scholarly journals Continuous Monitoring of Chlorophenols in Flue Gas from Waste Incinerators by Liquid Chromatography, (2) GC/MS Confirmation of Concentrations Measured at Municipal Plants by LC/EChD

2004 ◽  
Vol 14 (3) ◽  
pp. 633-641
Author(s):  
Ikuo WATANABE ◽  
Masako KUDO ◽  
Yasundo KURATA
Author(s):  
Wlodzimierz Blasiak ◽  
Weihong Yang

This work presents the main features, advantages and evaluation of applications of the novel “Ecotube” combustion improvement and emission reduction system by Ecomb AB of Sweden and Synterprise, LLC of Chattanooga, Tennessee. In the Ecotube system, the nozzles used for mixing are put on the suitable position inside the combustion chamber to control uniformity of temperature, mixing and reactants distribution in boilers and incinerators since the formation and reduction of pollutants (NO, CO and VOC) and in-furnace reduction processes (Air/Fuel staging, SNCR, flue gas recirculation and SOx reduction by dry sorbent injection) are related directly to mixing in a combustion chamber. The novel Ecotube combustion improvement system allows better control of mixing of the gases for example from a primary combustion zone with secondary combustion air or a recirculated flue gas. By means of the novel system it is possible to better control the residence time and to some degree gas phase temperature distribution as well as the heat release distribution in the furnace of the waste incinerators or boilers. This new combustion improvement system can be applied to supply different gas or liquid media — for example air, fuel, urea or even solid powder. Using the system a more efficient and environmentally clean combustion or incineration process can be performed. The Ecotube System may be used to meet increasingly stringent environmental emissions regulations, such as NOx SIP Call, while it delivers added benefits of reduced and stabilized CO and reduced fly ash and improved boiler efficiency. The study tool used in this work to present influence of the Ecotube system design on temperature as well as uniformity of reactants and flow field is numerical modeling. Using this tool, the influence of the position of the Ecotube system and the injection angle of the nozzles are studied. The studied boilers included the biomass waste incinerator, municipal solid waste incinerator and coal fired boiler. The concept of the Heat Release Distribution Ratio is proposed to classify the heat release inside the upper furnace of the boilers or incinerators. The results show that Ecotube spreads reaction zone over a larger furnace volume. The furnace flame occupation coefficient can be as high as 45% with the Ecotube system and it is around 40% higher comparing with the conventional multinozzle mixing system. Ecotube system allows keeping far more uniform heat release distribution, more uniform temperature distribution, and thus longer life of the heat transfer surfaces inside the furnace. Position of the Ecotube system and the injection angle of the nozzles are of primary importance and can be used as a technical parameter to control the boiler operation at different loads and varying operating conditions.


2009 ◽  
Vol 46 (6) ◽  
pp. 45-48
Author(s):  
李树珉 Li Shumin ◽  
刘斌 Liu Bin ◽  
孙长库 Sun Changku ◽  
赵玉梅 Zhao Yumei

1972 ◽  
Vol 55 (4) ◽  
pp. 757-761
Author(s):  
N Fred Ives ◽  
L Giuffrida

Abstract The liquid chromatography of 18 polycyclic aromatic hydrocarbons was investigated by using a continuous monitoring ultraviolet detection system. Two column materials, Durapak OPN and 40% cellulose acetate, were compared for orders of elution and resolution. Neither system resolves all the compounds tested but the use of more than one system increases the number which may be resolved. This investigation demonstrates the potential of analytical liquid chromatography for the resolution and analysis of such compounds.


Chemosphere ◽  
1999 ◽  
Vol 39 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Takashi Nishitani ◽  
Isao Fukunaga ◽  
Hisao Itoh ◽  
Tomohiro Nomura

Author(s):  
Akın Koluaçık ◽  
Göksel Tırpancı Sivri ◽  
Binnur Kaptan

Mycotoxin occurrence in foods, especially in uncontrolled produced traditional foods causes serious health problems. In this study, traditional Küp cheese samples were collected from different part of Anatolian region in Turkey (Ankara, Nevşehir and Yozgat) and analyzed to determine Aflatoxin M1 (AFM1) level. AFM1 analysis was carried out by, immunoaffinity column (IAC) clean-up and high performance liquid chromatography (HPLC) attached with fluorescence detector (FL) The level of AFM1 in all samples was in the range of 16 and 136 ng/kg which is lower than the maximum tolerance limit of the Turkish Codex Regulations (250 ng/kg). The levels of contamination indicated that more detailed and continuous monitoring is required to increase the public health conscious and reduce consumers’ exposure to AFM1.


2016 ◽  
Vol 832 ◽  
pp. 207-212
Author(s):  
Jiří Moskalík

This article is focused on formation of unwanted deposits in the municipal waste incinerator and their influence on incinerator operation. The solid deposits build up on heat transfer surfaces in flue gas channel of waste incinerator. The power stations fired solid fuels sometimes can have problems with growing of deposits. On this point of view, the municipal waste incinerators are a special category, because the municipal waste contains a lot of different types of compounds. Formation of deposits on heat transfer surfaces has in generally bad influence on operating parameters of waste incinerator. Deposits decrease the heat transfer from the flue gas into the working fluid and thereby it reduces the efficiency of incineration facility. The effect of decreasing of heat transfer ability was investigated on large-scale waste incinerator in Brno, where were monitored changes of operating parameters before and after the planned shutdown of the device. Deposits can too affect the shape of flue gas channel and thereby reduce his size. It can have more negative impact on waste incinerator operation.


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