Intercalated Montmorillonites as Fillers for Acrylonitrile-Butadiene Rubber

2007 ◽  
Vol 80 (2) ◽  
pp. 279-295 ◽  
Author(s):  
Marian Zaborski ◽  
Anna Kunert ◽  
Joanna Pietrasik ◽  
Malgorzata Iwona Szynkowska ◽  
Ewa Lesniewska
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Butadiene Rubber ◽  
Acrylonitrile Butadiene Rubber ◽  
Modified Montmorillonite ◽  
Roll Mill ◽  
Filler Network ◽  
Long Chains

Abstract Modified montmorillonite was used as filler for NBR. The effect of the montmorillonite structure and its concentration was studied. The composites were prepared with the use of a laboratory two-roll mill. Unmodified montmorillonite (MM_Na) agglomerated in NBR rubber resulting only in small enhancement of mechanical properties. The most effective exfoliation of the montmorillonite was observed for the modifier with two long chains (dihydrotallowdimethylammonium chloride (2M2HT)) and at its higher concentration (C1). The modified filler did not agglomerate in NBR. The montmorillonite (MM_2M2HT(C1)) formed a secondary filler network. This very well dispersed network demonstrated the strong reinforcement. Increasing the content of MM_2M2HT(C1) to 20 parts by wt. improved significantly the tensile strength of NBR vulcanizates (tensile strength > 25 MPa). Montmorillonite intercalated with hydrotallowdimethylbenzylammonium chloride (MM_2MBHT) did not improve the properties of the studied materials.

Properties of High Density Polyethylene (HDPE)/Recycled Acrylonitrile Butadiene Rubber (NBRr)/Banana Skin Powder (BSP) Composites: Oven Ageing

2015 ◽  
Vol 754-755 ◽  
pp. 197-200
Author(s):  
Ragunathan Santiagoo ◽  
Kamarudin Hussin ◽  
Sam Sung Ting ◽  
Azlinda Abdul Ghani ◽  
Hanafi Ismail ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Thermal Degradation ◽  
High Density Polyethylene ◽  
Thin Sheet ◽  
Heat Exposure ◽  
Testing Machine ◽  
High Density ◽  
Butadiene Rubber ◽  
Acrylonitrile Butadiene Rubber ◽  
Roll Mill

The thermal degradation of high density polyethylene (HDPE)/ recycled acrylonitrile butadiene rubber (NBRr)/ banana skin powder (BSP) composites with and without ENR-50 are fabricated and studied. The thermal degradation of this composite was evaluated for 30 days oven ageing. The BSP with size of 150 – 300 μm was utilized in this work. All compounds were mixed using heated two roll mill at 180 °C. The compounds were molded in a hot press machine at 180 °C for 11 minutes to produce 1 mm thin sheet. Then the sheet were cut into dumbbell shape for the mechanical testing using universal testing machine. The tensile strength of high density polyethylene/ recycled acrylonitrile butadiene rubber/ banana skin powder composites showed the decreasing trend with the increasing NBRr loading for the composites with and without ENR-50. However, the result for the oven ageing showed lower tensile strength. This may due to the chain session of PP matrix at heat exposure duration of 30 days.

Effects of APS Silane on Tensile Properties of Polypropylene (PP)/Recycled Acrylonitrile Butadiene Rubber (NBRr)/Banana Skin Powder (BSP) Composites

2016 ◽  
Vol 1133 ◽  
pp. 180-184
Author(s):  
Azlinda Abdul Ghani ◽  
Ragunathan Santiagoo ◽  
Tunku Alisha Zanariah Tunku Ozir ◽  
Sam Sung Ting ◽  
Hanafi Ismail
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Coupling Agent ◽  
Young's Modulus ◽  
Filler Loading ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Acrylonitrile Butadiene Rubber ◽  
Morphological Studies ◽  
Roll Mill

Polypropylene (PP)/ recycled acrylonitrile butadiene rubber (NBRr)/ banana skin powder (BSP) composites with different BSP filler loading (5,10,15,20,25,30wt. %) were studied. Composites were prepared by using heated two roll mill at 180 °C. The effect of 3-aminopropyltrimethoxysilane (APS) as coupling agent were evaluated. Mechanical properties such as tensile strength, Young’s Modulus and Elongation at Break (Eb) of the different composites were investigated. Tensile strength and Elongation at break of the composites were found to be decreasing with increasing BSP filler loading. The Young’s Modulus was found to be increasing with BSP filler loading due increment of composite rigidity. At similar BSP filler loadings, γ-APS treated BSP composites shows higher tensile strength and Young’s Modulus. This may due to strong bonding between BSP filler and PP/NBRr matrices in the presence of APS silane coupling agent. The morphological studies strongly support this findings whereby good interaction and less pull outs of BSP filler was noticed in the presence of APS silane.

scholarly journals Studying the physical and mechanical properties of Acrylonitrile butadiene rubber / carbon / clinke

2021 ◽  
Vol 28 (1) ◽  
pp. 110-116
Author(s):  
Ali Alhaidar ◽  
Ali Ali ◽  
Mayssa Shash
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Abrasion Resistance ◽  
Chemical Properties ◽  
Physical And Mechanical Properties ◽  
Filling Material ◽  
Butadiene Rubber ◽  
Rubber Blends ◽  
Roll Mill ◽  
And Chemical Properties

This research studies the effect of adding the clinker as a filling material on the properties of Acrylonitrilebutadiene rubber NBR ،by means of preparing rubber blends containing different percentage (0,5,10,15,20 Phr) of theclinker (Semi made-cement) ،on two roll mill. Physio -mechanical and chemical properties of the prepared blends weredescribed by testing them for tensile strength and abrasion resistance, values of hardness and swelling in differentsolvents. Results revealed a decrease in the tension resistance for rubber blends c/k at the percentage of 45% withincrease of the percentage of the clinker added with the above mentioned rubber blends ,Also ,values of hardnessdecreased direct proportional at a percentage of 19% with increasing the clinker ,percentage whereas, the frictionresistance decreased at a percentage of 254% with increasing the clinker percentage ,but according to elongation ,theresults were quite different from the previous results so that its percentage increased when cutting gradually with thevalue of 266%when percentage of added clinker increased. Results of the study also, revealed that swelling of thesamples containing only the black carbon (C45K0) was low comparing with the samples containing the clinker.

scholarly journals Enhanced compatibility, morphology, rheological and mechanical properties of carboxylated acrylonitrile butadiene rubber/chloroprene rubber/graphene nanocomposites: effect of compatibilizer and graphene content

RSC Advances ◽  
2020 ◽  
Vol 10 (20) ◽  
pp. 11777-11790
Author(s):  
Mohammad Javad Azizli ◽  
Sheida Rezaeinia ◽  
Katayoon Rezaeeparto ◽  
Masoud Mokhtary ◽  
Fahimeh Askari
Keyword(s):  
Mechanical Properties ◽  
Glycidyl Methacrylate ◽  
Butadiene Rubber ◽  
Graphene Nanocomposites ◽  
Acrylonitrile Butadiene Rubber ◽  
Roll Mill ◽  
Chloroprene Rubber ◽  
Graphene Content

Elastomeric nanocomposites were prepared from carboxylated acrylonitrile butadiene rubber/chloroprene rubber (XNBR/CR), graphene and a glycidyl methacrylate (GMA)-grafted XNBR (XNBR-g-GMA) compatibilizer by using a two-roll mill.

scholarly journals The effect of carbon black on the curing and mechanical properties of natural rubber/ acrylonitrile- butadiene rubber composites

2021 ◽  
Vol 19 (3) ◽  
pp. 194-201
Author(s):  
H. Boukfessa ◽  
B. Bezzazi
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Carbon Black ◽  
Natural Rubber ◽  
Abrasion Resistance ◽  
Tensile Modulus ◽  
Butadiene Rubber ◽  
Rubber Composites ◽  
Acrylonitrile Butadiene Rubber ◽  
Different Content

The present work investigates the effect of the amount of carbon black on curing and mechanical properties such as tensile strength, elongation at break, hardness and abrasion resistance of the natural rubber (NR)/ acrylonitrile-butadiene rubber (NBR) blend. For that purpose, a blend composed of 65% NR and 35% NBR filled with different content of carbon black N330 was used. The curing results indicate that the viscosity and the crosslink density of rubber composites increase and the scorch and curing times decrease with increasing the filler content. Mechanical properties such as tensile modulus and hardness of the CB filled NR/NBR blend were remarkably improved, indicating the inherent reinforcing potential of CB. Regarding tensile strength and abrasion resistance, they increase with the addition of carbon black, up to 50 phr. After that, these properties decrease slightly with filleraddition.

Elastomer nanocomposites based on NBR/BR/nanoclay: morphology and mechanical properties

2013 ◽  
Vol 33 (2) ◽  
pp. 133-139 ◽  
Author(s):  
Shohreh Tolooei ◽  
Ghasem Naderi ◽  
Shirin Shokoohi ◽  
Sedigheh Soltani
Keyword(s):  
Mechanical Properties ◽  
Polymer Chains ◽  
Butadiene Rubber ◽  
Cure Characteristics ◽  
Fluid Uptake ◽  
Roll Mill ◽  
Dispersion State ◽  
Cure Time ◽  
Diffraction Patterns ◽  
Nanoclay Content

Abstract Ternary elastomer nanocomposites based on acrylonitrile butadiene rubber (NBR), polybutadiene rubber (BR) and two types of nanoclay (Cloisite 15A and Cloisite 30B) were prepared using a laboratory scale two-roll mill. The effects of nanoclay composition on the cure characteristics, mechanical properties and morphology of NBR/BR (50/50) nanocomposite samples containing 3, 5, 7 and 10 wt% nanoclay were investigated. According to the cure characteristics both types of nanoclay caused a reduction in the scorch time and optimum cure time of the nanocomposite compound. X-ray diffraction patterns of all samples suggested the intercalation of polymer chains into the silicate layers. This was confirmed by transmission electron microscopy (TEM) micrographs. Dynamic mechanical thermal analysis (DMTA) was utilized to study the dispersion state of nanoclay within the elastomer blend matrix. The results showed the development of mechanical properties with the establishment of interactions between nanoclay and polymer chains. Antiknock and brake fluid uptake were also reduced with increasing the nanoclay content.

scholarly journals Utilization of Leather Waste Fibers in Polymer Matrix Composites Based on Acrylonitrile-Butadiene Rubber

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 117
Author(s):  
Le Thuy Hang ◽  
Do Quoc Viet ◽  
Nguyen Pham Duy Linh ◽  
Vu Anh Doan ◽  
Hai-Linh Thi Dang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polymer Matrix Composites ◽  
Waste Product ◽  
Dynamic Mechanical Properties ◽  
Hammer Mill ◽  
Butadiene Rubber ◽  
Matrix Composites ◽  
Leather Industry ◽  
Tear Strength

In this study, we present the fabrication of nitrile butadiene rubber/waste leather fiber (NBR/WLF) composites with different weight percentages of WLF and NBR (0/100, 20/80, 30/70, 40/60, 50/50, 60/40 wt/wt). WLF was prepared by cutting the scrap leathers from the waste product of the Vietnamese leather industry. Subsequently, in order to make the short fibers, it was mixed by a hammer mill. The characteristics of WLF/NBR composites such as mechanical properties (tensile strength, tear strength, hardness), dynamic mechanical properties, toluene absorption, and morphology were carefully evaluated. As a result, the tensile strength and tear strength become larger with increasing WLF content from 0 to 50 wt% and they decrease when further increasing WLF content. The highest tensile strength of 12.5 MPa and tear strength of 72.47 N/mm were achieved with the WLF/NBR ratio of 50/50 wt%. Both hardness and resistance of the developed materials with toluene increased with increasing WLF content. The SEM results showed a good adhesion of NBR matrix and the WLF. The increasing of storage modulus (E’) in comparison with raw NBR showed good compatibility between WLF and NBR matrix. This research showed that the recycled material from waste leather and NBR was successfully prepared and has great potential for manufacturing products such as floor covering courts and playgrounds, etc.

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