scholarly journals The design and development of a tuneable and portable radiation source for in situ spectrometer characterisation

2020 ◽  
Author(s):  
Marek Šmíd ◽  
Geiland Porrovecchio ◽  
Jiří Tesař ◽  
Tim Burnitt ◽  
Luca Egli ◽  
...  
Keyword(s):  
Radiation Source ◽  
Near Infrared ◽  
Region Of Interest ◽  
Field Calibration ◽  
Infrared Spectral ◽  
Wavelength Scale ◽  
Better Than

Abstract. For spectroradiometers the characterisation of their wavelength scale and spectral bandwidth underpins substantially the quality of measured data. This characterisation can be performed using metrology-grade tuneable monochromatic sources, which are currently available only in a few laboratories world-wide. Yet in numerous applications only the in-field calibration is a feasible solution. We have designed and developed a Tuneable and Portable radiation Source (TuPS) in the wavelength range from 300 nm to 350 nm for the in-field characterization of Dobson and Brewer spectrometers wavelength scale and slit-function with uncertainties better than 0.02 nm in wavelength and with the bandwidth of emitted radiation smaller than 0.1 nm FWHM. The TuPS is designed such that only minor modifications of its optical system extends/shifts its spectral range towards visible and near-infrared spectral regions and thus expand its application for characterisation of any spectroradiometers in the relevant spectral region of interest.

scholarly journals The design and development of a tuneable and portable radiation source for in situ spectrometer characterisation

2021 ◽  
Vol 14 (5) ◽  
pp. 3573-3582
Author(s):  
Marek Šmíd ◽  
Geiland Porrovecchio ◽  
Jiří Tesař ◽  
Tim Burnitt ◽  
Luca Egli ◽  
...  
Keyword(s):  
Radiation Source ◽  
Near Infrared ◽  
Feasible Solution ◽  
Region Of Interest ◽  
Field Calibration ◽  
Infrared Spectral ◽  
Wavelength Scale ◽  
Better Than

Abstract. For spectroradiometers, the characterisation of their wavelength scale and spectral bandwidth underpins the quality of measured data substantially. This characterisation can be performed using metrology-grade tuneable monochromatic sources, which are currently available only in a few laboratories worldwide. Yet in numerous applications, only the in-field calibration is a feasible solution. We have designed and developed a tuneable and portable radiation source (TuPS) in the wavelength range from 300 to 350 nm for the in-field characterisation of Dobson spectrometers' wavelength scale and slit function, with standard uncertainties better than 0.02 nm in wavelength and with the bandwidth of emitted radiation smaller than 0.13 nm full width at half maximum (FWHM). The TuPS is designed such that only minor modifications of its optical system extend/shift its spectral range towards visible and near-infrared spectral regions and thus expand its application for characterisation of any spectroradiometers in the relevant spectral region of interest.

scholarly journals Characterization of interferences to in situ observations of <i>δ</i><sup>13</sup>CH<sub>4</sub> and C<sub>2</sub>H<sub>6</sub> when using a cavity ring-down spectrometer at industrial sites

2017 ◽  
Vol 10 (6) ◽  
pp. 2077-2091 ◽  
Author(s):  
Sabina Assan ◽  
Alexia Baudic ◽  
Ali Guemri ◽  
Philippe Ciais ◽  
Valerie Gros ◽  
...  
Keyword(s):  
Near Infrared ◽  
Field Tests ◽  
Isotopic Signature ◽  
Ambient Conditions ◽  
Industrial Sites ◽  
Source Determination ◽  
Infrared Spectral ◽  
The Subject

Abstract. Due to increased demand for an understanding of CH4 emissions from industrial sites, the subject of cross sensitivities caused by absorption from multiple gases on δ13CH4 and C2H6 measured in the near-infrared spectral domain using CRDS has become increasingly important. Extensive laboratory tests are presented here, which characterize these cross sensitivities and propose corrections for the biases they induce. We found methane isotopic measurements to be subject to interference from elevated C2H6 concentrations resulting in heavier δ13CH4 by +23.5 ‰ per ppm C2H6 ∕ ppm CH4. Measured C2H6 is subject to absorption interference from a number of other trace gases, predominantly H2O (with an average linear sensitivity of 0.9 ppm C2H6 per  % H2O in ambient conditions). Yet, this sensitivity was found to be discontinuous with a strong hysteresis effect and we suggest removing H2O from gas samples prior to analysis. The C2H6 calibration factor was calculated using a GC and measured as 0.5 (confirmed up to 5 ppm C2H6). Field tests at a natural gas compressor station demonstrated that the presence of C2H6 in gas emissions at an average level of 0.3 ppm shifted the isotopic signature by 2.5 ‰, whilst after calibration we find that the average C2H6 : CH4 ratio shifts by +0.06. These results indicate that, when using such a CRDS instrument in conditions of elevated C2H6 for CH4 source determination, it is imperative to account for the biases discussed within this study.

scholarly journals Automated Testing and Characterization of Additive Manufacturing (ATCAM)

2021 ◽  
Author(s):  
Arash Alex Mazhari ◽  
Randall Ticknor ◽  
Sean Swei ◽  
Stanley Krzesniak ◽  
Mircea Teodorescu
Keyword(s):  
Additive Manufacturing ◽  
Fused Deposition Modeling ◽  
Cell System ◽  
Automated Testing ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Machine Calibration

AbstractThe sensitivity of additive manufacturing (AM) to the variability of feedstock quality, machine calibration, and accuracy drives the need for frequent characterization of fabricated objects for a robust material process. The constant testing is fiscally and logistically intensive, often requiring coupons that are manufactured and tested in independent facilities. As a step toward integrating testing and characterization into the AM process while reducing cost, we propose the automated testing and characterization of AM (ATCAM). ATCAM is configured for fused deposition modeling (FDM) and introduces the concept of dynamic coupons to generate large quantities of basic AM samples. An in situ actuator is printed on the build surface to deploy coupons through impact, which is sensed by a load cell system utilizing machine learning (ML) to correlate AM data. We test ATCAM’s ability to distinguish the quality of three PLA feedstock at differing price points by generating and comparing 3000 dynamic coupons in 10 repetitions of 100 coupon cycles per material. ATCAM correlated the quality of each feedstock and visualized fatigue of in situ actuators over each testing cycle. Three ML algorithms were then compared, with Gradient Boost regression demonstrating a 71% correlation of dynamic coupons to their parent feedstock and provided confidence for the quality of AM data ATCAM generates.

scholarly journals Quantitative Single-Cell Transcript Assessment of Biomarkers Supports Cellular Heterogeneity in the Bovine IVD

2019 ◽  
Vol 6 (2) ◽  
pp. 42 ◽  
Author(s):  
Kangning Li ◽  
Devin Kapper ◽  
Sumona Mondal ◽  
Thomas Lufkin ◽  
Petra Kraus
Keyword(s):  
In Situ Hybridization ◽  
Single Cell ◽  
Gaussian Mixture ◽  
Cellular Heterogeneity ◽  
Rna In Situ Hybridization ◽  
Ivd Degeneration

Severe and chronic low back pain is often associated with intervertebral disc (IVD) degeneration. While imposing a considerable socio-economic burden worldwide, IVD degeneration is also severely impacting on the quality of life of affected individuals. Cell-based regenerative medicine approaches have moved into clinical trials, yet IVD cell identities in the mature disc remain to be fully elucidated and tissue heterogeneity exists, requiring a better characterization of IVD cells. The bovine coccygeal IVD is an accepted research model to study IVD mechano-biology and disc homeostasis. Recently, we identified novel IVD biomarkers in the outer annulus fibrosus (AF) and nucleus pulposus (NP) of the mature bovine coccygeal IVD through RNA in situ hybridization (AP-RISH) and z-proportion test. Here we follow up on Lam1, Thy1, Gli1, Gli3, Noto, Ptprc, Scx, Sox2 and Zscan10 with fluorescent RNA in situ hybridization (FL-RISH) and confocal microscopy. This permits sub-cellular transcript localization and the addition of quantitative single-cell derived values of mRNA expression levels to our previous analysis. Lastly, we used a Gaussian mixture modeling approach for the exploratory analysis of IVD cells. This work complements our earlier cell population proportion-based study, confirms the previously proposed biomarkers and indicates even further heterogeneity of cells in the outer AF and NP of a mature IVD.

scholarly journals Photometric Normalization of Chang’e-4 Visible and Near-Infrared Imaging Spectrometer Datasets: A Combined Study of In-Situ and Laboratory Spectral Measurements

2020 ◽  
Vol 12 (19) ◽  
pp. 3211
Author(s):  
Xiaobin Qi ◽  
Zongcheng Ling ◽  
Jiang Zhang ◽  
Jian Chen ◽  
Haijun Cao ◽  
...  
Keyword(s):  
Near Infrared ◽  
Infrared Imaging ◽  
Landing Site ◽  
Near Infrared Imaging ◽  
Imaging Spectrometer ◽  
Quantitative Mineralogy ◽  
Infrared Spectral ◽  
Phase Functions ◽  
Phase Angles

Until 29 May 2020, the Visible and Near-Infrared Imaging Spectrometer (VNIS) onboard the Yutu-2 Rover of the Chang’e-4 (CE-4) has acquired 96 high-resolution surface in-situ imaging spectra. These spectra were acquired under different illumination conditions, thus photometric normalization should be conducted to correct the introduced albedo differences before deriving the quantitative mineralogy for accurate geologic interpretations. In this study, a Lommel–Seeliger (LS) model and Hapke radiative transfer (Hapke) model were used and empirical phase functions of the LS model were derived. The values of these derived phase functions exhibit declining trends with the increase in phase angles and the opposition effect and phase reddening effect were observed. Then, we discovered from in-situ and laboratory measurements that the shadows caused by surface roughness have significant impacts on reflectance spectra and proper corrections were introduced. The validations of different phase functions showed that the maximum discrepancy at 1500 nm of spectra corrected by the LS model was less (~3.7%) than that by the Hapke model (~7.4%). This is the first time that empirical phase functions have been derived for a wavelength from 450 to 2395 nm using in-situ visible and near-infrared spectral datasets. Generally, photometrically normalized spectra exhibit smaller spectral slopes, lower FeO contents and larger optical maturity parameter (OMAT) than spectra without correction. In addition, the band centers of the 1 and 2 μm absorption features of spectra after photometric normalization exhibit a more concentrated distribution, indicating the compositional homogeneity of soils at the CE-4 landing site.

Growth and Characterization of Single Crystal Epitaxial CoGa on MBE Grown III-V Semiconductors

1988 ◽  
Vol 144 ◽  
Author(s):  
K. C. Garrison ◽  
C. J. Palmstrøm ◽  
R. A. Bartynski
Keyword(s):  
Substrate Temperature ◽  
Single Crystal ◽  
Single Crystals ◽  
Structural Quality ◽  
High Quality ◽  
Auger Analysis ◽  
Post Deposition

ABSTRACTWe have demonstrated growth of high quality single crystal CoGa films on Ga1−xAlxAs. These films were fabricated in-situ by codeposition of Co and Ga on MBE grown Ga1−xAlxAs(100) surfaces. The elemental composition of the films was determined using Rutherford Backscattering (RBS) and in-situ Auger analysis. The structural quality of the films' surfaces was studied using RHEED (during deposition) and LEED (post deposition). RBS channeling was used to determine the bulk crystalline quality of these films.For ∼500 Å CoGa films grown at ∼450°C substrate temperature, channeling data showed good quality epitaxial single crystals [χmin ∼7%] with minimal dechanneling at the interface.

scholarly journals Quality indices of groundwater for agricultural use in the Soconusco, Chiapas, Mexico

2017 ◽  
Vol 21 (3) ◽  
pp. 117-127 ◽  
Author(s):  
Germán Santacruz de León ◽  
JOSE ALFREDO RAMOS LEAL ◽  
JANETE MORAN RAMIREZ ◽  
BRISEIDA LOPEZ ALVAREZ ◽  
EUGENIO ELISEO SANTACRUZ DE LEON
Keyword(s):  
Water Medium ◽  
Quality Indices ◽  
Sodium Percentage ◽  
Agricultural Use ◽  
Magnesium Adsorption Ratio ◽  
Anomalous Point ◽  
Very High

In Soconusco, Chiapas, in spite of the high availability of surface water, it is resorting to the use of groundwater. Knowledge about the quality of surface or groundwater used to irrigate crops in that region is low. This paper aims to contribute to the knowledge of the quality of groundwater for agricultural use through the characterization of the spatial variability. Assuming a random spatial distribution of 45 samples which were collected in situ were determined: acidity and alkalinity (pH), electrical conductivity (EC), Total Dissolved Solids (TDS), cations and anions and trace elements; in addition to the agricultural index: Sodium Adsorption Ratio (SAR), Residual Sodium Carbonate (RSC), Soluble Sodium Percentage (SSP), Sodium Percentage (% Na), Kelly Ratio (KR), Magnesium Adsorption Ratio (MAR), Permeability Index (PI), Effective Salinity (ES), Salinity Potential (SP) and Osmotic Potential (OP). In general, SSP, % Na, KR, PI are low, there is only one anomalous point (9) with high values at W of the study area. Similarly, PS, ES, Cl, Na and SAR are low except point 16 and conversely, RSC and pH are high, except at this point located in the center of the study area. The results allow us to infer that the water in that aquifer presents no problems or sodicity toxic ions. In 27 sites sampled values above 250 µmhos/cm were found at 25°C, classified as medium to high risk of salinity, unsuitable for agricultural use. Analysis of the combined effect of the presence of sodium (SAR) and salinity (EC or TDS) shows that 27 of analyzing sites have restricted water medium at very high for use in irrigation.

scholarly journals Spectral Characterization of Difusse Par Irradiance under Tipuana Tipu Shading

2018 ◽  
Vol 75 (1) ◽  
pp. 19
Author(s):  
Gonzalo GURREA-YSASI ◽  
Vicente BLANCA ◽  
Ana FITA ◽  
Jaime PROHENS ◽  
Inmaculada FITA ◽  
...  
Keyword(s):  
Near Infrared ◽  
Infrared Region ◽  
Photosynthetic Photon Flux Density ◽  
Photon Flux ◽  
Photon Flux Density ◽  
Tree Canopies ◽  
Common Tree ◽  
Soil Level

Tipa (Tipuana tipu) is a common tree in gardens and carparks, although the shading effect of its canopy must be still characterised to assess the decrease of temperature and quality of irradiance. This work is a preliminary study aimed to assess the effect of shading of tree canopies on the diffuse irradiance pattern received at the soil level in comparison to other conditions. The shade provided by a group of Tipa trees, located at the Universitat Politècnica de València (Valencia, Spain), was evaluated in this experiment and compared to cloudy days and direct sun. Photosynthetic Photon Flux Density (PPFD) and red/near infrared ratios were recorded with a portable spectrometer. Measurements were recorded in January and February 2017, at 10h, 13h and 16h. Depending on the region of the spectrum and time of the day, PPFD values ranged from 0.05 to 0.42, 0.40 to 1.14, and 0.94 to 3.90 μmol·m-2·s-1, for Tipa shade, cloudy days and direct sun, respectively. The spectral analysis of PPFD in cloudy days revealed maximum values in the green region and minimum at near infrared region, while maximum PPFD for tipa shade was mostly found at near infrared, revealing higher importance of this spectral region compared to cloudy days.

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