scholarly journals Sonochemical Formation of Peracetic Acid in Batch Reactor: Process Intensification and Kinetic Study

Author(s):  
Prashant D. Jolhe ◽  
Bharat A. Bhanvase ◽  
Satish P. Mardikar ◽  
Vilas S. Patil ◽  
Shirish H. Sonawane

Bioreactors ◽  
2020 ◽  
pp. 27-42
Author(s):  
Awais Bokhari ◽  
Suzana Yusup ◽  
Saira Asif ◽  
Lai Fatt Chuah ◽  
Leow Zi Yan Michelle


2016 ◽  
Vol 24 (33) ◽  
pp. 25667-25675 ◽  
Author(s):  
Juan Antonio Salas-Cortés ◽  
Flor de María Cuervo-López ◽  
Anne-Claire Texier


Author(s):  
Vivek D. Talnikar ◽  
Onkar A. Deorukhkar ◽  
Amit Katariya ◽  
Yogesh S. Mahajan

Abstract The reaction of acrylic acid and 2-ethyl-1 hexanol was explored in this work with the intent of process intensification. In order to assess the effect of important parameters on the course of reaction, this work initially conducted batch reactor experiments. Reaction conditions in the batch reactor for a specific conversion (~ 30 %) were obtained. A kinetic model was then obtained through regression to arrive at a rate expression that is later used in process development. Experiments were performed in the reactive distillation (RD) environment in batch mode, which showed substantial increase in conversion (~ 80 %) indicating the applicability of RD. Further, this work performed simulation in the RD environment to assess process intensification. Simulations show that it is possible to obtain complete conversion of the acid.



2010 ◽  
Vol 212 (1-4) ◽  
pp. 219-229 ◽  
Author(s):  
Agostina Chiavola ◽  
Renato Baciocchi ◽  
Federico Barducci


2016 ◽  
Vol 49 (2) ◽  
pp. 130-135 ◽  
Author(s):  
Dalia Heggo ◽  
Haitham Mohamed ◽  
Shinichi Ookawara ◽  
Yoshihisa Matsushita


2017 ◽  
Vol 23 (4) ◽  
pp. 573-580 ◽  
Author(s):  
Sema Akyalcin

The kinetics of the hydration of propylene oxide was studied using a pressurized batch reactor for both uncatalyzed and heterogeneously catalyzed reactions. Lewatit MonoPlus M500/HCO3 - was used as heterogeneous catalyst, which showed better performance than Dowex Marathon A/HCO3 -. The effects of the parameters, namely internal and external diffusion resistances, temperature, catalyst loading and mole ratios of reactants, on the reaction rate were studied. The uncatalyzed and heterogeneously catalyzed reactions were proven to follow a series-parallel irreversible homogeneous mechanism. The temperature dependencies of the rate constants appearing in the rate expressions were determined.





Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1362
Author(s):  
Alexey V. Bykov ◽  
Daria V. Alekseeva ◽  
Galina N. Demidenko ◽  
Alexandre L. Vasiliev ◽  
Linda Nikoshvili ◽  
...  

Supercritical (SC) fluid technologies are well-established methods in modern green chemical synthesis. Using SC fluids as solvents instead of traditional liquids gives benefits of higher diffusivity and lower viscosity, which allows mass transfer intensification and, thus, an increased production rate of chemical transformations. Therefore, a conjugation of heterogeneous catalysis with SC media is a large step toward a green chemistry. Tetralin (TL) is an important hydrogen donor solvent used for biomass liquefaction. In industry, TL is obtained via catalytic hydrogenation of naphthalene (NL). Herein, for the first time we have demonstrated the NL hydrogenation with close to 100% selectivity to TL at almost full conversion in the SC hexane. The observed transformation rates in SC hexane were much higher allowing process intensification. The downstream processes can be also facilitated since hexane after depressurisation can be easily separated from the reaction products via simple rectification. The TL synthesis was studied in a batch reactor at variation of reaction temperature and overall pressure. For the first time for this process, low Pt-loaded (1 wt.%) nanoparticles stabilized within hyper-cross-linked aromatic polymer (HAP) were applied. The Pt/HAP catalyst was stable under reaction conditions (250 °C, 6 MPa) allowing its recovery and reuse.



2022 ◽  
Vol 305 ◽  
pp. 114393
Author(s):  
Zineb Guellout ◽  
Emilie Francois-Lopez ◽  
Yacine Benguerba ◽  
Christine Dumas ◽  
Krishna Kumar Yadav ◽  
...  


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