Synergy between iron oxide sites and nitrogen-doped carbon xerogel/diamond matrix for boosting the oxygen reduction reaction

The innovative design and facile synthesis of efficient and stable electrocatalysts for the oxygen reduction reaction (ORR) are crucial in the field of fuel cells.

Xerogel-like Materials from Sustainable Sources: Properties and Electrochemical Performances

Energy storage is currently one of the most significant technological challenges globally, and supercapacitor is a prominent candidate over batteries due to its ability for fast charging and long lifetime. Supercapacitors typically use porous carbon as electrodes, because of both the high conductivity and surface area of the material. However, the state-of-the-art porous carbon described in the literature uses toxic chemicals and complex procedures that enhance costs and pollute the environment. Thus, a more sustainable procedure to produce porous carbon is highly desirable. In this context, xerogel-like carbons were prepared by a new, cheap, simple route to polymerization reactions of tannin-formaldehyde in a bio-oil by-product. Using bio-oil in its natural pH allowed a cost reduction and avoided using new reactants to change the reactional medium. Textural properties and electrochemical performances were improved by fast activating the material per 20 min. The non-activated carbon xerogel presented a capacitance of 92 F/g, while the activated one had 132 F/g, given that 77% of the components used are eco-friendly. These results demonstrate that renewable materials may find applications as carbon electrodes for supercapacitors. Overhauling the synthesis route with a different pH or replacing formaldehyde may enhance performance or provide a 100% sustainable carbon electrode.

Design of Self-Supported Flexible Nanostars MFe-LDH@ Carbon Xerogel-Modified Electrode for Methanol Oxidation

Layered double hydroxides (LDHs) have emerged as promising electrodes materials for the methanol oxidation reaction. Here, we report on the preparation of different LDHs with the hydrothermal process. The effect of the divalent cation (i.e., Ni, Co, and Zn) on the electrochemical performance of methanol oxidation was investigated. Moreover, nanocomposites of LDHs and carbon xerogels (CX) supported on nickel foam (NF) substrate were prepared to investigate the role of carbon xerogel. The results show that NiFe-LDH/CX/NF is an efficient electrocatalyst for methanol oxidation with a current density that reaches 400 mA·m−2 compared to 250 and 90 mA·cm−2 for NiFe-LDH/NF and NF, respectively. In addition, all LDH/CX/NF nanocomposites show excellent stability for methanol oxidation. A clear relationship is observed between the electrodes crystallite size and their activity to methanol oxidation. The smaller the crystallite size, the higher the current density delivered. Additionally, the presence of carbon xerogel in the nanocomposites offer 3D interconnected micro/mesopores, which facilitate both mass and electron transport.