Review of Organic Photorefractive Materials and Their Use for Updateable 3D Display

Photorefractive materials are capable of reversibly changing their index of refraction upon illumination. That property allows them to dynamically record holograms, which is a key function for developing an updateable holographic 3D display. The transition from inorganic photorefractive crystals to organic polymers meant that large display screens could be made. However, one essential figure of merit that needed to be worked out first was the sensitivity of the material that enables to record bright images in a short amount of time. In this review article, we describe how polymer engineering was able to overcome the problem of the material sensitivity. We highlight the importance of understanding the energy levels of the different species in order to optimize the efficiency and recording speed. We then discuss different photorefractive compounds and the reason for their particular figures of merit. Finally, we consider the technical choices taken to obtain an updateable 3D display using photorefractive polymer. By leveraging the unique properties of this holographic recording material, full color holograms were demonstrated, as well as refreshing rate of 100 hogels/second.

Nondegenerate Bright Solitons in Coupled Nonlinear Schrödinger Systems: Recent Developments on Optical Vector Solitons

Nonlinear dynamics of an optical pulse or a beam continue to be one of the active areas of research in the field of optical solitons. Especially, in multi-mode fibers or fiber arrays and photorefractive materials, the vector solitons display rich nonlinear phenomena. Due to their fascinating and intriguing novel properties, the theory of optical vector solitons has been developed considerably both from theoretical and experimental points of view leading to soliton-based promising potential applications. Mathematically, the dynamics of vector solitons can be understood from the framework of the coupled nonlinear Schrödinger (CNLS) family of equations. In the recent past, many types of vector solitons have been identified both in the integrable and non-integrable CNLS framework. In this article, we review some of the recent progress in understanding the dynamics of the so called nondegenerate vector bright solitons in nonlinear optics, where the fundamental soliton can have more than one propagation constant. We address this theme by considering the integrable two coupled nonlinear Schrödinger family of equations, namely the Manakov system, mixed 2-CNLS system (or focusing-defocusing CNLS system), coherently coupled nonlinear Schrödinger (CCNLS) system, generalized coupled nonlinear Schrödinger (GCNLS) system and two-component long-wave short-wave resonance interaction (LSRI) system. In these models, we discuss the existence of nondegenerate vector solitons and their associated novel multi-hump geometrical profile nature by deriving their analytical forms through the Hirota bilinear method. Then we reveal the novel collision properties of the nondegenerate solitons in the Manakov system as an example. The asymptotic analysis shows that the nondegenerate solitons, in general, undergo three types of elastic collisions without any energy redistribution among the modes. Furthermore, we show that the energy sharing collision exhibiting vector solitons arises as a special case of the newly reported nondegenerate vector solitons. Finally, we point out the possible further developments in this subject and potential applications.

Simulating self-learning in photorefractive optical reservoir computers

Photorefractive materials exhibit an interesting plasticity under the influence of an optical field. By extending the finite-difference time-domain method to include the photorefractive effect, we explore how this property can be exploited in the context of neuromorphic computing for telecom applications. By first priming the photorefractive material with a random bit stream, the material reorganizes itself to better recognize simple patterns in the stream. We demonstrate this by simulating a typical reservoir computing setup, which gets a significant performance boost on performing the XOR on two consecutive bits in the stream after this initial priming step.

High-performance organic photorefractive materials containing 2-ethylhexyl plasticized poly(triarylamine)

We report high-performance photorefractive materials containing poly(triarylamine), chromophore, and photosensitizer, exhibiting optical sensitivity 15.8 cm3 kJ−1 with 2 ms response-time.

Theoretical Study of the Electronic Structure and Properties of Alternating Donor-Acceptor Couples of Carbazole-Based Compounds for Advanced Organic Light-Emitting Diodes (OLED)

Generally, it is difficult to generate a high-performance pure blue emission organic light-emitting diode (OLED). That is because the intrinsically wide band-gap makes it hard to inject charges into the emitting layer in such devices. To solve the problem, carbazole derivatives have been widely used because they have more thermal stability, a good hole transporting property, more electron rich (p-type) material, and higher photoconductivity. In the present work, novel copolymers containing donor-acceptor-acceptor-donor (D-A-A-D) blue compounds used for OLEDs were investigated. The theory of the geometrical and electronic properties of N-ethylcarbazole (ECz) as donor molecule (D) coupled to a series of 6 acceptor molecules (A) for advanced OLEDs were investigated. The acceptors were thiazole (TZ), thiadiazole (TD), thienopyrazine (TPZ), thienothiadiazole (TTD), benzothiadiazole (BTD), and thiadiazolothienopyrazine (TDTP). The ground state structure of the copolymers were studied using Density Functional Theory (DFT) at B3LYP/6-31G(d) level. Molecular orbital analysis study indicated 3 investigated copolymers (ECz-diTZ-ECz, ECz-diTD-ECz, ECz-diBTD-ECz) have efficient bipolar charge transport properties for both electron and hole injection to the TiO2 conduction band (4.8 eV). In addition, the excited states electronic properties were calculated using Time-Dependent Density Functional Theory (TD-DFT) at the same level. Among these investigated copolymer ECz-diTZ-ECz and ECz-diTD-ECz showed the maximum absorption wavelengths (λabs) with blue emitting at 429 and 431 nm, respectively. The results suggested that selected D-A-A-D copolymers can improve the electron- and hole- transporting abilities of the devices. Therefore, the designed copolymers would be a promising material for future development of light-emitting diodes, electrochromic windows, photovoltaic cells, and photorefractive materials.