scholarly journals SPECTROSCOPICALLY AND/OR STRUCTURALLY INTRIGUING PHTHALOCYANINES AND RELATED COMPOUNDS. PART 2. MONOMERIC SYSTEMS

2019 ◽  
Vol 62 (8) ◽  
pp. 4-25
Author(s):  
Nagao Kobayashi
Keyword(s):  
Spectral Data ◽  
Time Resolution ◽  
Spectroscopic Data ◽  
Magnetic Circular Dichroism ◽  
Molecular Orbitals ◽  
P Systems ◽  
Spectroscopic Methods ◽  
Electron Absorption ◽  
The Third ◽  
Related Compounds

The second part of the series of review papers on the properties of some synthetically and spectroscopically interesting studies of our group for the period 2007-2017 is presented. In particular, examples of the analysis of spectroscopic data in combination with calculations by the molecular orbitals method are given. We mainly used spectroscopic methods of electron absorption and natural and magnetic circular dichroism, periodically applying fluorescence, phosphorescence and ESR with a time resolution. The spectra of (4n + 2) p systems, as well as some 4np antiaromatic systems, are analyzed theoretically, which helps the reader to interpret the spectral data. In the first and the second parts of this review monomer systems are considered, and in the third - trimeric and tetrameric systems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. .. .. . . . . . . . . . . . . . . .. . . . . . .. . . .. .. . .. . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . .. . . . . . . . .. .. . . . . . . .. . . . . . . .. . . .. . . . .. . . .. . . . . . .. . . .. .. . . . . . .. . . . .. . .. .. . .

scholarly journals SPECTROSCOPICALLY AND/OR STRUCTURALLY INTRIGUING PHTHALOCYANINES AND RELATED COMPOUNDS. PART 3. DIMERIC SYSTEMS, TETRAMERS, AND CONCLUSIONS

2019 ◽  
Vol 62 (11) ◽  
pp. 4-37
Author(s):  
Nagao Kobayashi
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Spectroscopic Data ◽  
Magnetic Circular Dichroism ◽  
Spectroscopic Methods ◽  
Paramagnetic Resonance ◽  
The Third ◽  
Electron Paramagnetic ◽  
Related Compounds

This work is the third part of the review, which presents the properties of a large group of phthalocyanines, which were synthesized and spectroscopically and theoretically studied in works performed under the guidance of the author for the period 2007-2017. Examples of the analysis of spectroscopic data in combination with quantum-chemical calculations of different level are given. As spectroscopic methods, we used the methods of electron absorption, natural and magnetic circular dichroism (CD and MCD) fluorescence, phosphorescence, and electron paramagnetic resonance with time resolution. Based on quantum-chemical calculations, the spectra of (4n + 2) p systems, as well as some 4np antiaromatic systems, were theoretically analyzed. Unlike the first and second parts of the review, this part deals with dimeric and tetrameric systems. <span style="opacity: 0;"> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . </span> <span style="opacity: 0;"> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . </span>

SPECTROSCOPICALLY AND/OR STRUCTURALLY INTRIGUING PHTHALOCYANINES AND RELATED COMPOUNDS. PART 1. MONOMERIC SYSTEMS

2019 ◽  
Author(s):  
Nagao Kobayashi
Keyword(s):  
Spectral Data ◽  
Electronic Absorption ◽  
Spectroscopic Data ◽  
Magnetic Circular Dichroism ◽  
Spectroscopic Techniques ◽  
Mo Calculations ◽  
Time Resolved ◽  
The Third ◽  
Aromatic Systems ◽  
Related Compounds

The first part of the series of review papers on the properties of some synthetically and spectroscopically interesting studies of our group for the period 2007-2017 is presented. In particular, examples are shown on the analysis of spectroscopic data in conjunction with molecular orbital (MO) calculations. We have used mainly electronic absorption and natural and magnetic circular dichroism (CD and MCD) spectroscopic techniques, with occasional use of fluorescence, phosphorescence, and time-resolved EPR. Not only the spectra of (4n + 2)π systems, but also some 4nπ anti-aromatic systems are theoretically analyzed, which helps the reader to learn how to interprete the spectral data. In the first part and the second part of this review monomer systems are considered, and in the third - trimeric and tetrameric systems. <span style="opacity: 0;"> . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . </span>

scholarly journals Guaiane Sesquiterpenoids from Jatropha curcas

2008 ◽  
Vol 3 (10) ◽  
pp. 1934578X0800301
Author(s):  
Xia-Chang Wang ◽  
Shi-Ping Ma ◽  
Jing-Han Liu ◽  
Li-Hong Hu
Keyword(s):  
Nmr Spectroscopy ◽  
Spectral Data ◽  
Jatropha Curcas ◽  
2D Nmr ◽  
Spectroscopic Methods ◽  
X Ray Diffraction ◽  
2D Nmr Spectroscopy ◽  
X Ray ◽  
Esi Ms ◽  
Related Compounds

Two new guaiane sesquiterpenoids named jatrophaols A and B (1, 2), along with three known analogues, were isolated from the roots of Jatropha curcas. Their structures were determined by spectroscopic methods, including 1D and 2D NMR spectroscopy, HR-EI-MS, HR-ESI-MS, and X-ray diffraction, as well as by comparison of their spectral data with those of related compounds.

New Furanocoumarins and Other Chemical Constituents from Ficus carica Root Heartwood

2013 ◽  
Vol 68 (1-2) ◽  
pp. 3-7 ◽  
Author(s):  
Renuka Jaina ◽  
Satish C. Jain ◽  
Teena Bhagchandani ◽  
Namita Yadav
Keyword(s):  
Spectral Data ◽  
Methyl Ether ◽  
Chemical Constituents ◽  
Ficus Carica ◽  
Spectroscopic Methods ◽  
Esi Ms ◽  
Chain Compounds ◽  
Related Compounds ◽  
Long Chain

Two new furanocoumarins, 5-(1”,1”-dimethylallyl)-8-methyl psoralen (1) and 2-O-acetyl oxypeucedanin hydrate-3”-methyl ether (2), were isolated from the root heartwood of Ficus carica Linn. together with three known furanocoumarins, two triterpenoids, two long-chain compounds, and a steroid. Their structures and relative confi gurations were elucidated by spectroscopic methods (IR, HR-ESI-MS, and NMR) and by comparison of their NMR spectral data with those of related compounds

Chemical components of the rhizomes of Drynaria fortunei (KUNZE) J. Sm. (polypodiaceae) in Vietnam

2011 ◽  
Vol 76 (9) ◽  
pp. 1133-1139 ◽  
Author(s):  
Pham Thi Nhat Trinh ◽  
Nguyen Cong Hao ◽  
Phan Thanh Thao ◽  
Le Tien Dung
Keyword(s):  
Data Analysis ◽  
Spectral Data ◽  
Phenolic Acid ◽  
Ethanol Extract ◽  
Chemical Components ◽  
Spectroscopic Methods ◽  
Phenylpropanoid Glycoside ◽  
Spectral Data Analysis ◽  
First Time

From the ethanol extract of Drynaria fortunei (KUNZE) J. Sm., a new phenylpropanoid glycoside, fortunamide (1), was isolated and characterized by spectroscopic methods. Together with a new glycoside, 9 known compounds, including three curcuminoids (2–4), two isoprenylated flavonoids (5, 6), two flavonoids (7, 8), one monoterpenoid (9) and one phenolic acid (10) were isolated and identified by spectral data analysis from the rhizomes of Drynaria fortunei (KUNZE) J. Sm. Eight of them were isolated from Drynaria fortunei (KUNZE) J. Sm. for the first time.

Synthesis and Ring Cyclization - Expansion - Contraction Reactions of Some New 2,2-Disubstituted Indan-1,3-diones and Related Compounds

2006 ◽  
Vol 59 (1) ◽  
pp. 59 ◽  
Author(s):  
Craig J. Roxburgh ◽  
Lee Banting
Keyword(s):  
Catalytic Hydrogenation ◽  
Pyridine Ring ◽  
Functional Group ◽  
Chemical Properties ◽  
Ring Expansion ◽  
Ring Structure ◽  
Side Reactions ◽  
The Third ◽  
Ring Expansion Reaction ◽  
Related Compounds

We have found that the hydrochloride of 2-phenyl-2-[2-(2-piperidyl)ethyl]-4,5,6,7-tetrahydroindan-1,3-dione 1 possesses marked analgesic activity (100% inhibition referenced to codeine) and report, as part of an extensive synthetic program, the synthesis of 38 new and structurally related compounds. Selective catalytic hydrogenation of the pyridine ring of 2-phenyl-2-[2-(2-pyridyl)ethyl]-indan-1,3-dione 2 yields the nine-membered nitrogen-containing heterocycle 6 by a novel ring cyclization–expansion reaction. The structural and functional group parameters required for this novel ring-expansion reaction have been extensively and thoroughly investigated through the synthesis of a series of structurally related compounds; principally by modification, substitution, and replacement of the various functionality contained within 2. In addition, we report the synthesis of a series of new 2-methyl-2-(ω-N-phthalimidoalkyl)-indan-1,3-diones 41, 45, and 53, two of which, like the parent 2-phenyl substituted indan-1,3-dione 2, also undergo a novel ring cyclization–expansion reaction to yield eight- and nine-membered nitrogen-containing rings. However, in these cases, further transannular reactions occur to produce the new 5,5- and 5,6-ring-fused nitrogen-containing heterocycles 44, 48 and 51, 52. Hydrazinolysis of the third, 2-methyl-2-(4-N-phthalimidobutyl)-indan-1,3-dione yields the new azepine-containing ring structure 56 by direct cyclization. Furthermore, some interesting and unexpected chemical properties of the final compounds, which include selective and non-selective pyridine-ring hydrogenations and a few unexpected side reactions, are described.

scholarly journals Образование нанометровых трещин и фрактолюминесценция при разрушении углеродной керамики

2020 ◽  
Vol 62 (11) ◽  
pp. 1860
Author(s):  
В.И. Веттегрень ◽  
А.Г. Кадомцев ◽  
И.П. Щербаков ◽  
Р.И. Мамалимов ◽  
В.Б. Кулик
Keyword(s):  
Silicon Carbide ◽  
Surface Layer ◽  
Raman Spectrum ◽  
Time Resolution ◽  
Spectrum Analysis ◽  
The Third ◽  
Silicon Crystals ◽  
Slip Planes ◽  
Formation Of Cracks ◽  
Carbon Ceramic

Raman spectrum of the surface layer with a thickness of approximately 80 nm of a porous carbon ceramic was obtained (the porosity was used equal to 5%). Spectrum analysis showed that the ceramics contains crystals of silicon carbide - 6H-SiC and silicon. The destruction of ceramics by diamond microcrystals resulted in fractoluminescence (FL). Spectrum of FL contains two bands at 1.6 and 1.9 eV. The first band is formed by breaking down the silicon crystals, and the second band is formed by breaking down the 6H-SiC crystals. The time dependence of the intensity of FL signals with a time resolution of 2 ns is obtained. Three types of signals were observed: one type of signal is formed when the 6H-SiC crystals break down, the second type of signal is formed when the silicon crystals break down, and the third type of signal is formed when these crystals break down simultaneously. The appearance of signals is associated with the formation of cracks arising from the breaking down of the barriers formed at the intersection of slip planes of dislocations in silicon carbide and silicon crystals. The size of cracks in 6H-SiC is estimated: the smallest ones is 5.5 nm, and the largest is approximately 18 nm.

Synthesis and third-order nonlinear optical properties of novel ethynyl-linked heteropentamer composed of four porphyrins and one pyrene

2009 ◽  
Vol 13 (02) ◽  
pp. 275-282 ◽  
Author(s):  
Ning Sheng ◽  
Jing Sun ◽  
Yongzhong Bian ◽  
Jianzhuang Jiang ◽  
Dong Xu
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Three Dimensional ◽  
Spectroscopic Methods ◽  
Third Order ◽  
Zinc Compounds ◽  
Nlo Properties ◽  
Metal Free ◽  
The Third ◽  
Wide Range

Novel heteropentameric porphyrins-pyrene arrays, in which four meso-tetraphenyl porphyrins are linked to the center unit of pyrene by four acetylenyl bonds, were designed and synthesized. The newly synthesized heteropentameric compounds have been characterized by a wide range of spectroscopic methods. The third-order nonlinear optical (NLO) properties of both the metal-free and zinc compounds of the three-dimensional arrays were investigated by Z-scan experiments, showing enhanced NLO properties compared with that of the porphyrin and pyrene monomers.

Synthesis, Optical Properties, Structures and Molecular Orbital Calculations of Subazaporphyrins, Subphthalocyanines, Subnaphthalocyanines and Related Compounds

1999 ◽  
Vol 03 (06) ◽  
pp. 453-467 ◽  
Author(s):  
NAGAO KOBAYASHI
Keyword(s):  
Molecular Orbital ◽  
Magnetic Circular Dichroism ◽  
Soret Band ◽  
Ring Expansion ◽  
Molecular Orbital Calculations ◽  
Mo Calculations ◽  
Key Points ◽  
Adsorption Data ◽  
Ring Expansion Reaction ◽  
Related Compounds

The synthesis of and spectroscopic data on subazaporphyrins, subphthalocyanines, subnaphthalocyanines and their related compounds reported to date are summarized, together with the results of molecular orbital (MO) calculations from our laboratory. Thus the problems and key points in the synthesis of these subazamacrocycles and their electronic absorption and magnetic circular dichroism (MCD) spectra are discussed, together with those of the monosubstituted-type low-symmetrical phthalocyanines obtained by their ring expansion reaction. The Q bands of these subazamacrocycles are orbitally doubly degenerate, and in the Soret band region, three transitions to the orbitally degenerate state are found. The MO calculations suggest that the HOMO levels destabilize considerably while the LUMO levels change slightly with increasing size of the π system. In addition, the electronic adsorption data are reproduced by the calculation only when the two pyrrole hydrogens in the monosubstituted-type phthalocyanines are assumed to be linked to the two pyrrole nitrogens along the short axis.

Sign in / Sign up

Export Citation Format

Share Document