Harmful chemical substances: v.1: Elements in groups I-IV of the periodic table and their inorganic compounds

1993 ◽  
Vol 31 (04) ◽  
pp. 31-2119-31-2119
2019 ◽  
Vol 100 ◽  
pp. 00036
Author(s):  
Wojciech Kołodyński ◽  
Katarzyna Piekarska ◽  
Daniel Strub

The bioluminescence inhibition bioassay using marine bacteria Vibrio fischeri is widely used as a tool to assess the toxicity of chemical compounds, because of the many benefits comprising cost and time effectiveness, rapidness, sensitivity, and ease of operation. In addition, the test is used for various types of organic and inorganic compounds. Due to the insolubility of organic compounds in water, a suitable solubilizer should be applied. The ecotoxicity of the solvent should be negligible in relation to marine bacteria. On account of superior human activities the synthesis of new chemical substances is inextricably linked to the emergence of chemical compounds that are a potential threat on environment. A Microtox system utilizing the 81.9% Basic Test with 14 dilutions was applied to pre-evaluate the ecotoxicity of β-cyclocitral oxime, citronellal oxime and perillaldehyde oxime. Substances solutions with an initial concentration of 0.036% in DMSO were prepared. The preliminary results show that the studied scent compounds are characterized by quite high toxicity. In order to confirm the received ecotoxicity values, it is necessary to carry out additional surveys using another range of concentrations and biotests on organisms at each trophic level.


2006 ◽  
Vol 53 (11) ◽  
pp. 99-106 ◽  
Author(s):  
H. Yamagata ◽  
H. Saino ◽  
M. Minamiyama ◽  
M. Takahashi

The annual quantity of discharge of 354 chemical substances from each business has been released based on PRTR law in Japan since 2003. MLIT and municipalities should be responsible for managing chemical risk in public water bodies through communication with stakeholders, such as the public and businesses. However, it is economically difficult to measure the discharge loads and behaviour of all chemical substances and reveal which substances should be particularly managed in each basin. NILIM has begun studies on survey methods to understand the discharge and behaviour of chemical substances in each basin based on PRTR information, and to conduct risk management of chemical substances in cooperation with stakeholders such as the public and businesses. We selected 30 chemical substances, such as those listed or nominated in environmental criteria and endocrine disrupters, collected the volume of discharge of chemical substances from public and industrial wastewater treatment plants using PRTR information, and surveyed their behaviour in the river in the model area. As a result, the discharge of 12 chemical substances were reported in PRTR, and 17 substances were detected in the river. Some inorganic compounds were detected intensively near discharge sites reported in the PRTR. But some organic compounds and endocrine disrupters, such as oestrone, were detected although their discharge was not reported in the model area in the PRTR. It suggested that PRTR information is useful to identify hot spots, but further study is needed to understand the discharge of chemical substances from small businesses, farmland and houses.


2021 ◽  
Vol 10 (5) ◽  
pp. e45610515152
Author(s):  
Ruan Sousa Bastos ◽  
Joabe Lima Araújo ◽  
Vitória Santos Azevedo ◽  
Maria de Lourdes de Aguiar Silva Ferreira ◽  
Lúcio Rocha de Lima ◽  
...  

Cadmium is a toxic metal from 12th group and 5th period of the periodic table. It’s common its use in batteries manufacturing and metal alloys production. It is absorbed by the organism of animals and plants causing risks to human health by bioaccumulation. Even with proven levels of toxicity, complexes involving this atom have biological activity according to several studies. As a study methodology, data were prospected in different databases for patents and the scientific papers published in the period up 1962 to 2021. Only 3 patents were found regarding the biological activity of complexes containing cadmium, although 3.257 results have been found for Cd (II) articles. The database with the highest number of published articles was Scifinder with 63% (2.037) of the articles. Few articles approached anthelmintic activity, showing that future research related to chemical substances containing this metal is a possibility in the new anthelmintic drugs investigation.


Author(s):  
Eric Scerri

Elements within a vertical group on the periodic table share certain chemical similarities, but the modern periodic system is not derived purely from descriptive characteristics. If chemical similarities were the sole basis for their classification, there would be many cases where the order and placement of the elements would be ambiguous. The development of the modern periodic system began when it was recognized that there are precise numerical relationships among the elements. Its subsequent evolution has also involved contributions from physics, as described in subsequent chapters. But whereas the latter contributions drew on fundamental physical theories, the ones that are examined in this chapter do not share this aspect. Instead, they involved looking for patterns among the numerical properties, such as equivalent weight or atomic weight, associated with each element. Throughout its history, the development of the periodic table has required a delicate interplay between two contrasting approaches: discerning quantitative physical data, on one hand, and observing qualitative similarities among the elements as a form of natural history, on the other. Both approaches are essential, and the balance that has been struck between them has been of crucial importance at various stages in our story. Whereas attention to qualitative aspects has always been an essential part of chemistry, the use of quantitative data has been a relatively new addition. The time when chemists began to pay attention to quantitative aspects of chemical reactions and chemical substances has been the source of much debate among historians. The traditional view has been that this step was taken by Antoine Lavoisier , who is regarded as the founder of modern chemistry. The more recent historical account is that Lavoisier made few original contributions and that much of his fame lay in his abilities as an organizer and presenter of chemical knowledge. Nevertheless, Lavoisier was able to dispel some of the vagueness and confusion that dogged the field of chemistry as he found it.


Author(s):  
R. Herrera ◽  
A. Gómez

Computer simulations of electron diffraction patterns and images are an essential step in the process of structure and/or defect elucidation. So far most programs are designed to deal specifically with crystals, requiring frequently the space group as imput parameter. In such programs the deviations from perfect periodicity are dealt with by means of “periodic continuation”.However, for many applications involving amorphous materials, quasiperiodic materials or simply crystals with defects (including finite shape effects) it is convenient to have an algorithm capable of handling non-periodicity. Our program “HeGo” is an implementation of the well known multislice equations in which no periodicity assumption is made whatsoever. The salient features of our implementation are: 1) We made Gaussian fits to the atomic scattering factors for electrons covering the whole periodic table and the ranges [0-2]Å−1 and [2-6]Å−1.


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