scholarly journals The design and development of a tuneable and portable radiation source for in situ spectrometer characterisation

2021 ◽  
Vol 14 (5) ◽  
pp. 3573-3582
Author(s):  
Marek Šmíd ◽  
Geiland Porrovecchio ◽  
Jiří Tesař ◽  
Tim Burnitt ◽  
Luca Egli ◽  
...  

Abstract. For spectroradiometers, the characterisation of their wavelength scale and spectral bandwidth underpins the quality of measured data substantially. This characterisation can be performed using metrology-grade tuneable monochromatic sources, which are currently available only in a few laboratories worldwide. Yet in numerous applications, only the in-field calibration is a feasible solution. We have designed and developed a tuneable and portable radiation source (TuPS) in the wavelength range from 300 to 350 nm for the in-field characterisation of Dobson spectrometers' wavelength scale and slit function, with standard uncertainties better than 0.02 nm in wavelength and with the bandwidth of emitted radiation smaller than 0.13 nm full width at half maximum (FWHM). The TuPS is designed such that only minor modifications of its optical system extend/shift its spectral range towards visible and near-infrared spectral regions and thus expand its application for characterisation of any spectroradiometers in the relevant spectral region of interest.

2020 ◽  
Author(s):  
Marek Šmíd ◽  
Geiland Porrovecchio ◽  
Jiří Tesař ◽  
Tim Burnitt ◽  
Luca Egli ◽  
...  

Abstract. For spectroradiometers the characterisation of their wavelength scale and spectral bandwidth underpins substantially the quality of measured data. This characterisation can be performed using metrology-grade tuneable monochromatic sources, which are currently available only in a few laboratories world-wide. Yet in numerous applications only the in-field calibration is a feasible solution. We have designed and developed a Tuneable and Portable radiation Source (TuPS) in the wavelength range from 300 nm to 350 nm for the in-field characterization of Dobson and Brewer spectrometers wavelength scale and slit-function with uncertainties better than 0.02 nm in wavelength and with the bandwidth of emitted radiation smaller than 0.1 nm FWHM. The TuPS is designed such that only minor modifications of its optical system extends/shifts its spectral range towards visible and near-infrared spectral regions and thus expand its application for characterisation of any spectroradiometers in the relevant spectral region of interest.


2017 ◽  
Vol 10 (6) ◽  
pp. 2077-2091 ◽  
Author(s):  
Sabina Assan ◽  
Alexia Baudic ◽  
Ali Guemri ◽  
Philippe Ciais ◽  
Valerie Gros ◽  
...  

Abstract. Due to increased demand for an understanding of CH4 emissions from industrial sites, the subject of cross sensitivities caused by absorption from multiple gases on δ13CH4 and C2H6 measured in the near-infrared spectral domain using CRDS has become increasingly important. Extensive laboratory tests are presented here, which characterize these cross sensitivities and propose corrections for the biases they induce. We found methane isotopic measurements to be subject to interference from elevated C2H6 concentrations resulting in heavier δ13CH4 by +23.5 ‰ per ppm C2H6 ∕ ppm CH4. Measured C2H6 is subject to absorption interference from a number of other trace gases, predominantly H2O (with an average linear sensitivity of 0.9 ppm C2H6 per  % H2O in ambient conditions). Yet, this sensitivity was found to be discontinuous with a strong hysteresis effect and we suggest removing H2O from gas samples prior to analysis. The C2H6 calibration factor was calculated using a GC and measured as 0.5 (confirmed up to 5 ppm C2H6). Field tests at a natural gas compressor station demonstrated that the presence of C2H6 in gas emissions at an average level of 0.3 ppm shifted the isotopic signature by 2.5 ‰, whilst after calibration we find that the average C2H6 : CH4 ratio shifts by +0.06. These results indicate that, when using such a CRDS instrument in conditions of elevated C2H6 for CH4 source determination, it is imperative to account for the biases discussed within this study.


2020 ◽  
Vol 12 (19) ◽  
pp. 3211
Author(s):  
Xiaobin Qi ◽  
Zongcheng Ling ◽  
Jiang Zhang ◽  
Jian Chen ◽  
Haijun Cao ◽  
...  

Until 29 May 2020, the Visible and Near-Infrared Imaging Spectrometer (VNIS) onboard the Yutu-2 Rover of the Chang’e-4 (CE-4) has acquired 96 high-resolution surface in-situ imaging spectra. These spectra were acquired under different illumination conditions, thus photometric normalization should be conducted to correct the introduced albedo differences before deriving the quantitative mineralogy for accurate geologic interpretations. In this study, a Lommel–Seeliger (LS) model and Hapke radiative transfer (Hapke) model were used and empirical phase functions of the LS model were derived. The values of these derived phase functions exhibit declining trends with the increase in phase angles and the opposition effect and phase reddening effect were observed. Then, we discovered from in-situ and laboratory measurements that the shadows caused by surface roughness have significant impacts on reflectance spectra and proper corrections were introduced. The validations of different phase functions showed that the maximum discrepancy at 1500 nm of spectra corrected by the LS model was less (~3.7%) than that by the Hapke model (~7.4%). This is the first time that empirical phase functions have been derived for a wavelength from 450 to 2395 nm using in-situ visible and near-infrared spectral datasets. Generally, photometrically normalized spectra exhibit smaller spectral slopes, lower FeO contents and larger optical maturity parameter (OMAT) than spectra without correction. In addition, the band centers of the 1 and 2 μm absorption features of spectra after photometric normalization exhibit a more concentrated distribution, indicating the compositional homogeneity of soils at the CE-4 landing site.


1986 ◽  
Vol 40 (3) ◽  
pp. 303-310 ◽  
Author(s):  
M. Martens ◽  
H. Martens

Rapid, precise, and relevant methods for predicting the sensory quality of frozen peas were sought. Pea batches chosen to span many different types of quality variations were analyzed by a consumer test, sensory laboratory analysis, and traditional chemical and physical measurements as well as by near-infrared reflectance analysis (NIR). Partial least-squares (PLS) regression was used to reveal the relationships between the different types of measurements. A noise-compensated value, relative ability of prediction (RAP), was used to express the degree of prediction (1.0 = perfect prediction). NIR was found to predict the sensory texture variables (RAP = 0.79) better than the flavor variables (RAP = 0.67). Average consumer preference was less well predicted (RAP = 0.48) by NIR. This was interpretable since NIR gave a better description of the chemical and physical methods relevant for texture (e.g., dry matter (RAP = 0.93)) than the flavor-related variables (e.g., sucrose (RAP = 0.45)) that apparently determine the consumer preference. However, NIR was found to describe the average variation in sensory quality better than the traditional tenderometer value (TV). The highest prediction of sensory variables was obtained by a combination of NIR, TV, and chemical measurements (RAP = 0.87 and 0.80 for texture and flavor variables, respectively). We discuss the predictive validity and the meaning of the present predictive abilities in practice, leading to a conclusion that NIR has a potential for predicting the sensory quality of peas.


1999 ◽  
Vol 2 (02) ◽  
pp. 125-133 ◽  
Author(s):  
M.N. Hashem ◽  
E.C. Thomas ◽  
R.I. McNeil ◽  
Oliver Mullins

Summary Determination of the type and quality of hydrocarbon fluid that can be produced from a formation prior to construction of production facilities is of equal economic importance to predicting the fluid rate and flowing pressure. We have become adept at making such estimates for formations drilled with water-based muds, using open-hole formation evaluation procedures. However, these standard open-hole methods are somewhat handicapped in wells drilled with synthetic oil-based mud because of the chemical and physical similarity between the synthetic oil-based filtrate and any producible oil that may be present. Also complicating the prediction is that in situ hydrocarbons will be miscibly displaced away from the wellbore by the invading oil-based mud filtrate, leaving little or no trace of the original hydrocarbon in the invaded zone. Thus, normal methods that sample fluids in the invaded zone will be of little use in predicting the in situ type and quality of hydrocarbons deeper in the formation. Only when we can pump significant volume of filtrate from the invaded zone to reconnect and sample the virgin fluids are we successful. However, since the in situ oil and filtrate are miscible, diffusion mixes the materials and blurs the interface; as mud filtrate is pumped from the formation into the borehole, the degree of contamination is greater than one might expect, and it is difficult to know when to stop pumping and start sampling. What level of filtrate contamination in the in situ fluid is tolerable? We propose a procedure for enhancing the value of the data derived from a particular open-hole wireline formation tester by quantitatively evaluating in real time the quality of the fluid being collected. The approach focuses on expanding the display of the spectroscopic data as a function of time on a more sensitive scale than has been used previously. This enhanced sensitivity allows one to confidently decide when in the pumping cycle to begin the sampling procedure. The study also utilizes laboratory determined PVT information on collected samples to form a data set that we use to correlate to the wireline derived spectroscopic data. The accuracy of these correlations has been verified with subsequent predictions and corroborated with laboratory measurements. Lastly, we provide a guideline for predicting the pump-out time needed to obtain a fluid sample of a pre-determined level of contamination when sampling conditions fall within our range of empirical data. Conclusions This empirical study validates that PVT quality hydrocarbon samples can be obtained from boreholes drilled with synthetic oil-based mud utilizing wireline formation testers deployed with downhole pump-out and optical analyzer modules. The data set for this study has the following boundary conditions: samples were obtained in the Gulf of Mexico area; the rock formations are unconsolidated to slightly consolidated, clean to slightly shaly sandstones; the in situ hydrocarbons and the synthetic oil-based mud filtrate have measurable differences in their visible and/or near infrared spectra. Specifically, this study demonstrates that during the pump-out phase of operations we can use the optical analyzer response to predict the API gravity and gas/oil ratio of the reservoir hydrocarbons prior to securing a downhole sample. Additionally, we can predict the pump out time required to obtain a reservoir sample with less than 10% mud filtrate contamination if we know or can estimate reservoir fluid viscosity and formation permeability. Extension of this method to other formations and locales should be possible using similar empirical correlation methodology. Introduction The high cost of offshore production facilities construction and deployment require accurate prediction of hydrocarbon PVT properties prior to fabrication. In the offshore Gulf of Mexico, one method to obtain a PVT quality hydrocarbon sample is to use a cased hole drill stem test. However, this procedure is usually quite costly due to the need for sand control. Shell has been an advocate of eliminating this costly step by utilizing openhole wireline test tools to obtain the PVT quality sample of the reservoir hydrocarbon. The success of this approach depends upon the availability of a wireline tool with a downhole pump that permits removal of the mud filtrate contamination prior to sampling the reservoir fluids, and a downhole fluid analyzer that can distinguish reservoir fluid from filtrate. One such tool is the Modular Formation Dynamics Tester (MDT).1 The optical fluid analyzer module of the MDT functions by subjecting the fluids being pumped to absorption spectroscopy in the visible and near-infrared (NIR) ranges. Interpretation of these spectra is the subject of this paper. Tool descriptions and basic theory of operations were presented in an earlier text.2 The concept of using visible and/or NIR spectroscopy to characterize the fluids being sampled while pumping is straightforward when there are measurable differences in the spectra of the mud filtrate and the reservoir hydrocarbons. As shown in Fig. 1, there are well known areas3,4 of the NIR spectrum (800-2000 nm) that are diagnostic of water and oil. The optical fluid analyzer module (OFA) of the MDT has channels tuned at 10 locations as indicated in Fig. 1, and thus the response in channels 6, 8, and 9 can be used to discern water from hydrocarbon. Another section of the OFA is designed to detect gas by measuring reflected polarized light from the pumped fluids, but we do not discuss its operation further except to say that it is a reliable gas indicator.


2020 ◽  
Author(s):  
zhongxiu zhao ◽  
Miaomiao Zhu ◽  
Qian Jian ◽  
Xialu Liu ◽  
Pingting Ma ◽  
...  

Abstract Background: Individualized ablation is not only able to correct corneal low-order aberrations but also to improve corneal high-order aberrations in patients with corneal asymmetry. In this study, we compared the effects of three different surgical methods, namely, corneal wavefront-guided femtosecond laser assisted in-situ keratomileusis (CWFG-FS-LASIK), aberration-free femtosecond laser assisted in-situ keratomileusis (AF-FS-LASIK) and small incision lenticule (SMILE), in patients with mid-to-high astigmatism asymmetric corneas (1-4D).Methods: One hundred-fourteen eyes from 58 patients were enrolled in this retrospective study. We measured and compared the best corrected visual acuity (BCVA), uncorrected visual acuity (UCVA), residual astigmatism, total coma, vertical coma (Z3-1), horizontal coma (Z31), modulation transfer function (MTF) and point spread function (PSF) preoperatively and three months postoperatively. Results: The visual acuity of patients in the three groups was increased after surgery, but the improvements in visual acuity and residual astigmatism among them were not significantly different. However, the improvements in 4-mm and 6-mm total coma, Z3-1 and Z31 in patients who underwent CWFG-FS-LASIK were better than those in patients who underwent AF-FS-LASIK and SMILE. Consistent with these results, the improvements in MTF and PSF (3 mm and 5 mm) in the CWFG-FS-LASIK group were better than those in the AF-FS-LASIK and SMILE groups.Conclusions: Among surgeries for treating patients with mid-to-high astigmatism in asymmetric corneas, the selective coma-guided modality was able to decrease the coma of original cornea, improve visual acuity and optimize the visual quality of patients.


2018 ◽  
Vol 11 (10) ◽  
pp. 5657-5672 ◽  
Author(s):  
Anne Kleinert ◽  
Manfred Birk ◽  
Gaétan Perron ◽  
Georg Wagner

Abstract. The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a Fourier transform spectrometer measuring the radiance emitted from the atmosphere in limb geometry in the thermal infrared spectral region. It was operated onboard the ENVISAT satellite from 2002 to 2012. Calibrated and geolocated spectra, the so-called level 1b data, are the basis for the retrieval of atmospheric parameters. In this paper we present the error budget for the level 1b data of the most recent data version 8 in terms of radiometric, spectral, and line of sight accuracy. The major changes of version 8 compared to older versions are also described. The impact of the different error sources on the spectra is characterized in terms of spectral, vertical, and temporal correlation because these correlations have an impact on the quality of the retrieved quantities. The radiometric error is in the order of 1 % to 2.4 %, the spectral accuracy is better than 0.3 ppm, and the line of sight accuracy at the tangent point is around 400 m. All errors are well within the requirements, and the achieved accuracy allows atmospheric parameters to be retrieved from the measurements with high quality.


2015 ◽  
Vol 8 (1) ◽  
pp. 1333-1363
Author(s):  
R. Checa-Garcia ◽  
J. Landgraf ◽  
F. Hase ◽  
H. Tran ◽  
V. Boudon ◽  
...  

Abstract. Sentinel-5 (S5) and its precursor (S5P) are future European satellite missions aiming at global monitoring of methane (CH4) column average dry air mole fractions (XCH4). The spectrometers to be deployed on-board the satellites record spectra of sunlight backscattered from the Earth's surface and atmosphere. In particular, they exploit CH4 absorption in the shortwave infrared spectral range around 1.65 μm (S5 only) and 2.35 μm (both, S5 and S5P) wavelength. Given an accuracy goal of better than 2% for XCH4 to be delivered on regional scales, assessment and reduction of potential sources of systematic error such as spectroscopic uncertainties is crucial. Here, we investigate how spectroscopic errors propagate into retrieval errors on the global scale. To this end, absorption spectra of a ground-based Fourier Transform Spectrometer (FTS) operating at very high spectral resolution serve as estimate for the quality of the spectroscopic parameters. Feeding the FTS fitting residuals as a perturbation into a global ensemble of simulated S5 and S5P-like spectra at relatively low spectral resolution, XCH4 retrieval errors exceed 1% in large parts of the world and show systematic correlations on regional scales, calling for improved spectroscopic parameters.


2013 ◽  
Vol 2013 ◽  
pp. 1-15 ◽  
Author(s):  
J. S. C. Chew ◽  
L. S. Lee ◽  
H. V. Seow

This paper considers solving a biobjective urban transit routing problem with a genetic algorithm approach. The objectives are to minimize the passengers’ and operators’ costs where the quality of the route sets is evaluated by a set of parameters. The proposed algorithm employs an adding-node procedure which helps in converting an infeasible solution to a feasible solution. A simple yet effective route crossover operator is proposed by utilizing a set of feasibility criteria to reduce the possibility of producing an infeasible network. The computational results from Mandl’s benchmark problems are compared with other published results in the literature and the computational experiments show that the proposed algorithm performs better than the previous best published results in most cases.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3848
Author(s):  
Lisa Ptacek ◽  
Alfred Strauss ◽  
Barbara Hinterstoisser ◽  
Andreas Zitek

The curing of concrete significantly influences the hydration process and its strength development. Inadequate curing leads to a loss of quality and has a negative effect on the durability of the concrete. Usually, the effects are not noticed until years later, when the first damage to the structure occurs because of the poor concrete quality. This paper presents a non-destructive measurement method for the determination of the curing quality of young concrete. Hyperspectral imaging in the near infrared is a contactless method that provides information about material properties in an electromagnetic wavelength range that cannot be seen with the human eye. Laboratory tests were carried out with samples with three different curing types at the age of 1, 7, and 27 days. The results showed that differences in the near infrared spectral signatures can be determined depending on the age of the concrete and the type of curing. The data was classified and analyzed by evaluating the results using k-means clustering. This method showed a high level of reliability for the differentiation between the different curing types and concrete ages. A recommendation for hyperspectral measurement and the evaluation of the curing quality of concrete could be made.


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