INTEGRATED ASSESSMENT OF CHEMICAL TECHNOLOGIES USING OPTICAL METHODS

Author(s):  
Irina Guskova
Author(s):  
A. Legrouri

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.


Author(s):  
H. Seiler ◽  
U. Haas ◽  
K.H. Körtje

The physical properties of small metal particles reveal an intermediate position between atomic and bulk material. Especially Ag has shown pronounced size effects. We compared silver layers evaporated in high vacuum with cluster layers of small silver particles, evaporated in N2 at a pressure of about 102 Pa. The investigations were performed by electron optical methods (TEM, SEM, EELS) and by Photoacoustic (PA) Spectroscopy (gas-microphone detection).The observation of cluster layers with TEM and high resolution SEM show small silver particles with diameters of about 50 nm (Fig. 1 and Figure 2, respectively). The electron diffraction patterns of homogeneous Ag layers and of cluster layers are similar, whereas the low loss EELS spectra due to plasmon excitation are quite different. Fig. 3 and Figure 4 show first results of EELS spectra of a cluster layer of small silver particles on carbon foil and of a homogeneous Ag layer, respectively.


2020 ◽  
pp. 44-49
Author(s):  
I. N. Pavlov

Two optical methods, namely surface plasmon resonance imaging and frustrated total internal reflection, are described in the paper in terms of comparing their sensitivity to change of refractive index of a thin boundary layer of an investigated medium. It is shown that, despite the fact that the theoretically calculated sensitivity is higher for the frustrated total internal reflection method, and the fact that usually in practice the surface plasmon resonance method, on the contrary, is considered more sensitive, under the same experimental conditions both methods show a similar result.


2014 ◽  
pp. 111-141 ◽  
Author(s):  
Maria Cerreta ◽  
Pasquale De Toro ◽  
Girard Luigi Fusco

2019 ◽  
Vol 6 (4) ◽  
pp. 60-65
Author(s):  
Elena Vyacheslavovna Zaytseva

The problem statement (relevance). The article illustrates the outcome of analytical research in the area of substantiation of organizational and managerial structures of cement companies on the basis of conducting an integral estimation of complex conditions of operation (manufacturability of mining and geological conditions of cement production, level of production and technical conditions and social conditions) and outputs (production and technical level and financial level). Integrated assessment is provided by the appropriate methodology, the purpose of which supports an increase in the objectivity, reliability and reliability of decisions in the development of technological systems of cement enterprises.Purpose: development of an enlarged flowchart of the decision-making procedure algorithm for development strategies for cement enterprises. Methods used: the work used the method of “vector norm”, based on the methodological principles of the theory of complex decision making, utility theory, game theory, qualimetry, expert survey method and other generally accepted methods and principles.Novelty. The elements of novelty include an improved method of integrated assessment of the technological structure of cement enterprises in the conditions of external and internal environments of operation.Result. The article presents an iterative algorithm and decision-making procedure for structurally selected groups of cement enterprises with the choice of a specific form of their development. The results of the work made it possible to form the key areas of training and a list of information technologies that ensure technological readiness for the implementation of the directions of digitalization in relation to cement enterprises.Practical significance: the organizational and management apparatus with the appropriate mathematical reinforcement for the selection and justification of strategies for the development of cement enterprises. The practical implication of the outcome of the study due to the possibility to increase the effectiveness of organizational-technological and managerial solutions based on the developed methodology, technique and algorithm of formation of innovative strategy of development of the mining enterprises of the cement industry. The main provisions of the work are used in the holding “EUROCEMENT” in the development and implementation of plans for the development of industrial production in the short and long term.


2011 ◽  
Vol 17 (6) ◽  
pp. 30-44
Author(s):  
Yu.V. Kostyuchenko ◽  
◽  
M.V. Yushchenko ◽  
I.M. Kopachevskyi ◽  
S. Levynsky ◽  
...  

2009 ◽  
Vol 10 (4) ◽  
pp. 85-103 ◽  
Author(s):  
김석태 ◽  
김태인

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