Corg) and stable isotope (δ13Corg) composition of sediments offshore Taiwan to assess the fate of terrestrial OC. We account for rock-derived fossil OC to assess the preservation of OC eroded from the terrestrial biosphere (non-fossil OC) during flood discharges (hyperpycnal river plumes) and when river inputs are dispersed more widely (hypopycnal). The Corg, Δ14Corg and δ13Corg of marine sediment traps and cores indicate that during flood discharges, terrestrial OC is transferred efficiently to the deep ocean and accumulates offshore with little evidence for terrestrial OC loss. In marine sediments fed by dispersive river inputs, the Corg, Δ14Corg and δ13Corg are consistent with mixing of marine OC and terrestrial OC and suggest that efficient preservation of terrestrial OC (> 70%) is also associated with hypopycnal delivery. Re-burial of fossil OC is pervasive. Our findings from Taiwan suggest that erosion and marine burial of terrestrial non-fossil OC may sequester > 8 TgC yr−1 across Oceania, a significant geological CO2 sink which requires better constraint. We postulate that mountain islands of Oceania provide strong link between tectonic uplift and the carbon cycle, one moderated by the climatic variability that controls terrestrial OC delivery to the ocean.

Sediment transport to the Arctic Ocean and adjoining cold oceans*

2006 ◽  
Vol 37 (4-5) ◽  
pp. 413-432 ◽  
Author(s):  
Bent Hasholt ◽  
Nelly Bobrovitskaya ◽  
Jim Bogen ◽  
James McNamara ◽  
Sebastian H. Mernild ◽  
...  
Keyword(s):  
Sediment Transport ◽  
Arctic Ocean ◽  
Monitoring Network ◽  
High Arctic ◽  
Sediment Flux ◽  
The Arctic ◽  
Sediment Loads ◽  
The Arctic Ocean ◽  
Available Information ◽  
Total Sediment

This paper reviews and synthesises available information on sediment transport to the Arctic Ocean and adjoining seas with open contact to the Atlantic and Pacific Oceans. Special emphasis is placed on calculation and estimation of the sediment flux from the mostly ungauged high Arctic areas on the American continent, in Greenland, and on islands in the Arctic Ocean, and from Russia. In the absence of reliable information on bedload fluxes for most rivers, attention is directed primarily to suspended sediment loads. By combining available monitoring data and estimates for ungauged areas, the total sediment transport to the Arctic Ocean is estimated to be 324–884 × 106 t yr−1. Of this total, a maximum of about 56% can be considered as monitored, while the rest is based on different types of estimate. It is clearly demonstrated that the monitoring network in the high Arctic is inadequate and that there is a lack of knowledge concerning the proportion of the load that actually reaches the sea, as well as bedload.

Seasonal methane and carbon dioxide emissions from the coastal nearshore of the Kolyma river, Siberia.

2021 ◽  
Author(s):  
Juri Palmtag ◽  
Cara Manning ◽  
Michael Bedington ◽  
Matthias Fuchs ◽  
Mathias Göckede ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Arctic Ocean ◽  
Carbon Dioxide Emissions ◽  
Open Water ◽  
The Arctic ◽  
Global Ocean ◽  
Nearshore Zone ◽  
Terrestrial Organic Matter ◽  
The Arctic Ocean ◽  
Kolyma River

<p>Arctic rivers deliver ≈11% of global river discharge into the Arctic Ocean, while this ocean represents only ≈1% of the global ocean volume. Ongoing climate warming across the Arctic, and specifically Siberia, has led to regional-scale changes in precipitation patterns, greater rates of permafrost thaw and active layer deepening, as well as enhanced riverbank and coastal erosion. Combined, these climatic and cryospheric perturbations have already resulted in increased freshwater discharge and changes to constituent loads (e.g. dissolved organic carbon - OC) supplied from land to the Arctic Ocean.</p><p>To date, the majority of studies examining terrestrial organic matter (OM) delivery to the Arctic Ocean have focused almost entirely on freshwater (riverine) or fully-marine environments and been conducted during late summer seasons – often due to logistical constraints. Despite this, an improved understanding of how OC is transformed, mineralised and released during transit through the highly reactive nearshore estuarine environment is critical for examining the fate and influence of terrestrial OM on the Arctic Ocean. Capturing seasonality over the open water period is also necessary to identify current OM fluxes to the ocean vs the atmosphere, and aid in constraining how future changes may modify them.</p><p>Here we focus upon carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>) measurements collected during six repeated transects of the Kolyma River and nearshore zone (covering ~120 km) from 2019. Transects spanned almost the entirety of the riverine open water season (June to September). We use these results, in parallel with gas concentrations derived from prior studies, to develop and validate a simple box-model of gas emissions from the nearshore zone.</p><p>Observations and model‐derived output data reveal that more than 50% of the cumulative gross delivery of CH<sub>4</sub> and CO<sub>2</sub> to the coastal ocean occurred during the freshet period with dissolved CH<sub>4</sub> concentrations in surface water reaching 660 Nanomole per liter [nmol/l]. These results demonstrate the relevance of seasonal dynamics and its spatial variability which are needed in order to estimate greenhouse gas fluxes on an annual basis.</p><p>More accurate understanding of land-ocean carbon fluxes in the Arctic is therefore crucial to mitigate the effects of climate change and to support the decisions of policy makers.</p>

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