Investigation of the Ferredoxin’s Influence on the Anaerobic and Aerobic, Enzymatic H2 Production

Ferredoxins are metalloproteins that deliver electrons to several redox partners, including [FeFe] hydrogenases that are potentially a component of biological H2 production technologies. Reduced ferredoxins can also lose electrons to molecular oxygen, which may lower the availability of electrons for cellular or synthetic reactions. Ferredoxins thus play a key role in diverse kinds of redox biochemistry, especially the enzymatic H2 production catalyzed by [FeFe] hydrogenases. We investigated how the yield of anaerobic and aerobic H2 production vary among the four different types of ferredoxins that are used to deliver electrons extracted from NADPH within the synthetic, fermentative pathway. We also assessed the electron loss due to O2 reduction by reduced ferredoxins within the pathway, for which the difference was as high as five-fold. Our findings provide valuable insights for further improving biological H2 production technologies and can also facilitate elucidation of mechanisms governing interactions between Fe–S cluster(s) and molecular oxygen.

Adaptive Response by an Electrolyte: Resilience to Electron Losses in a Dye-Sensitized Porous Photoanode

Photovoltage and photocurrents below theoretical limits in dye-sensitized photoelectrochemical solar energy conversion systems are usually attributed to electron loss processes such as dye-electron and electrolyte-electron recombination reactions within the porous...

Negative ion formation by neutral hydrogen atom grazing scattering from a LiF(100) surface

H− conversion during H0 grazing scattering on a LiF(100) surface, includes H− affinity electron loss to a surface image state.

Calculations of Electron Loss to Continuum in Collisions of Li- and Be-Like Uranium Ions with Nitrogen Targets

Doubly differential cross sections for projectile ionization in fast collisions of few-electron uranium ions with the nitrogen target are calculated within the first order of the relativistic perturbation theory. A comparison with the recent measurements of the energy distribution of forward-emitted electrons is made and good agreement is found.

Cell Charge Loss by Formation of Inversion Channel in DRAM

As dimension shrinkage, uncommon phenomena have been occurring during write and read operation in DRAM. These phenomena are strongly related cell capacitance, and the sensitivity of leakage current increases. Leakage current, especially in cell capacitor or cell transistor, is a major cause of the imbalance between stored charge in write operation and served charge in the read operation. Generally, error induced by leakage current appears data-1 failure, but in our study data-0 failure is observed in the case of extreme low cell capacitance that failure level is ppb (parts per billion). Results show that this phenomenon is influenced by cell capacitance, gate/body voltage of cell transistor, and supplied voltage level of the bitline sense amplifier. Based on various results, the electron loss to form inversion electron channel of cell transistor is regarded as a major factor like Charge Feedthrough [5].