scholarly journals Measuring air–sea gas exchange velocities in a large scale annular wind-wave tank

2014 ◽  
Vol 11 (3) ◽  
pp. 1643-1689 ◽  
Author(s):  
E. Mesarchaki ◽  
C. Kräuter ◽  
K. E. Krall ◽  
M. Bopp ◽  
F. Helleis ◽  
...  
Keyword(s):  
Gas Exchange ◽  
Large Scale ◽  
Wind Wave ◽  
Chemical Species ◽  
Surface States ◽  
Gas Transfer ◽  
Transfer Velocity ◽  
Wave Tank ◽  
Wide Range ◽  
Triton X

Abstract. In this study we present gas exchange measurements conducted in a large scale wind-wave tank. Fourteen chemical species spanning a wide range of solubility (dimensionless solubility, α = 0.4 to 5470) and diffusivity (Schmidt number in water, Scw = 594 to 1194) were examined under various turbulent (u10 = 0.8 to 15 m s−1 conditions. Additional experiments were performed under different surfactant modulated (two different concentration levels of Triton X-100) surface states. This paper details the complete methodology, experimental procedure and instrumentation used to derive the total transfer velocity for all examined tracers. The results presented here demonstrate the efficacy of the proposed method, and the derived gas exchange velocities are shown to be comparable to previous investigations. The gas transfer behaviour is exemplified by contrasting two species at the two solubility extremes, namely nitrous oxide (N2O) and methanol (CH3OH). Interestingly, a strong transfer velocity reduction (up to a factor of three) was observed for N2O under a surfactant covered water surface. In contrast, the surfactant affected CH3OH, the high solubility tracer only weakly.

scholarly journals Measuring air–sea gas-exchange velocities in a large-scale annular wind–wave tank

Ocean Science ◽  
2015 ◽  
Vol 11 (1) ◽  
pp. 121-138 ◽  
Author(s):  
E. Mesarchaki ◽  
C. Kräuter ◽  
K. E. Krall ◽  
M. Bopp ◽  
F. Helleis ◽  
...  
Keyword(s):  
Gas Exchange ◽  
Large Scale ◽  
Wind Wave ◽  
Chemical Species ◽  
Surface States ◽  
Gas Transfer ◽  
Transfer Velocity ◽  
Wave Tank ◽  
Wide Range ◽  
Triton X

Abstract. In this study we present gas-exchange measurements conducted in a large-scale wind–wave tank. Fourteen chemical species spanning a wide range of solubility (dimensionless solubility, α = 0.4 to 5470) and diffusivity (Schmidt number in water, Scw = 594 to 1194) were examined under various turbulent (u10 = 0.73 to 13.2 m s−1) conditions. Additional experiments were performed under different surfactant modulated (two different concentration levels of Triton X-100) surface states. This paper details the complete methodology, experimental procedure and instrumentation used to derive the total transfer velocity for all examined tracers. The results presented here demonstrate the efficacy of the proposed method, and the derived gas-exchange velocities are shown to be comparable to previous investigations. The gas transfer behaviour is exemplified by contrasting two species at the two solubility extremes, namely nitrous oxide (N2O) and methanol (CH3OH). Interestingly, a strong transfer velocity reduction (up to a factor of 3) was observed for the relatively insoluble N2O under a surfactant covered water surface. In contrast, the surfactant effect for CH3OH, the high solubility tracer, was significantly weaker.

scholarly journals First air–sea gas exchange laboratory study at hurricane wind speeds

2013 ◽  
Vol 10 (6) ◽  
pp. 1971-1996
Author(s):  
K. E. Krall ◽  
B. Jähne
Keyword(s):  
Wave Breaking ◽  
High Speed ◽  
Wind Wave ◽  
Breaking Waves ◽  
Gas Transfer ◽  
Transfer Velocity ◽  
Wind Speeds ◽  
Hurricane Wind ◽  
Wide Range ◽  
Enhanced Surface

Abstract. In a pilot study conducted in October and November 2011, air–sea gas transfer velocities of the two sparingly soluble trace gases hexafluorobenzene and 1,4-difluorobenzene were measured in the unique High-Speed Wind-Wave Tank at Kyoto University, Japan. This air–sea interaction facility is capable of producing hurricane strength wind speeds of up to u10=67 m s−1. This constitutes the first lab study of gas transfer at such high wind speeds. The measured transfer velocities k600 spanned two orders of magnitude, lying between 11 cm h−1 and 1180 cm h−1 with the latter being the highest ever measured wind induced gas transfer velocity. The measured gas transfer velocities are in agreement with the only available dataset at hurricane wind speeds (McNeil and D'Asaro, 2007). The disproportionately large increase of the transfer velocities found at highest wind speeds indicates a new regime of air–sea gas transfer, which is characterized by strong wave breaking, enhanced turbulence and bubble cloud entrainment. It was found that tracers spanning a wide range of solubilities and diffusivities are needed to separate the effects of enhanced surface area and turbulence due to breaking waves from the effects of bubble and spray mediated gas transfer.

scholarly journals Changes in gross oxygen production, net oxygen production, and air-water gas exchange during seasonal ice melt in the Bras d'Or Lake, a Canadian estuary

2017 ◽  
Author(s):  
Cara C. Manning ◽  
Rachel H. R. Stanley ◽  
David P. Nicholson ◽  
Brice Loose ◽  
Ann Lovely ◽  
...  
Keyword(s):  
Gas Exchange ◽  
Open Water ◽  
Gas Transfer ◽  
Polar Regions ◽  
Oxygen Production ◽  
Transfer Velocity ◽  
Gas Transfer Velocity ◽  
Ice Melt ◽  
Wide Range ◽  
Water Gas

Abstract. Sea ice is an important control on gas exchange and primary production in polar regions. We measured net oxygen production and gross oxygen production using near-continuous measurements of the O2 / Ar gas ratio and discrete measurements of the triple isotopic composition of O2 in the Bras d'Or Lake, an estuary in Nova Scotia, Canada, as the bay transitioned from ice-covered to ice-free conditions. The volumetric gross oxygen production was 5.4(+2.8−1.6) mmol O2 m−3 d−1, similar at the beginning and end of the time-series, and likely peaked at the end of the ice melt period. Net oxygen production displayed more temporal variability and the system was on average net autotrophic during ice melt and net heterotrophic following the ice melt. We performed the first field-based dual tracer release experiment in ice-covered water to quantify air-water gas exchange. The gas transfer velocity at > 90 % ice cover was 6 % of the rate for nearly ice-free conditions. Published studies have shown a wide range of results for gas transfer velocity in the presence of ice, and this study indicates that gas transfer through ice is much slower than the rate of gas transfer through open water. The results also indicate that both primary producers and heterotrophs are active in Whycocomagh Bay during spring while it is covered in ice.

scholarly journals Changes in gross oxygen production, net oxygen production, and air-water gas exchange during seasonal ice melt in Whycocomagh Bay, a Canadian estuary in the Bras d'Or Lake system

2019 ◽  
Vol 16 (17) ◽  
pp. 3351-3376
Author(s):  
Cara C. Manning ◽  
Rachel H. R. Stanley ◽  
David P. Nicholson ◽  
Brice Loose ◽  
Ann Lovely ◽  
...  
Keyword(s):  
Gas Exchange ◽  
Gas Transfer ◽  
Polar Regions ◽  
Oxygen Production ◽  
Transfer Velocity ◽  
Gas Transfer Velocity ◽  
Ice Melt ◽  
Lake System ◽  
Wide Range ◽  
Water Gas

Abstract. Sea ice is an important control on gas exchange and primary production in polar regions. We measured net oxygen production (NOP) and gross oxygen production (GOP) using near-continuous measurements of the O2∕Ar gas ratio and discrete measurements of the triple isotopic composition of O2, during the transition from ice-covered to ice-free conditions, in Whycocomagh Bay, an estuary in the Bras d'Or Lake system in Nova Scotia, Canada. The volumetric gross oxygen production was 5.4+2.8-1.6 mmol O2 m−3 d−1, similar at the beginning and end of the time series, and likely peaked at the end of the ice melt period. Net oxygen production displayed more temporal variability and the system was on average net autotrophic during ice melt and net heterotrophic following the ice melt. We performed the first field-based dual tracer release experiment in ice-covered water to quantify air–water gas exchange. The gas transfer velocity at >90 % ice cover was 6 % of the rate for nearly ice-free conditions. Published studies have shown a wide range of results for gas transfer velocity in the presence of ice, and this study indicates that gas transfer through ice is much slower than the rate of gas transfer through open water. The results also indicate that both primary producers and heterotrophs are active in Whycocomagh Bay during spring while it is covered in ice.

scholarly journals Sea-to-air and diapycnal nitrous oxide fluxes in the eastern tropical North Atlantic Ocean

2012 ◽  
Vol 9 (3) ◽  
pp. 957-964 ◽  
Author(s):  
A. Kock ◽  
J. Schafstall ◽  
M. Dengler ◽  
P. Brandt ◽  
H. W. Bange
Keyword(s):  
Nitrous Oxide ◽  
Gas Exchange ◽  
Mixed Layer ◽  
North Atlantic Ocean ◽  
Gas Transfer ◽  
Potential Contribution ◽  
Transfer Velocity ◽  
N2o Production ◽  
Gas Transfer Velocity ◽  
Upwelled Water

Abstract. Sea-to-air and diapycnal fluxes of nitrous oxide (N2O) into the mixed layer were determined during three cruises to the upwelling region off Mauritania. Sea-to-air fluxes as well as diapycnal fluxes were elevated close to the shelf break, but elevated sea-to-air fluxes reached further offshore as a result of the offshore transport of upwelled water masses. To calculate a mixed layer budget for N2O we compared the regionally averaged sea-to-air and diapycnal fluxes and estimated the potential contribution of other processes, such as vertical advection and biological N2O production in the mixed layer. Using common parameterizations for the gas transfer velocity, the comparison of the average sea-to-air and diapycnal N2O fluxes indicated that the mean sea-to-air flux is about three to four times larger than the diapycnal flux. Neither vertical and horizontal advection nor biological production were found sufficient to close the mixed layer budget. Instead, the sea-to-air flux, calculated using a parameterization that takes into account the attenuating effect of surfactants on gas exchange, is in the same range as the diapycnal flux. From our observations we conclude that common parameterizations for the gas transfer velocity likely overestimate the air-sea gas exchange within highly productive upwelling zones.

scholarly journals Surfactant control of gas transfer velocity along an offshore coastal transect: results from a laboratory gas exchange tank

2016 ◽  
Vol 13 (13) ◽  
pp. 3981-3989 ◽  
Author(s):  
R. Pereira ◽  
K. Schneider-Zapp ◽  
R. C. Upstill-Goddard
Keyword(s):  
Organic Matter ◽  
Gas Exchange ◽  
Trace Gas ◽  
Gas Transfer ◽  
Transfer Velocity ◽  
Chl A ◽  
Gas Transfer Velocity ◽  
Biogeochemical Models ◽  
Sea Surface Microlayer ◽  
Laboratory Water

Abstract. Understanding the physical and biogeochemical controls of air–sea gas exchange is necessary for establishing biogeochemical models for predicting regional- and global-scale trace gas fluxes and feedbacks. To this end we report the results of experiments designed to constrain the effect of surfactants in the sea surface microlayer (SML) on the gas transfer velocity (kw; cm h−1), seasonally (2012–2013) along a 20 km coastal transect (North East UK). We measured total surfactant activity (SA), chromophoric dissolved organic matter (CDOM) and chlorophyll a (Chl a) in the SML and in sub-surface water (SSW) and we evaluated corresponding kw values using a custom-designed air–sea gas exchange tank. Temporal SA variability exceeded its spatial variability. Overall, SA varied 5-fold between all samples (0.08 to 0.38 mg L−1 T-X-100), being highest in the SML during summer. SML SA enrichment factors (EFs) relative to SSW were  ∼  1.0 to 1.9, except for two values (0.75; 0.89: February 2013). The range in corresponding k660 (kw for CO2 in seawater at 20 °C) was 6.8 to 22.0 cm h−1. The film factor R660 (the ratio of k660 for seawater to k660 for “clean”, i.e. surfactant-free, laboratory water) was strongly correlated with SML SA (r ≥ 0.70, p ≤ 0.002, each n = 16). High SML SA typically corresponded to k660 suppressions  ∼  14 to 51 % relative to clean laboratory water, highlighting strong spatiotemporal gradients in gas exchange due to varying surfactant in these coastal waters. Such variability should be taken account of when evaluating marine trace gas sources and sinks. Total CDOM absorbance (250 to 450 nm), the CDOM spectral slope ratio (SR = S275 − 295∕S350 − 400), the 250 : 365 nm CDOM absorption ratio (E2 : E3), and Chl a all indicated spatial and temporal signals in the quantity and composition of organic matter in the SML and SSW. This prompts us to hypothesise that spatiotemporal variation in R660 and its relationship with SA is a consequence of compositional differences in the surfactant fraction of the SML DOM pool that warrants further investigation.

scholarly journals Coastal Wave Extremes around the Pacific and Their Remote Seasonal Connection to Climate Modes

Climate ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 168
Author(s):  
Julien Boucharel ◽  
Loane Santiago ◽  
Rafael Almar ◽  
Elodie Kestenare
Keyword(s):  
Large Scale ◽  
Wind Wave ◽  
Boreal Summer ◽  
Opposite Hemisphere ◽  
Ocean Surface Waves ◽  
First Order ◽  
Coastal Waves ◽  
The Pacific ◽  
Wide Range ◽  
The Tropics

At first order, wind-generated ocean surface waves represent the dominant forcing of open-coast morpho-dynamics and associated vulnerability over a wide range of time scales. It is therefore paramount to improve our understanding of the regional coastal wave variability, particularly the occurrence of extremes, and to evaluate how they are connected to large-scale atmospheric regimes. Here, we propose a new “2-ways wave tracking algorithm” to evaluate and quantify the open-ocean origins and associated atmospheric forcing patterns of coastal wave extremes all around the Pacific basin for the 1979–2020 period. Interestingly, the results showed that while extreme coastal events tend to originate mostly from their closest wind-forcing regime, the combined influence from all other remote atmospheric drivers is similar (55% local vs. 45% remote) with, in particular, ~22% coming from waves generated remotely in the opposite hemisphere. We found a strong interconnection between the tropical and extratropical regions with around 30% of coastal extremes in the tropics originating at higher latitudes and vice-versa. This occurs mostly in the boreal summer through the increased seasonal activity of the southern jet-stream and the northern tropical cyclone basins. At interannual timescales, we evidenced alternatingly increased coastal wave extremes between the western and eastern Pacific that emerge from the distinct seasonal influence of ENSO in the Northern and SAM in the Southern Hemisphere on their respective paired wind-wave regimes. Together these results pave the way for a better understanding of the climate connection to wave extremes, which represents the preliminary step toward better regional projections and forecasts of coastal waves.

scholarly journals A parameter model of gas exchange for the seasonal sea ice zone

Ocean Science ◽  
2014 ◽  
Vol 10 (1) ◽  
pp. 17-28 ◽  
Author(s):  
B. Loose ◽  
W. R. McGillis ◽  
D. Perovich ◽  
C. J. Zappa ◽  
P. Schlosser
Keyword(s):  
Boundary Layer ◽  
Gas Exchange ◽  
Sea Ice ◽  
Open Water ◽  
Field Studies ◽  
The Arctic ◽  
Gas Transfer ◽  
Transfer Velocity ◽  
Using Data ◽  
Effective Transfer

Abstract. Carbon budgets for the polar oceans require better constraint on air–sea gas exchange in the sea ice zone (SIZ). Here, we utilize advances in the theory of turbulence, mixing and air–sea flux in the ice–ocean boundary layer (IOBL) to formulate a simple model for gas exchange when the surface ocean is partially covered by sea ice. The gas transfer velocity (k) is related to shear-driven and convection-driven turbulence in the aqueous mass boundary layer, and to the mean-squared wave slope at the air–sea interface. We use the model to estimate k along the drift track of ice-tethered profilers (ITPs) in the Arctic. Individual estimates of daily-averaged k from ITP drifts ranged between 1.1 and 22 m d−1, and the fraction of open water (f) ranged from 0 to 0.83. Converted to area-weighted effective transfer velocities (keff), the minimum value of keff was 10−55 m d−1 near f = 0 with values exceeding keff = 5 m d−1 at f = 0.4. The model indicates that effects from shear and convection in the sea ice zone contribute an additional 40% to the magnitude of keff, beyond what would be predicted from an estimate of keff based solely upon a wind speed parameterization. Although the ultimate scaling relationship for gas exchange in the sea ice zone will require validation in laboratory and field studies, the basic parameter model described here demonstrates that it is feasible to formulate estimates of k based upon properties of the IOBL using data sources that presently exist.

scholarly journals Evidence for surface organic matter modulation of air-sea CO<sub>2</sub> gas exchange

2009 ◽  
Vol 6 (6) ◽  
pp. 1105-1114 ◽  
Author(s):  
M. Ll. Calleja ◽  
C. M. Duarte ◽  
Y. T. Prairie ◽  
S. Agustí ◽  
G. J. Herndl
Keyword(s):  
Organic Matter ◽  
Wind Speed ◽  
Gas Exchange ◽  
Co2 Exchange ◽  
Open Ocean ◽  
Gas Transfer ◽  
Co2 Fluxes ◽  
Transfer Velocity ◽  
Gas Transfer Velocity

Abstract. Air-sea CO2 exchange depends on the air-sea CO2 gradient and the gas transfer velocity (k), computed as a function of wind speed. Large discrepancies among relationships predicting k from wind suggest that other processes also contribute significantly to modulate CO2 exchange. Here we report, on the basis of the relationship between the measured gas transfer velocity and the organic carbon concentration at the ocean surface, a significant role of surface organic matter in suppressing air-sea gas exchange, at low and intermediate winds, in the open ocean, confirming previous observations. The potential role of total surface organic matter concentration (TOC) on gas transfer velocity (k) was evaluated by direct measurements of air-sea CO2 fluxes at different wind speeds and locations in the open ocean. According to the results obtained, high surface organic matter contents may lead to lower air-sea CO2 fluxes, for a given air-sea CO2 partial pressure gradient and wind speed below 5 m s−1, compared to that observed at low organic matter contents. We found the bias in calculated gas fluxes resulting from neglecting TOC to co-vary geographically and seasonally with marine productivity. These results support previous evidences that consideration of the role of organic matter in modulating air-sea CO2 exchange may improve flux estimates and help avoid possible bias associated to variability in surface organic concentration across the ocean.

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