Elemental quantification, chemistry, and source apportionment in golf course facilities in semi-arid urban landscape using portable x-ray fluorescence spectrometer
Abstract. This study extends the application of the portable x-ray fluorescence (PXRF) spectrometry to examination of elements in semi-arid urban landscapes of the Southern High Plains (SHP) of the United States (US), focusing on golf courses. The complex environmental challenges of this region and the unique management practices at golf course facilities could lead to differences in concentration and chemistry of elements between managed (irrigated) and non-managed (non-irrigated) portions of these facilities. Soil samples were collected at the depths of 0–10, 10–20, and 20–30 cm from managed and non-managed areas of seven different facilities in the city of Lubbock, Texas, and analyzed for a suite of soil properties. Total elemental quantification was conducted using PXRF. Findings mostly indicated no significant differences in concentration of examined elements between the managed and non-managed areas of the facilities. However, strong positive relationships (R2 = 0.82–0.91, p < 0.001) were observed among elements (e.g. Fe and each of Cr, Mn, Ni, and As; Cu and Zn; As and Cr) and between these elements and soil constituents or properties such as clay, calcium carbonate, organic matter, and pH. The strengths of these relationships were mostly higher in the non-managed areas, suggesting possible alteration in the chemistry of these elements by anthropogenic influences. Principal component analyses (PCA) and correlation analyses within the managed areas suggested that As, Cr, Fe, Mn, and Ni could be of lithogenic origin, while Cu, Pb, and Zn were attributed to anthropogenic influences. Only one possible source of element, likely lithogenic, was identified within non-managed areas. As evidenced from the study, the PXRF can be a valuable tool for elemental quantification, and rapid investigation of elemental interaction and source apportionment in semi-arid climates.