scholarly journals Initial investigation of the wavelength dependence of optical properties measured with a new multi-pass aerosol extinction differential optical absorption spectrometer (AE-DOAS)

2011 ◽  
Vol 4 (5) ◽  
pp. 6315-6349
Author(s):  
R. T. Chartier ◽  
M. E. Greenslade
Keyword(s):  
Refractive Index ◽  
Optical Absorption ◽  
Radiative Forcing ◽  
Wavelength Dependence ◽  
Polystyrene Latex ◽  
Light Extinction ◽  
Aerosol Extinction ◽  
New Instrument ◽  
The Impact ◽  
Absorption Spectrometer

Abstract. Atmospheric aerosols directly affect climate by scattering and absorbing radiation. The magnitude of the impact is dependent upon the wavelength of light, but is often estimated near 550 nm. When light scattering and absorption by aerosols is approximated, the wavelength dependence of the refractive index for specific components is lost. As a result, climate models would have inherent uncertainties for aerosol contributions to radiative forcing when considering the entire solar spectrum. An aerosol extinction differential optical absorption spectrometer has been developed to directly measure aerosol extinction at mid-ultraviolet to near infrared wavelengths. The instrument consists of a spectrometer coupled to a closed White-type multi-pass gas cell with an adjustable path length of up to approximately 20 m. Laboratory measurements of various gases are compared with known absorption cross sections. Additionally, the extinction of monodisperse samples of polystyrene latex spheres are measured and compared to Mie theory generated with refractive index values from the literature to validate the new instrument. The polystyrene experiments also emphasize the ability of the new instrument to retrieve the wavelength dependent refractive index, especially in the ultraviolet wavelength regions where variability is expected. The spectrometer will be a significant advancement for determining wavelength dependent complex refractive indices in future laboratory studies as well as provide the ability to monitor ambient aerosol light extinction.

scholarly journals Initial investigation of the wavelength dependence of optical properties measured with a new multi-pass Aerosol Extinction Differential Optical Absorption Spectrometer (AE-DOAS)

2012 ◽  
Vol 5 (4) ◽  
pp. 709-721 ◽  
Author(s):  
R. T. Chartier ◽  
M. E. Greenslade
Keyword(s):  
Refractive Index ◽  
Optical Absorption ◽  
Radiative Forcing ◽  
Wavelength Dependence ◽  
Polystyrene Latex ◽  
Light Extinction ◽  
Aerosol Extinction ◽  
New Instrument ◽  
The Impact ◽  
Absorption Spectrometer

Abstract. Atmospheric aerosols directly affect climate by scattering and absorbing radiation. The magnitude of the impact is dependent upon the wavelength of light, but is often estimated near 550 nm. When light scattering and absorption by aerosols is approximated, the wavelength dependence of the refractive index for specific components is lost. As a result, climate models would have inherent uncertainties for aerosol contributions to radiative forcing when considering the entire solar spectrum. An aerosol extinction differential optical absorption spectrometer has been developed to directly measure aerosol extinction at mid-ultraviolet to near infrared wavelengths. The instrument consists of a spectrometer coupled to a closed White-type multi-pass gas cell with an adjustable path length of up to approximately 20 m. Laboratory measurements of various gases are compared with known absorption cross sections. Additionally, the extinction of monodisperse samples of polystyrene latex spheres are measured and compared to Mie theory generated with refractive index values from the literature to validate the new instrument. The polystyrene experiments also emphasize the ability of the new instrument to retrieve the wavelength dependent refractive index, especially in the ultraviolet wavelength regions where variability is expected. The spectrometer will be a significant advancement for determining wavelength dependent complex refractive indices in future laboratory studies as well as provide the ability to monitor ambient aerosol light extinction.

scholarly journals Light extinction by secondary organic aerosol: an intercomparison of three broadband cavity spectrometers

2013 ◽  
Vol 6 (11) ◽  
pp. 3115-3130 ◽  
Author(s):  
R. M. Varma ◽  
S. M. Ball ◽  
T. Brauers ◽  
H.-P. Dorn ◽  
U. Heitmann ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Cavity ◽  
Light Extinction ◽  
Organic Nitrates ◽  
Aerosol Extinction ◽  
Particle Phase ◽  
Extinction Coefficients ◽  
Enhanced Absorption ◽  
Intercomparison Study ◽  
Absorption Spectrometer

Abstract. Broadband optical cavity spectrometers are maturing as a technology for trace-gas detection, but only recently have they been used to retrieve the extinction coefficient of aerosols. Sensitive broadband extinction measurements allow explicit separation of gas and particle phase spectral contributions, as well as continuous spectral measurements of aerosol extinction in favourable cases. In this work, we report an intercomparison study of the aerosol extinction coefficients measured by three such instruments: a broadband cavity ring-down spectrometer (BBCRDS), a cavity-enhanced differential optical absorption spectrometer (CE-DOAS), and an incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS). Experiments were carried out in the SAPHIR atmospheric simulation chamber as part of the NO3Comp campaign to compare the measurement capabilities of NO3 and N2O5 instrumentation. Aerosol extinction coefficients between 655 and 690 nm are reported for secondary organic aerosols (SOA) formed by the NO3 oxidation of β-pinene under dry and humid conditions. Despite different measurement approaches and spectral analysis procedures, the three instruments retrieved aerosol extinction coefficients that were in close agreement. The refractive index of SOA formed from the β-pinene + NO3 reaction was 1.61, and was not measurably affected by the chamber humidity or by aging of the aerosol over several hours. This refractive index is significantly larger than SOA refractive indices observed in other studies of OH and ozone-initiated terpene oxidations, and may be caused by the large proportion of organic nitrates in the particle phase. In an experiment involving ammonium sulfate particles, the aerosol extinction coefficients as measured by IBBCEAS were found to be in reasonable agreement with those calculated using the Mie theory. The results of the study demonstrate the potential of broadband cavity spectrometers for determining the optical properties of aerosols.

scholarly journals Light extinction by Secondary Organic Aerosol: an intercomparison of three broadband cavity spectrometers

2013 ◽  
Vol 6 (4) ◽  
pp. 6685-6727 ◽  
Author(s):  
R. M. Varma ◽  
S. M. Ball ◽  
T. Brauers ◽  
H.-P. Dorn ◽  
U. Heitmann ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Cavity ◽  
Light Extinction ◽  
Organic Nitrates ◽  
Aerosol Extinction ◽  
Particle Phase ◽  
Extinction Coefficients ◽  
Enhanced Absorption ◽  
Intercomparison Study ◽  
Absorption Spectrometer

Abstract. Broadband optical cavity spectrometers are maturing as a technology for trace gas detection, but only recently have they been used to retrieve the extinction coefficient of aerosols. Sensitive broadband extinction measurements allow explicit separation of gas and particle phase spectral contributions, as well as continuous spectral measurements of aerosol extinction in favourable cases. In this work, we report an intercomparison study of the aerosol extinction coefficients measured by three such instruments: a broadband cavity ring-down spectrometer (BBCRDS), a cavity-enhanced differential optical absorption spectrometer (CE-DOAS), and an incoherent broadband cavity-enhanced absorption spectrometer (IBBCEAS). Experiments were carried out in the SAPHIR atmospheric simulation chamber as part of the NO3Comp campaign to compare the measurement capabilities of NO3 and N2O5 instrumentation. Aerosol extinction coefficients between 655 and 690 nm are reported for secondary organic aerosols (SOA) formed by the NO3 oxidation of β-pinene under dry and humid conditions. Despite different measurement approaches and spectral analysis procedures, the three instruments retrieved aerosol extinction coefficients that were in close agreement. The refractive index of SOA formed from the β-pinene + NO3 reaction was 1.61, and was not measurably affected by the chamber humidity or by aging of the aerosol over several hours. This refractive index is significantly larger than SOA refractive indices observed in other studies of OH and ozone-initiated terpene oxidations, and may be caused by the large proportion of organic nitrates in the particle phase. In an experiment involving ammonium sulphate particles the aerosol extinction coefficients as measured by IBBCEAS were found to be in reasonable agreement with those calculated using Mie theory. The results of the study demonstrate the potential of broadband cavity spectrometers for determining the optical properties of aerosols.

scholarly journals Spectral Aerosol Extinction (SpEx): a new instrument for in situ ambient aerosol extinction measurements across the UV/visible wavelength range

2015 ◽  
Vol 8 (6) ◽  
pp. 6469-6509 ◽  
Author(s):  
C. E. Jordan ◽  
B. E. Anderson ◽  
A. J. Beyersdorf ◽  
C. A. Corr ◽  
J. E. Dibb ◽  
...  
Keyword(s):  
Wavelength Range ◽  
Theoretical Calculations ◽  
Polystyrene Latex ◽  
Aerosol Extinction ◽  
Brown Carbon ◽  
Ambient Aerosol ◽  
Measurement Capability ◽  
New Instrument ◽  
Visible Wavelengths

Abstract. We introduce a new instrument for the measurement of in situ ambient aerosol extinction over the 300–700 nm wavelength range, the Spectral Aerosol Extinction (SpEx) instrument. This measurement capability is envisioned to complement existing in situ instrumentation, allowing for simultaneous measurement of the evolution of aerosol optical, chemical, and physical characteristics in the ambient environment. In this work, a detailed description of the instrument is provided along with characterization tests performed in the laboratory. Measured spectra of NO2 and polystyrene latex spheres (PSLs) agreed well with theoretical calculations. Good agreement was also found with simultaneous aerosol extinction measurements at 450, 530, and 630 nm using CAPS PMex instruments in a series of 22 tests including non-absorbing compounds, dusts, soot, and black and brown carbon analogs. SpEx can more accurately distinguish the presence of brown carbon from other absorbing aerosol due to its 300 nm lower wavelength limit compared to measurements limited to visible wavelengths. Extinction spectra obtained with SpEx contain more information than can be conveyed by a simple power law fit (typically represented by Ångström Exponents). Planned future improvements aim to lower detection limits and ruggedize the instrument for mobile operation.

scholarly journals Spectral aerosol extinction (SpEx): a new instrument for in situ ambient aerosol extinction measurements across the UV/visible wavelength range

2015 ◽  
Vol 8 (11) ◽  
pp. 4755-4771 ◽  
Author(s):  
C. E. Jordan ◽  
B. E. Anderson ◽  
A. J. Beyersdorf ◽  
C. A. Corr ◽  
J. E. Dibb ◽  
...  
Keyword(s):  
Wavelength Range ◽  
Theoretical Calculations ◽  
Polystyrene Latex ◽  
Aerosol Extinction ◽  
Brown Carbon ◽  
Ambient Aerosol ◽  
Measurement Capability ◽  
New Instrument ◽  
Visible Wavelengths

Abstract. We introduce a new instrument for the measurement of in situ ambient aerosol extinction over the 300–700 nm wavelength range, the spectral aerosol extinction (SpEx) instrument. This measurement capability is envisioned to complement existing in situ instrumentation, allowing for simultaneous measurement of the evolution of aerosol optical, chemical, and physical characteristics in the ambient environment. In this work, a detailed description of the instrument is provided along with characterization tests performed in the laboratory. Measured spectra of NO2 and polystyrene latex spheres (PSLs) agreed well with theoretical calculations. Good agreement was also found with simultaneous aerosol extinction measurements at 450, 530, and 630 nm using CAPS PMex instruments in a series of 22 tests including nonabsorbing compounds, dusts, soot, and black and brown carbon analogs. SpEx measurements are expected to help identify the presence of ambient brown carbon due to its 300 nm lower wavelength limit compared to measurements limited to longer UV and visible wavelengths. Extinction spectra obtained with SpEx contain more information than can be conveyed by a simple power law fit (typically represented by Ångström exponents). Planned future improvements aim to lower detection limits and ruggedize the instrument for mobile operation.

The Impact of Dust Storms on Aerosol Optical Depth and Radiative Forcing

2020 ◽  
Vol 16 (1) ◽  
pp. 1-14
Author(s):  
Monim Jiboori ◽  
Nadia Abed ◽  
Mohamed Abdel Wahab
Keyword(s):  
Aerosol Optical Depth ◽  
Optical Depth ◽  
Radiative Forcing ◽  
Dust Storms ◽  
The Impact

Stress Whitening in Polypropylene. I. Light Scattering Theory and Model Experiments

1995 ◽  
Vol 60 (11) ◽  
pp. 1875-1887 ◽  
Author(s):  
Jaroslav Holoubek ◽  
Miroslav Raab
Keyword(s):  
Refractive Index ◽  
Light Scattering ◽  
Incident Light ◽  
Polymeric Materials ◽  
Wavelength Dependence ◽  
Theoretical Background ◽  
Surrounding Matrix ◽  
Embedded Particles ◽  
The One ◽  
Stress Whitening

Theoretical background for an optical method is presented which makes it possible to distinguish unambiguously between voids and particles as light scattering sites in polymeric materials. Typical dependences of turbidity as a function of diameter of scattering elements, their volume fractions and also turbidity curves as a function of the wavelength of the incident light were calculated, based both on the Lorenz-Mie theory and the fluctuation theory. Such dependences calculated for polypropylene-containing voids on the one hand and particles, differing only slightly from the surrounding matrix in their refractive index, on the other hand, are markedly different. The most significant results are: (i) Turbidity is at least by two orders of magnitude larger for voids in comparison to embedded particles of ethylene-propylene (EPDM) rubber of the same size, concentration and at the same wavelength. (ii) The wavelength dependence of turbidity for EPDM particles and the inherent refractive index fluctuations in the polypropylene matrix is much steeper as compared to voids for all considered diameters (0.1-10 μm). Thus, the nature of stress whitening in complex polymeric materials can be determined from turbidity measurements.

Comparative crosstalk performance analysis of different configurations of heterogeneous multicore fiber

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Umar Farooque ◽  
Rakesh Ranjan
Keyword(s):  
Refractive Index ◽  
Mode Coupling ◽  
The Other ◽  
Heterogeneous Multicore ◽  
Coupled Mode ◽  
The Core ◽  
Bending Radius ◽  
Multicore Fiber ◽  
The Impact ◽  
Core Pitch

AbstractIn order to select the heterogeneous multicore fiber (MCF) configuration with ultra-low crosstalk and low peak bending radius, comparative crosstalk analysis have been done for the three possible core configurations, namely, Configuration 1 - different refractive index (R.I.) and different radius, Configuration 2 - different R.I., and Configuration 3 - different radius. Using the coupled mode equation and the simplified expressions of mode coupling coefficient (MCC) for different configurations of heterogeneous cores, the crosstalk performance of all the heterogeneous MCF configurations along with the homogeneous MCF have been investigated analytically with respect to core pitch (D) and fiber bending radius (${R}_{b}$). Further, these expressions of MCC have been extended to obtain the simplified expressions of MCC for the estimation of crosstalk levels in respective trench-assisted (TA) heterogeneous MCF configurations. It is observed from the analysis that in Configuration 1, crosstalk level is lowest and the rate of decrease in the crosstalk with respect to the core pitch is highest compared to the other configurations of heterogeneous MCF. The values of crosstalk obtained analytically have been validated by comparing it with the values obtained from finite element method (FEM) based numerical simulation results. Further, we have investigated the impact of a fixed percent change (5%) in the core parameters (radius and/or R.I.) of one of the core of a homogeneous MCF, to realize the different heterogeneous MCF configurations, on the variations in crosstalk levels, difference in the mode effective refractive index of the core 1 and core 2 ($\Delta {n}_{eff}={n}_{eff1}-{n}_{eff2}$), and the peak bending radius (${R}_{pk}$). For the same percent variations (5%) in the core parameters (radius and/or R.I.) of different configurations of cores (Config. 1-Config. 3), Config. 1 MCF has highest variation in $\Delta {n}_{eff}$ value compared to other configurations of MCF. Further, this highest variation in $\Delta {n}_{eff}$ value of Config. 1 MCF results in smallest peak bending radius. The smaller value of peak bending radius allows MCF to bend into smaller radius. Therefore, Configuration 1 is the potential choice for the design of MCF with smaller peak bending radius and ultra-low crosstalk level compared to the other configurations of SI-heterogeneous MCF.

scholarly journals Synthesis of PVA/CeO2 Based Nanocomposites with Tuned Refractive Index and Reduced Absorption Edge: Structural and Optical Studies

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1570
Author(s):  
Shujahadeen B. Aziz ◽  
Elham M. A. Dannoun ◽  
Dana A. Tahir ◽  
Sarkawt A. Hussen ◽  
Rebar T. Abdulwahid ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Absorption Edge ◽  
Ceo2 Nanoparticles ◽  
Poly Vinyl Alcohol ◽  
Optical Parameters ◽  
Single Oscillator Model ◽  
Vis Spectroscopy ◽  
The Impact ◽  
Host Polymer

In the current study, polymer nanocomposites (NCPs) based on poly (vinyl alcohol) (PVA) with altered refractive index and absorption edge were synthesized by means of a solution cast technique. The characterization techniques of UV–Vis spectroscopy and XRD were used to inspect the structural and optical properties of the prepared films. The XRD patterns of the doped samples have shown clear amendments in the structural properties of the PVA host polymer. Various optical parameters were studied to get more insights about the influence of CeO2 on optical properties of PVA. On the insertion of CeO2 nanoparticles (NPs) into the PVA matrix, the absorption edge was found to move to reduced photon energy sides. It was concluded that the CeO2 nanoparticles can be used to tune the refractive index (n) of the host polymer, and it reached up to 1.93 for 7 wt.% of CeO2 content. A detailed study of the bandgap (BG) was conducted using two approaches. The outcomes have confirmed the impact of the nanofiller on the BG reduction of the host polymer. The results of the optical BG study highlighted that it is crucial to address the ɛ” parameter during the BG analysis, and it is considered as a useful tool to specify the type of electronic transitions. Finally, the dispersion region of n is conferred in terms of the Wemple–DiDomenico single oscillator model.

scholarly journals Anthropogenic climate change has changed frequency of past flood during 2010-2013

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Yukiko Hirabayashi ◽  
Haireti Alifu ◽  
Dai Yamazaki ◽  
Yukiko Imada ◽  
Hideo Shiogama ◽  
...  
Keyword(s):  
Climate Change ◽  
South America ◽  
Radiative Forcing ◽  
Water Cycle ◽  
Flood Frequency ◽  
Anthropogenic Climate Change ◽  
Climate Change Signal ◽  
Northern Eurasia ◽  
Large Ensemble ◽  
The Impact

AbstractThe ongoing increases in anthropogenic radiative forcing have changed the global water cycle and are expected to lead to more intense precipitation extremes and associated floods. However, given the limitations of observations and model simulations, evidence of the impact of anthropogenic climate change on past extreme river discharge is scarce. Here, a large ensemble numerical simulation revealed that 64% (14 of 22 events) of floods analyzed during 2010-2013 were affected by anthropogenic climate change. Four flood events in Asia, Europe, and South America were enhanced within the 90% likelihood range. Of eight snow-induced floods analyzed, three were enhanced and four events were suppressed, indicating that the effects of climate change are more likely to be seen in the snow-induced floods. A global-scale analysis of flood frequency revealed that anthropogenic climate change enhanced the occurrence of floods during 2010-2013 in wide area of northern Eurasia, part of northwestern India, and central Africa, while suppressing the occurrence of floods in part of northeastern Eurasia, southern Africa, central to eastern North America and South America. Since the changes in the occurrence of flooding are the results of several hydrological processes, such as snow melt and changes in seasonal and extreme precipitation, and because a climate change signal is often not detectable from limited observation records, large ensemble discharge simulation provides insights into anthropogenic effects on past fluvial floods.

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