Determination of the anisotropic thermal conductivity of an aerogel-based plaster using transient plane source method

Aerogel-based plasters are composite materials with declared thermal conductivities in the range of traditional insulating materials, i.e. 30-50 mW/(m·K). Based on the results from reported field measurements, aerogel-based plasters can significantly reduce the thermal transmittance of uninsulated walls. However, the in-situ measured thermal conductivities have sometimes been higher than the declared values measured in laboratory and in the main direction of the heat flow. Meanwhile, the anisotropic thermal performance of aerogel-based plasters, i.e., deviating thermal performance in the different directions of heat flow, has not been explored yet. The objective of this study is thus to evaluate the anisotropic thermal conductivity of an aerogel-based plaster. This is done in a set of laboratory measurements using the transient plane source method. Six identical and cubic samples with the dimensions of 10×10×10 cm3 were paired two and two, creating three identical sample sets. In total, 360 measurements of thermal conductivity and thermal diffusivity, and 130 measurements for specific heat capacity were conducted. The results indicate a weak anisotropy of less than ±6.5 % between the three directions (x, y, z). Considering the accuracy of the selected measurement technique, better than ±5 %, supplementary measurements using another technique are recommended.

Feasibility study of fracture interpretation using multicomponent seismic data: SEAM II Barrett model

Several P-wave azimuthal anisotropy studies have been conducted for the SEAM II Barrett model data. However, these analyses provide fracture property estimation that is inconsistent with the actual model properties. Therefore, we perform a feasibility study to understand the influence of the overburden and reservoir properties, and the processing and inversion steps, which together determine the success of the fracture interpretation from seismic data. 1D model properties (orthorhombic for both overburden and reservoir) are first extracted from the actual Barrett model properties at two locations. Anisotropic prestack reflectivity modeling exposes the true orthorhombic response of the 1D medium in the form of Common Offset and Common Azimuth (COCA) gathers. The true anisotropic response is obscured in the Barrett data (generated by finite element modeling) due to the mild lateral velocity variations and orthorhombic anisotropy in the overburden. We then expose the reservoir anisotropic response by using an isotropic overburden in the reflectivity modeling. This shows that the P-wave VVAZ responses generated by the reservoir itself are weak, which leads to an unstable VVAZ inversion to estimate the interval NMO velocity anisotropy. The reservoir thickness (125m or 65ms TWT) or NMO velocity anisotropy (6-7%) needs to be at least doubled to obtain a stable VVAZ inversion. Anisotropic geometrical-spreading correction improves the amplitude-versus-azimuth (AVAZ) inversion results when reflectivity modeling models orthorhombic overburden. The converted wave ( C-wave) has a stronger VVAZ response compared to the P-wave. We suggest that the C-wave data could be useful to constrain fracture interpretation in the Barrett model. We conclude that the results of previous studies are due to the combination of the residual influence of overburden after processing and imaging, and the weak anisotropy responses from the reservoir.

Selective Anisotropy of Mechanical Properties in Inconel718 Alloy

Mechanical anisotropy behaviors are investigated in slightly rolled Inconel718 alloy with string-like δ phase and carbides produced during various solid-solution and aging treatments. A weak anisotropy in the strengths and rupture properties at 650 °C is visible, whereas ductility, i.e., reduction in area (RA) and impact toughness (CVN), presents a sound anisotropy behavior. MC carbides promote the operation of slip systems and thus are conducive to weakening the strength anisotropy. The RA anisotropy mainly stems from high-density δ phase particles that provide more crack nucleation sites and stimulate rapid propagation because of the shorter bridge distance between micro-cracks at the rolling direction. In contrast, CVN anisotropy arises from both δ phase and carbides at a lower solid-solution temperature of 940 °C but only depends on carbides at 980 °C where the δ phase fully dissolves. Apart from dislocation motions operated at room temperature, the activated grain boundary processes are responsible for the weak anisotropy of rupture properties at the elevated temperature. This work provides a guideline for technological applications in the hot working processes for Inconel718 alloys.

Weak-anisotropy approximation of P-wave geometrical spreading in horizontally layered anisotropic media of arbitrary symmetry: TTI specification

Understanding the role of geometrical spreading and estimating its effects on seismic wave propagation play an important role in several techniques used in seismic exploration. The spreading can be estimated through dynamic ray tracing or determined from reflection traveltime derivatives. In the latter case, derivatives of non-hyperbolic moveout approximations are often used. We offer an alternative approach based on the weak-anisotropy approximation. The resulting formula is applicable to P-waves reflected from the bottom of a stack of horizontal layers, in which each layer can be of arbitrary anisotropy. At an arbitrary surface point, the formula depends, in each layer, on the thickness of the layer, on the P-wave reference velocity used for the construction of reference rays, and on nine P-wave weak-anisotropy (WA) parameters specifying the layer anisotropy. Along an arbitrary surface profile, the number of WA parameters reduces to five parameters related to the profile. WA parameters represent an alternative to the elastic moduli, and as such can be used for the description of any anisotropy. The relative error of the approximate formula for a multilayered structure consisting of layers of anisotropy between 8% and 20% is, at most, 10%. For models including layers of anisotropy stronger than 20%, the relative errors may reach, locally, even 30%. For any offset, relative errors remain under a finite limit, which varies with anisotropy strength.

Анизотропия анионной проводимости в монокристаллах суперионного проводника CeF-=SUB=-3-=/SUB=-

The anisotropy of anionic conductivity in crystals of a superionic conductor CeF3 with the tysonite structure (sp. gr. P-3с1) has been studied for the first time. The conductivity measurements at temperatures from 300 K to 600 K were carried out along the principal a- and c-axes of trigonal unit cell of the crystal. The maximum value of electrical conductivity is observed along the c-axis. The superionic CeF3 crystals have the weak anisotropy of electrical conductivity equal to σ||c/σ||a = 2.4 and σ||c = 5.6 10–4 S/cm at 500 K. The anisotropy effect of anionic conductivity in individual fluorides with the tysonite structure is discussed in connection with the peculiarities of their atomic structure.

Carrier Concentration of CeFe2Al10 as a Candidate of Thermoelectric Material

The study of Hall effect of Kondo semiconductor CeFe2Al10 is reported as a candidate of thermoelectric material used at low temperatures. Single crystals of CeFe2Al10 with orthorhombic crystal structure were grown by Al self-flux method. An anisotropy of the Hall effect is clarified by measuring Hall resistance by changing the direction of electrical current, magnetic field, and voltage respect to all the three crystal axes of orthorhombic crystal structure. The Hall effect of CeFe2Al10 has a strong anisotropy against the direction of magnetic field but weak anisotropy against the directions of current and voltage. The value of carrier concentration indicates that CeFe2Al10 is matallic, which causes a low performance as a thermoelectric material. In order to improve the value of dimensionless figure of merit, the electrons should be doped to CeFe2Al10.

Estimation of weak anisotropy parameters and fracture density of asymmetric fractures in monoclinic medium

One of the typical anisotropic media is the monoclinic anisotropy (MA) medium, which is formed by embedding two sets of non-orthogonal fracture sets into an isotropic or vertical transverse isotropic (VTI) background medium. Weak anisotropy (WA) parameters and fracture density provide important in situ stress and high-porosity zone information. Estimation of WA parameters and fracture density of MA medium by prestack seismic amplitude inversion is important for shale reservoir characterisation. We derive the expression of generalised WA parameters in a basic reflection coefficients formula of MA medium by incorporating a stiffness matrix of VTI background and disturbance compliance matrix of asymmetric fracture. We then re-express the P-wave reflection coefficients in terms of WA parameters and fracture compliance tensors. To achieve the direct inversion of fracture density, we rewrite the linearised expression of P-wave reflection coefficients related to WA parameters and fracture density. Finally, under the Bayesian framework, the WA parameters and fracture density are estimated by using the amplitude versus offset and azimuth (AVOA) inversion parameters. We use a Monte Carlo simulation to test the effect of uncertainties in the priori information about fracture property parameters. The application of synthetic seismic gathers show that the proposed inversion strategy is reliable within moderate noise. Compared with the results obtained by using inversion based on a rotationally invariant fracture, the test indicates that a fracture model with a simplified shape or wrong assumption will increase calculation error and reduce the inversion accuracy.