scholarly journals Methyl iodide production in the open ocean

2014 ◽  
Vol 11 (16) ◽  
pp. 4459-4476 ◽  
Author(s):  
I. Stemmler ◽  
I. Hense ◽  
B. Quack ◽  
E. Maier-Reimer

Abstract. Production pathways of the prominent volatile organic halogen compound methyl iodide (CH3I) are not fully understood. Based on observations, production of CH3I via photochemical degradation of organic material or via phytoplankton production has been proposed. Additional insights could not be gained from correlations between observed biological and environmental variables or from biogeochemical modeling to identify unambiguously the source of methyl iodide. In this study, we aim to address this question of source mechanisms with a three-dimensional global ocean general circulation model including biogeochemistry (MPIOM–HAMOCC (MPIOM – Max Planck Institute Ocean Model HAMOCC – HAMburg Ocean Carbon Cycle model)) by carrying out a series of sensitivity experiments. The simulated fields are compared with a newly available global data set. Simulated distribution patterns and emissions of CH3I differ largely for the two different production pathways. The evaluation of our model results with observations shows that, on the global scale, observed surface concentrations of CH3I can be best explained by the photochemical production pathway. Our results further emphasize that correlations between CH3I and abiotic or biotic factors do not necessarily provide meaningful insights concerning the source of origin. Overall, we find a net global annual CH3I air–sea flux that ranges between 70 and 260 Gg yr−1. On the global scale, the ocean acts as a net source of methyl iodide for the atmosphere, though in some regions in boreal winter, fluxes are of the opposite direction (from the atmosphere to the ocean).

2013 ◽  
Vol 10 (11) ◽  
pp. 17549-17595 ◽  
Author(s):  
I. Stemmler ◽  
I. Hense ◽  
B. Quack ◽  
E. Maier-Reimer

Abstract. Production pathways of the prominent volatile organic halogen compound methyl iodide (CH3I) are not fully understood. Previous model studies suggest either production via photochemical degradation of organic material or rather phytoplankton production. Correlations between biological and environmental variables derived from observations also suggest both production pathways. In this study we aim to address this question of source mechanisms with a global three-dimensional ocean general circulation model including biogeochemistry (MPIOM-HAMOCC) by carrying out a series of sensitivity experiments. Simulated distribution patterns and emissions of CH3I differ largely for the different production pathways. However, the evaluation of our model results with observations from a newly available global data set shows that observed surface concentrations of CH3I can be best explained by the photochemical production pathway. Our results further emphasize that correlations between CH3I and abiotic or biotic factors do not necessarily provide meaningful insights concerning the source of origin. Overall, we find a net global annual CH3I air–sea flux that ranges between 70 and 260 Gg yr−1. Hence, at the global scale the ocean is a net source of methyl iodide for the atmosphere, though in some regions in boreal winter fluxes are of opposite direction (from the atmosphere to the ocean).


2002 ◽  
Vol 20 (5) ◽  
pp. 661-677 ◽  
Author(s):  
A. H. Manson ◽  
C. Meek ◽  
M. Hagan ◽  
J. Koshyk ◽  
S. Franke ◽  
...  

Abstract. In an earlier paper (Manson et al., 1999a) tidal data (1990–1997) from six Medium Frequency Radars (MFR) were compared with the Global Scale Wave Model (GSWM, original 1995 version). The radars are located between the equator and high northern latitudes: Christmas Island (2° N), Hawaii (22° N), Urbana (40° N), London (43° N), Saskatoon (52° N) and Tromsø (70° N). Common harmonic analysis was applied, to ensure consistency of amplitudes and phases in the 75–95 km height range. For the diurnal tide, seasonal agreements between observations and model were excellent while for the semi-diurnal tide the seasonal transitions between clear solstitial states were less well captured by the model. Here the data set is increased by the addition of two locations in the Pacific-North American sector: Yamagawa 31° N, and Wakkanai 45° N. The GSWM model has undergone two additional developments (1998, 2000) to include an improved gravity wave (GW) stress parameterization, background winds from UARS systems and monthly tidal forcing for better characterization of seasonal change. The other model, the Canadian Middle Atmosphere Model (CMAM) which is a General Circulation Model, provides internally generated forcing (due to ozone and water vapour) for the tides. The two GSWM versions show distinct differences, with the 2000 version being either closer to, or further away from, the observations than the original 1995 version. CMAM provides results dependent upon the GW parameterization scheme inserted, but one of the schemes provides very useful tides, especially for the semi-diurnal component.Key words. Meteorology and atmospheric dynamics (middle atmosphere dynamics; waves and tides)


2020 ◽  
Author(s):  
Linus Shihora ◽  
Henryk Dobslaw

<p>The Atmosphere and Ocean De-Aliasing Level-1B (AOD1B) product provides a priori information about temporal variations in the Earth's gravity field caused by global mass variability in the atmosphere and ocean and is routinely used as background model in satellite gravimetry. The current version 06 provides Stokes coefficients expanded up to d/o 180 every 3 hours. It is based on ERA-Interim and the ECMWF operational model for the atmosphere, and simulations with the global ocean general circulation model MPIOM consistently forced with the fields from the same atmospheric data-set.</p> <p>We here present preliminary numerical experiments in the development towards a new release 07 of AOD1B. The experiments are performed with the TP10 configuration of MPIOM and include (I) new hourly atmospheric forcing based on the new ERA-5 reanalysis from ECMWF; (II) an improved bathymetry around Antarctica including cavities under the ice shelves; and (III) an explicit implementation of the feedback effects of self-attraction and loading to ocean dynamics. The simulated ocean bottom pressure variability is discussed with respect to AOD1B version 6 as well as in situ ocean observations. A preliminary timeseries of hourly AOD1B-like coefficients for the year 2019 that incorporate the above mentioned improvements will be made available for testing purposes.</p>


2006 ◽  
Vol 3 (4) ◽  
pp. 1011-1063
Author(s):  
Z. Lachkar ◽  
J. C. Orr ◽  
J.-C. Dutay ◽  
P. Delecluse

Abstract. Global-scale tracer simulations are typically made at coarse resolution without explicitly modeling eddies. Here we ask what role do eddies play in ocean uptake, storage, and meridional transport of transient tracers. We made global anthropogenic transient-tracer simulations in non-eddying (2°cosφ×2°, ORCA2) and eddying (½°cosφ×½°, ORCA05) versions of the ocean general circulation model OPA9. We focus on the Southern Ocean where tracer air-sea fluxes are largest. Eddies have little effect on global and regional bomb Δ14C uptake and storage. Yet for anthropogenic CO2 and CFC-11, increased eddy activity reduces southern extratropical uptake by 28% and 25% respectively. There is a similar decrease in corresponding inventories, which provides better agreement with observations. With higher resolution, eddies strengthen upper ocean vertical stratification and reduce excessive ventilation of intermediate waters by 20% between 60° S and 40° S. By weakening the Residual Circulation, i.e., the sum of Eulerian mean flow and the opposed eddy-induced flow, eddies reduce the supply of tracer-impoverished deep waters to the surface near the Antarctic divergence, thus reducing the air-sea tracer flux. Consequently, inventories for both CFC-11 and anthropogenic CO2 decrease because their mixed layer concentrations in that region equilibrate with the atmosphere on relatively short time scales (15 days and 6 months, respectively); conversely, the slow air-sea equilibration of bomb Δ14C of 6 years, gives surface waters little time to exchange with the atmosphere before they are subducted.


2006 ◽  
Vol 19 (16) ◽  
pp. 3771-3791 ◽  
Author(s):  
E. Roeckner ◽  
R. Brokopf ◽  
M. Esch ◽  
M. Giorgetta ◽  
S. Hagemann ◽  
...  

Abstract The most recent version of the Max Planck Institute for Meteorology atmospheric general circulation model, ECHAM5, is used to study the impact of changes in horizontal and vertical resolution on seasonal mean climate. In a series of Atmospheric Model Intercomparison Project (AMIP)-style experiments with resolutions ranging between T21L19 and T159L31, the systematic errors and convergence properties are assessed for two vertical resolutions. At low vertical resolution (L19) there is no evidence for convergence to a more realistic climate state for horizontal resolutions higher than T42. At higher vertical resolution (L31), on the other hand, the root-mean-square errors decrease monotonically with increasing horizontal resolution. Furthermore, except for T42, the L31 versions are superior to their L19 counterparts, and the improvements become more evident at increasingly higher horizontal resolutions. This applies, in particular, to the zonal mean climate state and to the stationary wave patterns in boreal winter. As in previous studies, increasing horizontal resolution leads to a warming of the troposphere, most prominently at midlatitudes, and to a poleward shift and intensification of the midlatitude westerlies. Increasing the vertical resolution has the opposite effect, almost independent of horizontal resolution. Whereas the atmosphere is colder at low and middle latitudes, it is warmer at high latitudes and close to the surface. In addition, increased vertical resolution results in a pronounced warming in the polar upper troposphere and lower stratosphere, where the cold bias is reduced by up to 50% compared to L19 simulations. Consistent with these temperature changes is a decrease and equatorward shift of the midlatitude westerlies. The substantial benefits in refining both horizontal and vertical resolution give some support to scaling arguments deduced from quasigeostrophic theory implying that horizontal and vertical resolution ought to be chosen consistently.


2014 ◽  
Vol 10 (1) ◽  
pp. 359-375 ◽  
Author(s):  
F. Arfeuille ◽  
D. Weisenstein ◽  
H. Mack ◽  
E. Rozanov ◽  
T. Peter ◽  
...  

Abstract. As the understanding and representation of the impacts of volcanic eruptions on climate have improved in the last decades, uncertainties in the stratospheric aerosol forcing from large eruptions are now linked not only to visible optical depth estimates on a global scale but also to details on the size, latitude and altitude distributions of the stratospheric aerosols. Based on our understanding of these uncertainties, we propose a new model-based approach to generating a volcanic forcing for general circulation model (GCM) and chemistry–climate model (CCM) simulations. This new volcanic forcing, covering the 1600–present period, uses an aerosol microphysical model to provide a realistic, physically consistent treatment of the stratospheric sulfate aerosols. Twenty-six eruptions were modeled individually using the latest available ice cores aerosol mass estimates and historical data on the latitude and date of eruptions. The evolution of aerosol spatial and size distribution after the sulfur dioxide discharge are hence characterized for each volcanic eruption. Large variations are seen in hemispheric partitioning and size distributions in relation to location/date of eruptions and injected SO2 masses. Results for recent eruptions show reasonable agreement with observations. By providing these new estimates of spatial distributions of shortwave and long-wave radiative perturbations, this volcanic forcing may help to better constrain the climate model responses to volcanic eruptions in the 1600–present period. The final data set consists of 3-D values (with constant longitude) of spectrally resolved extinction coefficients, single scattering albedos and asymmetry factors calculated for different wavelength bands upon request. Surface area densities for heterogeneous chemistry are also provided.


2021 ◽  
Author(s):  
Linus Shihora ◽  
Henryk Dobslaw

<p>The Atmosphere and Ocean De-Aliasing Level-1B (AOD1B) product provides a priori information about temporal variations in the Earth's gravity field caused by global mass variability in the atmosphere and ocean and is routinely used as background model in satellite gravimetry. The current version 06 provides Stokes coefficients expanded up to d/o 180 every 3 hours. It is based on ERA-Interim and the ECMWF operational model for the atmosphere, and simulations with the global ocean general circulation model MPIOM consistently forced with the fields from the same atmospheric data-set.</p><p>We here present preliminary numerical experiments in the development towards a new release 07 of AOD1B. The experiments are performed with the TP10 configuration of MPIOM and include (I) new hourly atmospheric forcing based on the new ERA-5 reanalysis from ECMWF; (II) an improved bathymetry around Antarctica including cavities under the ice shelves and the consideration of shielding effects of the ice cover; and (III) an explicit implementation of the feedback effects of self-attraction and loading to ocean dynamics.</p>


1997 ◽  
Vol 25 ◽  
pp. 111-115 ◽  
Author(s):  
Achim Stössel

This paper investigates the long-term impact of sea ice on global climate using a global sea-ice–ocean general circulation model (OGCM). The sea-ice component involves state-of-the-art dynamics; the ocean component consists of a 3.5° × 3.5° × 11 layer primitive-equation model. Depending on the physical description of sea ice, significant changes are detected in the convective activity, in the hydrographic properties and in the thermohaline circulation of the ocean model. Most of these changes originate in the Southern Ocean, emphasizing the crucial role of sea ice in this marginally stably stratified region of the world's oceans. Specifically, if the effect of brine release is neglected, the deep layers of the Southern Ocean warm up considerably; this is associated with a weakening of the Southern Hemisphere overturning cell. The removal of the commonly used “salinity enhancement” leads to a similar effect. The deep-ocean salinity is almost unaffected in both experiments. Introducing explicit new-ice thickness growth in partially ice-covered gridcells leads to a substantial increase in convective activity, especially in the Southern Ocean, with a concomitant significant cooling and salinification of the deep ocean. Possible mechanisms for the resulting interactions between sea-ice processes and deep-ocean characteristics are suggested.


2006 ◽  
Vol 19 (16) ◽  
pp. 3903-3931 ◽  
Author(s):  
H. Schmidt ◽  
G. P. Brasseur ◽  
M. Charron ◽  
E. Manzini ◽  
M. A. Giorgetta ◽  
...  

Abstract This paper introduces the three-dimensional Hamburg Model of the Neutral and Ionized Atmosphere (HAMMONIA), which treats atmospheric dynamics, radiation, and chemistry interactively for the height range from the earth’s surface to the thermosphere (approximately 250 km). It is based on the latest version of the ECHAM atmospheric general circulation model of the Max Planck Institute for Meteorology in Hamburg, Germany, which is extended to include important radiative and dynamical processes of the upper atmosphere and is coupled to a chemistry module containing 48 compounds. The model is applied to study the effects of natural and anthropogenic climate forcing on the atmosphere, represented, on the one hand, by the 11-yr solar cycle and, on the other hand, by a doubling of the present-day concentration of carbon dioxide. The numerical experiments are analyzed with the focus on the effects on temperature and chemical composition in the mesopause region. Results include a temperature response to the solar cycle by 2 to 10 K in the mesopause region with the largest values occurring slightly above the summer mesopause. Ozone in the secondary maximum increases by up to 20% for solar maximum conditions. Changes in winds are in general small. In the case of a doubling of carbon dioxide the simulation indicates a cooling of the atmosphere everywhere above the tropopause but by the smallest values around the mesopause. It is shown that the temperature response up to the mesopause is strongly influenced by changes in dynamics. During Northern Hemisphere summer, dynamical processes alone would lead to an almost global warming of up to 3 K in the uppermost mesosphere.


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