scholarly journals Comparison of Surface Characteristics and Adsorption Rate of Benzene Vapor According to Modifications of Activated Carbon

2008 ◽  
Vol 17 (8) ◽  
pp. 919-924 ◽  
Author(s):  
Song-Woo Lee ◽  
Sang-Kyu Kam ◽  
Min-Gyu Lee
2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Lingjie Liu ◽  
Min Ji ◽  
Fen Wang

Coconut granular activated carbon (CGAC) was modified by impregnating with ZnCl2solution to remove nitrate from aqueous solutions. Sorption isotherm and kinetic studies were carried out in a series of batch experiments. Nitrate adsorption of both ZnCl2-modified CGAC and CGAC fitted the Langmuir and Freundlich models. Batch adsorption isotherms indicated that the maximum adsorption capacities of ZnCl2-modified CGAC and CGAC were calculated as 14.01 mgN·g−1and 0.28 mgN·g−1, respectively. The kinetic data obtained from batch experiments were well described by pseudo-second-order model. The column study was used to analyze the dynamic adsorption process. The highest bed adsorption capacity of 1.76 mgN·g−1was obtained by 50 mgN·L−1inlet nitrate concentration, 20 g adsorbents, and 10 ml·min−1flow rate. The dynamic adsorption data were fitted well to the Thomas and Yoon–Nelson models with coefficients of correlationR2 > 0.834 at different conditions. Surface characteristics and pore structures of CGAC and ZnCl2-modified CGAC were performed by SEM and EDAX and BET and indicated that ZnCl2had adhered to the surface of GAC after modified. Zeta potential, Raman spectra, and FTIR suggested the electrostatic attraction between the nitrate ions and positive charge. The results revealed that the mechanism of adsorption nitrate mainly depended on electrostatic attraction almost without any chemical interactions.


1993 ◽  
Vol 19 (5) ◽  
pp. 803-808 ◽  
Author(s):  
Yoshitaka Sudo ◽  
Takuji Yamamoto ◽  
Motoyuki Suzuki

Author(s):  
S. Manocha ◽  
Parth Joshi ◽  
Amit Brahmbhatt ◽  
Amiya Banerjee ◽  
Snehasis Sahoo ◽  
...  

In the present work, a one step carbon activation process was developed by stabilized poly-blend. It is carbonized in nitrogen atmosphere and activated in steam in one step for known interval of times to enhance the surface area and develop interconnected porosity. The weight-loss behavior during steam activation of stabilized poly-blend at different temperatures, surface area and pore size distribution were studied to identify the optimum synthesis parameters. The results of surface characteristics were compared with those of activated carbon prepared by carbonization and activation in two steps. It was found that activation temperature has profound effect on surface characteristics. As activation temperature was raised from 800 °C to 1150 °C, surface area of activated carbon increased about three times. In addition to surface area, average pore diameter also increases with increasing activation temperature. Thus, activated carbon with high percentage of porosity and surface area can be developed by controlling the activation temperature during activation process.


2021 ◽  
Vol 1162 ◽  
pp. 65-73
Author(s):  
Rakhmawati Farma ◽  
Ona Lestari ◽  
Erman Taer ◽  
Apriwandi ◽  
Minarni ◽  
...  

Heavy metal such as Cu, Fe, and Zn are the most serious contributers to environmental problems. The removal of heavy metal from the environment is the research interest nowdays. The adsorption of Cu, Fe and Zn from wastewater was investigated with various activated carbons as adsorbents. The activated carbons were produced from oil palm leaves by using multi-activation methods. The H3PO4, NaOH, ZnCl2 and KOH were chosen as chemical activating agents. Batch adsorption experiment was used to test the ability of activated carbon to remove Cu, Fe, and Zn from wastewater. The surface characteristics of activated carbon were evaluated using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption-desorption isotherms. The Activated carbons were able to purify wastewater with a maximum turbidity level of 2.83 NTU. The AC-H3PO4 activated carbon showed the highest absorbability of Cu metal as 91.540%, while the highest absorbabilities of Zn and Fe metals were indicated by AC-KOH activated carbon of 22.853% and 82.244% absorption respectively. Therefore, these results enable the oil palm leaves to become a high potential for activated carbon as removal the heavy metals.


2013 ◽  
Vol 807-809 ◽  
pp. 1343-1346
Author(s):  
Yi Fan Li ◽  
Ying Liu ◽  
Hou Qi Liu ◽  
Li Li

The research used activated carbon fiber (ACF) as adsorbent to remove atrazine, a kind of herbicide. It set a series of static adsorption experiments under different solution temperature, pH value and initial concentration to get a optimum adsorption condition. The experiment shows that the optimum pH for the removal of atrazine is 7. The adsorption rate is highest at 20°C. The adsorption rate decreases while the initial concentration increases.


2014 ◽  
Vol 9 (2) ◽  
pp. 155892501400900 ◽  
Author(s):  
Wei Liu ◽  
Sabit Adanur

Activated carbon fibers (ACFs) are one of the most promising adsorbents due to their outstanding properties, such as more exposed adsorption surface, narrower pore size distribution, fast adsorption rate and flexibility, in comparison with granular activated carbon and activated carbon powder. In this work, ACFs manufactured from various raw materials were studied and their pore structures and sulfur dioxide removal performance under dry and humid conditions were investigated. From the ACFs studied in this paper, larger surface area was found correspond to higher total pore volume and larger DA micropore diameter. In dry air, breakthrough capacity of ACFs with sulfur dioxide was found to be proportionately dependent on micropore ratio and pore size distribution. Although powdered activated carbon (PAC) showed higher breakthrough capacity, its adsorption rate was slower than ACFs due to the difference of the pore structure. The presence of water vapor in the air stream greatly increased SO2 adsorption capacities of ACFs but affected their utilization differently.


2021 ◽  
Vol 93 ◽  
pp. 267-278
Author(s):  
E. García-Hernández ◽  
C.G. Aguilar-Madera ◽  
E.C. Herrera-Hernández ◽  
R. Ocampo-Pérez ◽  
E. Bailón-García ◽  
...  

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