scholarly journals An Efficient Synthesis of 1,8-Dioxo-Octahydroxanthenes Derivatives Using Heterogeneous Ce-ZSM-11 Zeolite Catalyst

2018 ◽  
Vol 13 (3) ◽  
pp. 436 ◽  
Author(s):  
Rameshwar R. Magar ◽  
Ganesh T. Pawar ◽  
Sachin P. Gadekar ◽  
Machhindra Karbhari Lande
Keyword(s):  
Zeolite Catalyst ◽  
Bet Surface Area ◽  
High Yield ◽  
Efficient Synthesis ◽  
X Ray Diffraction ◽  
One Pot ◽  
Efficient Catalyst ◽  
Temperature Programmed ◽  
The One ◽  
Work Up

The Ce-ZSM-11 zeolite has been used as an efficient catalyst for the one pot synthesis of 1,8-dioxo-octahydroxanthene derivatives from aromatic aldehyde and 5,5-dimethyl-cyclohexane-1,3-dione under reflux condition. The catalyst was characterized by Powder X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FTIR), Brunauer-Emmer-Teller (BET) surface area analysis, and Temperature Programmed Desorption (TPD) techniques. This method provides several advantageous such as use of inexpensive catalyst, simple work-up procedure, high yield of desired product and reusability of catalyst. Copyright © 2018 BCREC Group. All rights reservedReceived: 5th January 2018; Revised: 25th May 2018; Accepted: 27th May 2018How to Cite: Magar, R.R., Pawar, G.T., Gadekar, S.P., Lande, M.K. (2018). An Efficient Synthesis of  1,8-Dioxo-Octahydroxanthenes Derivatives Using Heterogeneous Ce-ZSM-11 Zeolite Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 436-446 (doi:10.9767/bcrec.13.3.2062.436-446)Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.2062.436-446 

Anchoring of ruthenium onto imine-functionalized zeolite beta: an efficient route for the synthesis of 4H-benzo[b]pyrans and pyrano[c]chromenes

2014 ◽  
Vol 92 (11) ◽  
pp. 1086-1091 ◽  
Author(s):  
Khalil Tabatabaeian ◽  
Mohammad Ali Zanjanchi ◽  
Manouchehr Mamaghani ◽  
Ali Dadashi
Keyword(s):  
Significant Loss ◽  
Zeolite Beta ◽  
Bet Surface Area ◽  
Reusable Catalyst ◽  
Scanning Electron Micrographs ◽  
X Ray Diffraction ◽  
One Pot ◽  
Efficient Catalyst ◽  
Efficient Route ◽  
The One

The synthesis and characterization of a highly efficient and reusable catalyst, ruthenium immobilized in zeolite beta, are reported. The catalyst was characterized by powder X-ray diffraction, BET surface area measurements, scanning electron micrographs, Fourier-transform infrared spectroscopy, inductive coupled plasma, and elemental analysis. The supported material was used as an efficient catalyst for the one-pot three-component synthesis of 4H-benzo[b]pyrans and pyrano[c]chromenes in good yields. The catalyst was separated from the reaction mixture and reused up to five runs without significant loss of activity.

TiO2 Nanoparticles as an Efficient Catalyst for the One-pot Preparation of Tetrahydrobenzo[c]acridines in Aqueous Media

2013 ◽  
Vol 68 (4) ◽  
pp. 362-366 ◽  
Author(s):  
Shahrzad Abdolmohammadi ◽  
Mahdieh Mohammadnejad ◽  
Faezeh Shafaei
Keyword(s):  
Ammonium Acetate ◽  
Titanium Dioxide Nanoparticles ◽  
Aqueous Media ◽  
Aromatic Aldehydes ◽  
Catalytic Amount ◽  
One Pot ◽  
Efficient Catalyst ◽  
The One ◽  
Work Up ◽  
Operational Simplicity

A series of tetrahydrobenzo[c]acridinone derivatives have been prepared by a one-pot fourcomponent reaction of 1-naphthol, aromatic aldehydes, dimedone, and ammonium acetate in aqueous media using a catalytic amount of titanium dioxide nanoparticles (TiO2 NPs). The advantages of this novel protocol include the excellent yields, operational simplicity, short reaction time, easy work-up, reusability of the catalyst and an environmentally friendly procedure.

Diastereoselective Synthesis of Functionalised Trans-Tetrahydrobenzofuran-4-Ones in an Aqueous Medium by using DABCO as an Efficient Catalyst

2017 ◽  
Vol 41 (11) ◽  
pp. 657-660 ◽  
Author(s):  
Mohammad Reza Salari ◽  
Mohammad H. Mosslemin ◽  
Alireza Hassanabadi
Keyword(s):  
Aqueous Medium ◽  
High Purity ◽  
Reaction Times ◽  
Diastereoselective Synthesis ◽  
Efficient Synthesis ◽  
One Pot ◽  
Efficient Catalyst ◽  
Pyridinium Bromide ◽  
Work Up

A one-pot, efficient synthesis of 11 novel 2,3-diacylated trans-tetrahydrobenzofuran-4-one derivatives has been achieved via a three-component condensation of a N-(4-halophenacyl)-pyridinium bromide, a cyclic 1,3-diketone such as 5,5-dimethyl-1,3-cyclohexanedione (dimedone) or cyclohexane-1,3-dione and an arylglyoxal in the presence of catalytic amounts of 1,4-diaza-bicyclo[2.2.2]octane (DABCO) in water under reflux conditions. The attractive features of the method are excellent yields and high purity, short reaction times, easy work-up, and use of an inexpensive and non-toxic catalyst.

CeCl3·7H2O as mild and efficient catalyst for the one-pot multicomponent synthesis of 8-aryl-7,8-dihydro[1,3]dioxolo[4,5-g]chromen-6-ones

2011 ◽  
Vol 76 (4) ◽  
pp. 235-241 ◽  
Author(s):  
Li-Qiang Wu ◽  
Wei-Lin Li ◽  
Fu-Lin Yan
Keyword(s):  
Aromatic Aldehydes ◽  
Environmentally Benign ◽  
Multicomponent Synthesis ◽  
One Pot ◽  
Efficient Catalyst ◽  
Solvent Free Conditions ◽  
Three Component Reaction ◽  
The One ◽  
High Yields ◽  
Work Up

A series of new 8-aryl-7,8-dihydro[1,3]dioxolo[4,5-g]chromen-6-ones were synthesized via a three-component reaction of 3,4-methylenedioxyphenol, aromatic aldehydes and Meldrum’s acid in the presence of CeCl3·7H2O under solvent-free conditions. The method provided several advantages such as easy work-up, high yields and environmentally benign procedure.

scholarly journals Leucine: green and efficient catalyst for the synthesis of 4H-chromenes

2017 ◽  
Vol 10 (9) ◽  
pp. 3197-3202 ◽  
Author(s):  
Davood Azarifar ◽  
Younes Abbasi ◽  
Omolbanin Badalkhani
Keyword(s):  
Amino Acid ◽  
Condensation Reaction ◽  
Reaction Times ◽  
Aromatic Aldehydes ◽  
One Pot ◽  
Efficient Catalyst ◽  
Naturally Occurring ◽  
The One ◽  
High Yields ◽  
Work Up

Leucine, a naturally occurring α-amino acid, has been found as an effective catalyst to effect the one-pot three-component condensation reaction between aromatic aldehydes, malononitrile and 5,5-dimethyl-1,3-cyclohexanedione (dimedone). Various 2-amino-4-aryl-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile derivatives are conveniently prepared by these reactions in excellent yields. High yields, short reaction times, simple work-up, use of green and naturally occurring catalyst and solvent are the main merits of the present protocol. 

A Suitable One-Pot Synthesis of 3,4-Dihydropyrano[3,2-c]Chromenes Using Magnetic Nanoparticles Tag: Piperidinium Benzene-1,3-Disulfonate Ionic Liquid as a Novel, Green, Efficient and Reusable Catalyst in Aqueous Medium

2017 ◽  
Vol 14 (6) ◽  
pp. 904-911 ◽  
Author(s):  
Ramin Ghorbani-Vaghei ◽  
Jafar Mahmoodi ◽  
Yaser Maghbooli ◽  
Azadeh Shahriari
Keyword(s):  
Ionic Liquid ◽  
Magnetic Nanoparticles ◽  
Reaction Times ◽  
Catalytic Amount ◽  
High Yield ◽  
Reusable Catalyst ◽  
One Pot ◽  
Efficient Catalyst ◽  
Water Solvent ◽  
The One

Background: The synthesis of 3,4-dihydropyrano[3,2-c]chromenes via the one-pot three-component reactions of various aldehydes, malononitrile, and 4-hydroxycumarin at 60 °C in water as a solvent by the magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a green and efficient catalyst. Some benefits of the presented technique are significant cost impact, impressive catalysis and the ability to reuse of the catalyst. The current procedure offers high yield, short reaction times, neat reaction and simple reusable catalyst. Objective: A magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a green, efficient, reusable and heterogeneous catalyst was used for the synthesis of 3,4-dihydropyrano[3,2-c]chromenes. Method: We have described an efficient and green process for the synthesis of the one-pot three-component synthesis of 3,4-dihydropyrano[3,2-c]chromenes from the reaction between 4-hydroxy-coumarin with malononitrile and aldehydes in the presence of catalytic amount of magnetic nanoparticles tag: piperidinium benzene-1,3-disulfonate ionic liquid as a novel and powerful nano ionic liquid with good to excellent yields and in a short reaction time in water solvent at 60 °C. Result: The main advantage of this process is the simplicity of the work-up and the products can be isolated without chromatography. Conclusion: We suggest that the method has also various additional advantages such as low loading of catalyst, clean reaction, which makes it a suitable and noteworthy approach for the synthesis of 3,4- dihydropyrano[3,2-c]chromenes.

scholarly journals Zr(HSO4)4: An Efficient Catalyst for the Synthesis of 3-(2'- Benzothiazolyl)-2,3-dihydroquinazolin- 4(1H)-ones

2012 ◽  
Vol 9 (2) ◽  
pp. 739-743 ◽  
Author(s):  
Liqiang Wu
Keyword(s):  
Solvent Free ◽  
Isatoic Anhydride ◽  
Efficient Synthesis ◽  
One Pot ◽  
Efficient Catalyst ◽  
Solvent Free Conditions ◽  
One Pot Condensation ◽  
The One

A simple and efficient synthesis of 3-(2'-benzothiazolyl)-2,3-dihydro quinazolin-4(1H)- ones has been accomplished by the one-pot condensation of isatoic anhydride, aldehyde and 2-aminobenzothiazole under solvent-free conditions in the presence of Zr(HSO4)4.

scholarly journals A Clean, Simple, and Efficient Synthesis of 2-Substituted Aryl (Indolyl) Kojic Acid Derivatives by Kaolin/Ag Nanocomposite as a Reusable Catalyst: A Green Protocol

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Bahareh Sadeghi ◽  
Mohammad Reza Shahedi
Keyword(s):  
Kojic Acid ◽  
High Yield ◽  
Reusable Catalyst ◽  
Indole Derivatives ◽  
Efficient Synthesis ◽  
One Pot ◽  
Green Protocol ◽  
Solvent Free Conditions ◽  
Three Component Reaction ◽  
The One

Kaolin/Ag nanocomposite (kaolin/Ag nanocomposite) was synthesized in a nanoreactor by the calcination of the precursor at high temperature and was shown to efficiently catalyze the one-pot, three-component reaction of an aromatic aldehyde, kojic acid, and indole derivatives under solvent-free conditions to afford the corresponding 2-substituted aryl (indolyl) kojic acid derivatives in high yield.

DMAP as a new efficient catalyst for the one-pot synthesis of condensed phthalazines

2017 ◽  
Vol 72 (5) ◽  
pp. 361-368 ◽  
Author(s):  
Esma Lamera ◽  
Sofiane Bouacida ◽  
Hocine Merazig ◽  
Aissa Chibani ◽  
Marc Le Borgne ◽  
...  
Keyword(s):  
Environmental Pollution ◽  
Efficient Method ◽  
Toxic Metals ◽  
Aromatic Aldehydes ◽  
One Pot ◽  
Efficient Catalyst ◽  
One Pot Synthesis ◽  
The One ◽  
The Cost ◽  
Work Up

AbstractA new, convenient, and efficient method for the synthesis of 1H-pyrazolo[1,2-b]phthalazine-5,10-diones is developed starting from phthalhydrazide, aromatic aldehydes, and malononitrile using 4-N,N-dimethylaminopyridin as catalyst. This modified route provides much higher yields and a simple work-up procedure of products. Also this methodology is of interest due to the use of ethanol as a solvent without use of any toxic metals as catalyst, thus minimizing the cost, the operational hazards, and environmental pollution.

scholarly journals Solvent-free synthesis of 1-amidoalkyl-2-naphthol and 3-amino-1-phenyl-1H benzo[f]chromene-2-carbonitrile derivatives by Fe3O4@enamine-B(OSO3H)2 as an efficient and novel heterogeneous magnetic nanostructure catalyst

2020 ◽  
Vol 22 (2) ◽  
pp. 9-19 ◽  
Author(s):  
Fangping Li ◽  
Jun Zhang ◽  
Longjiang Wang ◽  
Weijian Liu ◽  
Qahtan A. Yousif
Keyword(s):  
Reaction Times ◽  
Catalytic Amount ◽  
X Ray Diffraction ◽  
One Pot ◽  
X Ray ◽  
Magnetic Nanostructure ◽  
The One ◽  
High Yields ◽  
Green Procedure ◽  
Work Up

AbstractA green procedure for the one-pot three-component synthesis of 1-amidoalkyl-2-naphthol and 3-amino-1-phenyl-1H benzo[f]chromene-2-carbonitrile derivatives from the reaction of 2-naphtol, aldehydes, and malononitrile/acetamide in the presence of a catalytic amount of Fe3O4@enamine-B(OSO3H)2 as an efficient and novel heterogeneous magnetic nanostructure catalyst is described. The catalyst was characterized using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). These strategies possess some merits such as simple work-up method, easy preparation of the catalyst, short reaction times, good-to-high yields, and non-use of hazardous solvents during all steps of the reactions. Moreover, due to the magnetic nature of the catalyst, it was readily recovered by magnetic decantation and can be recycled at least six runs with no considerable decrease in catalytic activity.

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