Coupling geochemical and isotopic tracers (δ18O, δ2H and 87Sr/86Sr) to quantify groundwater mixing in carbonate environment

2021 ◽  
Author(s):  
Thibaut Garin ◽  
Bernard Ladouche ◽  
Bruno Arfib ◽  
Benoit Dewandel ◽  
Julio Goncalves
Keyword(s):  
Quantitative Estimation ◽  
Groundwater Resources ◽  
Mixing Processes ◽  
Isotopic Tracers ◽  
Dye Tracing ◽  
Rock Interaction ◽  
Marine Influence ◽  
End Members ◽  
Different Origins

<p>Carbonate aquifers are known as a major source for drinking water in the Mediterranean region. Therefore, qualitative and quantitative estimation of the groundwater resource are crucial, especially in area with densely populated areas.</p><p>In this study, geochemical and isotopic tracers (δ<sup>18</sup>O, δ<sup>2</sup>H and <sup>87</sup>Sr/<sup>86</sup>Sr) have been used to discriminate different origins of groundwater and evaluate water-mass mixing in a Mediterranean carbonate environment. The case study, located in south-eastern France, offers an attractive geological context to explore strontium isotopic tracers: trias to cretaceous carbonate rocks, that have been eroded and locally resedimented in fluvial deposits during Oligocene extension and Quaternary periods. Moreover, many karst features act as sinking zones, generating fast infiltration. The 500 km² zone investigated has also a large range of elevation, from the sea to 1148m, giving an expected significant contrast in water isotopes. Monthly water samples have been collected in-situ for two years on ground and surface waters, in rivers, boreholes as well as karstic springs. Monthly rainwater samples provide the isotopic signal of the recharge at two distinct elevations and distance from the sea.</p><p>The hydrogeochemical signatures allow to discriminate the end-members of two main waterbodies as well as a slight marine influence on one borehole. Nitrates concentrations (NO<sub>3</sub><sup>-</sup>) highlight anthropogenic influence on groundwater resources. A multi-tracer approach taking in account water-rock interaction, mixing processes and recharge, coupled with hydrogeological conditions and dye-tracing tests, leads to a conceptual model of this complex hydrosystem.</p>

Magmatic-Hydrothermal Mineralization Processes at the Yidong Tin Deposit, South China: Insights from In Situ Chemical and Boron Isotope Changes of Tourmaline

2021 ◽  
Author(s):  
He-Dong Zhao ◽  
Kui-Dong Zhao ◽  
Martin R. Palmer ◽  
Shao-Yong Jiang ◽  
Wei Chen
Keyword(s):  
South China ◽  
Hydrothermal Fluids ◽  
Boron Isotope ◽  
Granitic Magma ◽  
Gangue Mineral ◽  
Rock Interaction ◽  
Hydrothermal Mineralization ◽  
Mineralization Processes ◽  
Tin Deposit

Abstract Owing to the superimposition of water-rock interaction and external fluids, magmatic source signatures of ore-forming fluids for vein-type tin deposits are commonly overprinted. Hence, there is uncertainty regarding the involvement of magmatic fluids in mineralization processes within these deposits. Tourmaline is a common gangue mineral in Sn deposits and can crystallize from both the magmas and the hydrothermal fluids. We have therefore undertaken an in situ major, trace element, and B isotope study of tourmaline from the Yidong Sn deposit in South China to study the transition from late magmatic to hydrothermal mineralization. Six tourmaline types were identified: (1) early tourmaline (Tur-OE) and (2) late tourmaline (Tur-OL) in tourmaline-quartz orbicules from the Pingying granite, (3) early tourmaline (Tur-DE) and (4) late tourmaline (Tur-DL) in tourmaline-quartz dikelets in the granite, and (5 and 6) core (Tur-OC) and rim (Tur-OR), respectively of hydrothermal tourmaline from the Sn ores. Most of the tourmaline types belong to the alkali group and the schorl-dravite solid-solution series, but the different generations of magmatic and hydrothermal tourmaline are geochemically distinct. Key differences include the hundredfold enrichment of Sn in hydrothermal tourmaline compared to magmatic tourmaline, which indicates that hydrothermal fluids exsolving from the magma were highly enriched in Sn. Tourmaline from the Sn ores is enriched in Fe3+ compared to the hydrothermal tourmaline from the granite and displays trends of decreasing Al and increasing Fe content from core to rim, relating to the exchange vector Fe3+Al–1. This reflects oxidation of fluids during the interaction between hydrothermal fluids and the mafic-ultramafic wall rocks, which led to precipitation of cassiterite. The hydrothermal tourmaline has slightly higher δ11B values than the magmatic tourmaline (which reflects the metasedimentary source for the granite), but overall, the tourmaline from the ores has δ11B values similar to those from the granite, implying a magmatic origin for the ore-forming fluids. We identify five stages in the magmatic-hydrothermal evolution of the system that led to formation of the Sn ores in the Yidong deposit based on chemical and boron isotope changes of tourmaline: (1) emplacement of a B-rich, S-type granitic magma, (2) separation of an immiscible B-rich melt, (3) exsolution of an Sn-rich, reduced hydrothermal fluid, (4) migration of fluid into the country rocks, and (5) acid-consuming reactions with the surrounding mafic-ultramafic rocks and oxidation of the fluid, leading to cassiterite precipitation.

Developing an in situ, hydromechanical coupling, true triaxial rock compression tester and investigating the deformation patterns of reservoir bank slopes

2021 ◽  
pp. qjegh2021-043
Author(s):  
Lei Fan ◽  
Meiwan Yu ◽  
Aiqing Wu ◽  
Yihu Zhang
Keyword(s):  
Coupling Effect ◽  
Water Pressure ◽  
Pressure Coefficient ◽  
Hydromechanical Coupling ◽  
Rock Interaction ◽  
True Triaxial ◽  
Rock Structure ◽  
Deformation Patterns

Interactions between water and rocks are the main factors affecting the deformation of rock masses on sloped banks by reservoir impoundment. The technology used in laboratory tests of water-rock interaction mechanisms cannot simulate the coupling of water, the rock structure and the initial stress environment. In this work, we develop an in situ hydromechanical true triaxial rock compression tester and apply it to investigate the coupling response of reservoir bank rocks to changing groundwater levels. The tester is composed of a sealed chamber, loader, reactor, and device for measuring deformation, which are all capable of withstanding high water pressures, and a high-precision servo controller. The maximum axial load, lateral load and water pressure are 12 000 kN, 3 000 kN and 3 MPa, respectively. The dimensions of the test specimens are 310 mm×310 mm×620 mm. The test specimens are grey-black basalts with well-developed cracks from the Xiluodu reservoir area. The results show that increasing water pressure promotes axial compression and lateral expansion, while decreasing water pressure causes axial expansion and lateral compression. A water pressure coefficient, K, is introduced as a measure of the hydromechanical coupling effect (expansion or compression) with changing groundwater level. A mechanical tester can be used to perform accurate field tests of the response of wet rocks to hydromechanical coupling. The test results provide new information about the deformation patterns of rock slopes in areas surrounding high dams and reservoirs.Thematic collection: This article is part of the Role of water in destabilizing slopes collection available at: https://www.lyellcollection.org/cc/Role-of-water-in-destabilizing-slopes

In situ remediation potential for Southern African groundwater resources

2004 ◽  
pp. 143-150
Author(s):  
Pannie Engelbrecht ◽  
Sumaya Clarke ◽  
Gideon Tredoux
Keyword(s):  
Groundwater Resources ◽  
In Situ Remediation

Comment and Reply on "Nd isotopic gradients in upper crustal magma chambers: Evidence for in situ magma-wall-rock interaction"

Geology ◽  
1991 ◽  
Vol 19 (2) ◽  
pp. 185
Author(s):  
Benjamin C. Schuraytz ◽  
Thomas A. Vogel ◽  
Leland W. Younker ◽  
G. Lang Farmer ◽  
Kathryn J. Tegtmeyer
Keyword(s):  
Wall Rock ◽  
Magma Chambers ◽  
Rock Interaction ◽  
Crustal Magma

Oxygen, hydrogen, and strontium isotope constraints on the origin of granites

1988 ◽  
Vol 79 (2-3) ◽  
pp. 317-338 ◽  
Author(s):  
Hugh P. Taylor
Keyword(s):  
Large Scale ◽  
Wide Spectrum ◽  
Volcanic Field ◽  
Parent Material ◽  
Rock Interaction ◽  
Metasedimentary Rocks ◽  
Clear Cut ◽  
End Members ◽  
Type 3

ABSTRACTOxygen isotope data are very useful in determining the source rocks of granitic magmas, particularly when used in combination with Sr, Pb, and Nd isotope studies. For example, unusually high δ18O values in magmas (δ18O> +8) require the involvement of some precursor parent material that at some time in the past resided on or near the Earth's surface, either as sedimentary rocks or as weathered or hydrothermally altered rocks. The isotopic systematics which are preserved in the Mesozoic and Cenozoic batholiths of western North America can be explained by grand-scale mixing of three broadly defined end-members: (1) oceanic island-arc magmas derived from a “depleted” (MORB-type?) source in the upper mantle (δ18O c. +6 and 87Sr/86Sr c. 0·703); (2) a high-18O (c. +13 to +17) source with a very uniform 87Sr/86Sr (c. 0·708 to 0·712), derived mainly from eugeosynclinal volcanogenic sediments and (or) hydrothermally altered basalts; and (3) a much more heterogeneous source (87Sr/86Sr c. 0·706 to 0·750, or higher) with a high δ18O (c. +9 to +15) where derived from supracrustal metasedimentary rocks and a much lower δ18O (c. +7 to +9) where derived from the lower continental crust of the craton. These end-members were successively dominant from W to E, respectively, within three elongate N–S geographic zones that can be mapped from Mexico all the way N to Idaho.18O/16O studies (together with D/H analyses) can, however, play a more important and certainly a unique role in determining the origins of the aqueous fluids involved in the formation of granitic and rhyolitic magmas. Fluid-rock interaction effects are most clear-cut when low-18O, low-D meteoric waters are involved in the isotopic exchange and melting processes, but the effects of other waters such as seawater (with a relatively high δD c. 0) can also be recognised. Because of these hydrothermal processes, rocks that ultimately undergo partial melting may exhibit isotopic signatures considerably different from those that they started with. We discuss three broad classes of potential source materials of such “hydrothermal-anatectic” granitic magmas, based mainly on water/rock (w/r), temperature (T), and the length of time (t) that fluid-rock interaction proceeds: (Type 1) epizonal systems with a wide variation in whole-rock δ18O and extreme 18O/16O disequilibrium among coexisting minerals (e.g. quartz and feldspar); (Type 2) deeper-seated and (or) longer-lived systems, also with a wide spectrum of whole-rock δ18O, but with equilibrated 18O/16O ratios among coexisting minerals; (Type 3) thoroughly homogenised and equilibrated systems with relatively uniform δ18O in all lithologies. Low-18O magmas formed by melting of rocks altered in a Type 2 or a Type 3 meteoric-hydrothermal system are the only kinds of “hydrothermal-anatectic” granitic magmas that are readily recognisable in the geological record. Analogous effects produced by other kinds of aqueous fluids may, however, be quite common, particularly in areas of extensional tectonics and large-scale rifting. The greatly enhanced permeabilities in such fractured terranes make possible the deep convective circulation of ground waters and sedimentary pore fluids. The nature and origin of low-18O magmas in the Yellowstone volcanic field and the Seychelles Islands are briefly reviewed in light of these concepts, as is the development of high-D, peraluminous magmas in the Hercynian of the Pyrenees.

scholarly journals A Photometric Study of Regolith Intimate Mixing with Ice-Like Impurity

2021 ◽  
Author(s):  
Dwaipayan Deb ◽  
Pavan Chakraborty
Keyword(s):  
Solar System ◽  
Linear Trend ◽  
Geological Processes ◽  
Solar System Objects ◽  
Shadowing Effect ◽  
Mixing Proportion ◽  
In Situ Observations ◽  
End Members ◽  
Reflectance Data

Abstract Surfaces of solid solar system objects are covered by layers of particulate materials called regolith originated from their surface bedrock. They preserve important information about surface geological processes. Often regolith is composed of more than one type of particle in terms of composition, maturity, size, etc. Experiments and theoretical works are being carried out to constrain the result of mixing and extract the abundance of compositional end-members from regolith spectra. In this work we have studied, photometric light scattering from simulated surfaces made of two different materials – one is highly bright quartz particles ≈ 80µm and the other moderately bright sandstone particles ≈ 250µm. The samples were mixed with varying proportions and investigated at normal illumination conditions to avoid the shadowing effect. Said combinations may resemble ice mixed regolith on various solar system objects and therefore important for in situ observations. We find that the combinations show a linear trend in the corresponding reflectance data in terms of their mixing proportion and some interesting facts come out when compared to previous studies.

scholarly journals Hydrogeochemical Characteristics and Groundwater Quality Evaluation Based on Multivariate Statistical Analysis

Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2792
Author(s):  
Yunxu Chai ◽  
Changlai Xiao ◽  
Mingqian Li ◽  
Xiujuan Liang
Keyword(s):  
Water Quality ◽  
Groundwater Quality ◽  
Quality Evaluation ◽  
Control Mechanism ◽  
Groundwater Resources ◽  
Fuzzy Comprehensive Evaluation ◽  
Multivariate Statistical ◽  
Rock Interaction ◽  
Geological Conditions ◽  
Development And Management

Hydrogeochemical research and water quality evaluation are an important part of groundwater development and management projects in Dehui City, Jilin Province, China. We collected 217 groundwater samples in the study area and used two multivariate statistical methods, hierarchical cluster analysis and principal component analysis to classify groundwater; combined graphical method, piper diagram, and Gibbs diagram to characterize groundwater chemical types and distinguish the water chemical control mechanism; and fuzzy comprehensive evaluation method to evaluate groundwater quality. Three major categories have been identified. Most of the groundwater in the study area is Ca-HCO3 type water. The water chemistry control mechanism is determined to be based on water-rock interaction and less evaporation. From east to west in the study area, the total dissolved solids (TDS) gradually increased, and water quality gradually deteriorated. In the whole region, 79.26% of the groundwater is suitable for drinking. With Yinma River at the boundary, the water quality in the eastern part is excellent, while that in the southwest is poor. After appropriate treatment, it can be used in industry and agriculture. The excess NO3− is mainly affected by human activities. The unique geological conditions of the Songnen Plain result in an excess amount of Fe3+ and Mn2+ in some areas. This study determined the chemical characteristics of groundwater in the study area and distinguished water quality levels. The results will be helpful for the development and management of groundwater resources.

Sign in / Sign up

Export Citation Format

Share Document