Kinetic study of the hydration of propylene oxide in the presence of heterogeneous catalyst
2017 ◽
Vol 23
(4)
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pp. 573-580
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Keyword(s):
The kinetics of the hydration of propylene oxide was studied using a pressurized batch reactor for both uncatalyzed and heterogeneously catalyzed reactions. Lewatit MonoPlus M500/HCO3 - was used as heterogeneous catalyst, which showed better performance than Dowex Marathon A/HCO3 -. The effects of the parameters, namely internal and external diffusion resistances, temperature, catalyst loading and mole ratios of reactants, on the reaction rate were studied. The uncatalyzed and heterogeneously catalyzed reactions were proven to follow a series-parallel irreversible homogeneous mechanism. The temperature dependencies of the rate constants appearing in the rate expressions were determined.
2011 ◽
Vol 383-390
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pp. 2945-2950
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2021 ◽
Vol 134
(1)
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pp. 7-23
1971 ◽
Vol 26
(10)
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pp. 1010-1016
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Keyword(s):
1969 ◽
Vol 47
(21)
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pp. 3957-3964
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1993 ◽
Vol 58
(8)
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pp. 1777-1781
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Keyword(s):
1979 ◽
Vol 44
(12)
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pp. 3588-3594
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2004 ◽
Vol 69
(10)
◽
pp. 1877-1888
Keyword(s):
2015 ◽
Vol 13
(1)
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pp. 119-127
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