stainless steel slag
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2021 ◽  
Author(s):  
Elia Boonen ◽  
Slyvie Smets ◽  
Audrey Van der Wielen

Alternative aggregates, including recycled (concrete) aggregates as well as artificial aggregates (such as crushed stainless steel slag), are being increasingly used in road construction in the context of a more circular economy, e.g. in base and subbase layers. As these materials are applied higher up in the structure (surface and binder courses), stricter requirements are made to allow for higher loads and the stronger influence of the environment, and the application of these aggregates becomes less straightforward. The Belgian standard specifications, for instance, allow incorporation of recycled concrete aggregates in concrete pavements or linear elements in concrete, but only if certain stringent requirements are met and only up to certain percentages of substitution of the natural coarse aggregates. Furthermore, artificial aggregates originating from stainless steel slag are not even allowed for the time being in pavement quality concrete, although a Belgian standardization working group has recently been installed to investigate this matter in more detail. This paper presents an overview of laboratory research conducted in Belgium to characterize several types of alternative aggregates and concrete mixtures incorporating them, while focusing on practical execution as well as on the durability of pavement concrete. In addition, several concomitant pilot applications in Belgium are discussed in view of future perspectives for the application of alternative (recycled and/or artificial) aggregates in road construction.


2021 ◽  
Vol 11 (24) ◽  
pp. 12106
Author(s):  
Mattia De Colle ◽  
Ross Kielman ◽  
Andreas Karlsson ◽  
Andrey Karasev ◽  
Pär G. Jönsson

Several stainless-steel slags have been successfully employed in previous studies as substitutes for lime in the treatment of industrial acidic wastewaters. This study deepens the knowledge of such application, by analyzing the neutralizing capacity of different slags related to their mineral compositions. To do so, firstly the chemical and mineral compositions of all the slag samples are assessed. Then, 0.5 g, 1 g, 2 g of each slag and 0.25 g and 0.5 g of lime are used to neutralize 100 g of 0.1 M HCl or HNO3 solutions. After the has neutralization occurred, the solid residues are extracted and analyzed using XRD spectroscopy. Then, the solubility of the minerals is assessed and ranked, by comparing the XRD spectra of the residues with the obtained pH values. The results show that minerals such as dicalcium silicate and bredigite are highly soluble in the selected experimental conditions, while minerals such as merwinite and åkermanite, only partially. Moreover, Al-rich slags seem to perform poorly due to the formation of hydroxides, which generate extra protons. However, when the weight of slag is adequately adjusted, Al-rich slags can increase the pH values to higher levels compared to the other studied slags.


Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2266
Author(s):  
Meng-Jie Tao ◽  
Ya-Jun Wang ◽  
Jun-Guo Li ◽  
Ya-Nan Zeng ◽  
Shao-Hua Liu ◽  
...  

Argon oxygen decarburization stainless steel slag (AOD slag) has high mineral carbonation activity. AOD slag carbonation has both the resource utilization of metallurgical waste slag and the carbon reduction effect of CO2 storage. This paper aimed to study carbonation reaction characteristics of AOD slag. Under the slurry-phase accelerated carbonation route, the effect of stirring speed (r) and reaction temperature (T) on AOD slag’s carbonation was studied by controlling the reaction conditions. Mineral composition analysis and microscopic morphology analysis were used to explore the mineral phase evolution of AOD slag during the carbonation process. Based on the unreacted core model, the kinetic model of the carbonation reaction of AOD slag was analyzed. The results showed that the carbonation ratio of AOD slag reached its maximum value of 66.7% under the reaction conditions of a liquid to solid ratio (L/S) of 8:1, a CO2 partial pressure of 0.2 MPa, a stirring speed of 450 r.min−1, and a reaction temperature of 80 °C. The carbonation reaction of AOD slag was controlled by internal diffusion, and the calculated apparent activation energy was 22.28 kJ/mol.


Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1498
Author(s):  
Ya-Jun Wang ◽  
Meng-Jie Tao ◽  
Jun-Guo Li ◽  
Ya-Nan Zeng ◽  
Song Qin ◽  
...  

EAF stainless steel slag (EAF slag) is one kind of chromium-bearing metallurgical solid waste, which belongs to alkaline steel slag, and contains a large number of alkaline mineral phases. The carbonation activity of these minerals gives EAF slag the capability to effectively capture CO2. In this paper, EAF slag samples with different carbonation degrees were prepared by the slurry-phase accelerated carbonation route. The mineralogical identification analysis was used to qualitatively and semi-quantitatively determine the types and contents of the carbonatable mineral phases in the EAF slag. The sequential leaching test was used to study the chromium leachabilities in EAF slags with different carbonation degrees. The results showed that the main minerals with carbonation activity in EAF slag were Ca3Mg(SiO4)2 and Ca2SiO4, with mass percentages of 56.9% and 23%, respectively. During the carbonation process, Ca2SiO4 was the main reactant and calcite was the main product. As the degree of carbonation increased, the pH of the EAF slags’ leachate gradually decreased while the redox potential (Eh) gradually increased. At the same time, a large amount of Ca2+ in the EAF slag combined with CO2 to form slightly soluble calcium carbonate, which led to a significant decrease in the conductivity of the leachate. With the gradual increase in carbonation ratio, the leachability of chromium in the EAF slag first decreased and then increased, and reached its lowest value when the CO2 uptake ratio was 11.49%.


Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1055
Author(s):  
Qiang Zeng ◽  
Jianli Li ◽  
Yue Yu ◽  
Hangyu Zhu

Stainless steel slag has been applied to other silicate materials due to its CaO-SiO2-based system. This is done to improve the utilization rate of stainless steel slag and apply it more safely. This paper investigated the occurrence of chromium in synthetic stainless steel slag containing FetO and its leaching behavior. The phase composition of the equilibrium reaction was calculated by FactSage 7.3 Equlib module. XRD, SEM-EDS and IPP 6.0 were used to investigate the phase compositions, microstructure and count the size of spinel crystals. The results indicate that the increase of Fe2O3 content can promote the precipitation of spinel phases and effectively inhibit the formation and precipitation of α-C2S in a CaO-SiO2-MgO-Cr2O3-Al2O3-FeO system. Fe2O3 contents increased from 2 wt% to 12 wt%, and the crystal size increased from 4.01 μm to 6.06 μm, with a growing rate of 51.12%. The results of SEM line scanning show the Cr-rich center and Fe-rich edge structure of the spinel phase. Comparing the TRGS 613 standard with the HJ/T 299-2007 standard, the leaching of Cr6+ in the FetO samples is far lower than the standards’ limit, and the minimum concentration is 0.00791 mg/L in 12 wt% Fe2O3 samples.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3945
Author(s):  
Julia Rosales ◽  
Francisco Agrela ◽  
José Luis Díaz-López ◽  
Manuel Cabrera

This work develops the manufacture of self-compacting concrete (SCC) with 50% cement reduction. As an alternative binder to cement, the viability of using an alkali-activated combination of stainless steel slag (SSS) and fly ash (FA) has been demonstrated. SSS was processed applying three different treatments. Binders were manufactured mixing 35% SSS with 65% FA, as precursors, and a hydroxide activating solution. This binder was replaced by the 50% cement for the manufacture of SCC. The results obtained show good mechanical properties and durability. The study shows a reduction in the use of cement in the manufacture of SCC reusing two wastes.


2021 ◽  
Vol 11 (14) ◽  
pp. 6418
Author(s):  
Hadi Kazemi Kamyab ◽  
Peter Nielsen ◽  
Peter Van Mierloo ◽  
Liesbeth Horckmans

To reduce CO2 emissions from the building industry, one option is to replace cement in specific applications with alternative binders. The Carbstone technology is based on the reaction of calcium- and magnesium-containing minerals with CO2 to form carbonate binders. Mixes of carbon steel slag and stainless-steel slag, with tailored particle size distributions, were compacted with a vibro-press and subsequently carbonated in an autoclave to produce carbonated steel slag pavers. The carbonated materials sequester 100–150 g CO2/kg slag. Compressive and tensile splitting strength of the resulting pavers were determined, and the ratio was found to be comparable to that of concrete. The environmental performance of the Carbstone pavers, with an average tensile splitting strength of 3.6 MPa, was found to be in compliance with Belgian and Dutch leaching limit values for construction materials. In addition, leaching results for a concrete mix made with aggregates of crushed Carbstone pavers (simulating the so-called “second life” of pavers) demonstrate that the pavers can be recycled as aggregates in cement-bound products after their product lifetime.


Author(s):  
Yeong-Nain Sheen ◽  
Duc-Hien Le ◽  
My Ngoc-Tra Lam

Recently, stainless steel slag -a byproduct of manufacturing stainless steel is accepted as a cementitious material, the chemical characteristics of which are highly variant. This study reuses two types of stainless steel reducing slag with specific surface area of 1766 cm2/g (S1) and 7970 cm2/g (S2) in developing self-compacting concrete (SCC). Particularly, two S2-blended SCCs incorporating with S1 and fly ash as fillers (calling as S-mix and F-mix) were prepared for a comparative investigation. In both SCCs, ordinary Portland cement was replaced by S2 with various ratios (from 0 % to 50 %, increment 10 %). Testing results show that in fresh state, the F-mix exhibits higher workability and longer initial setting time than those of S-mix. In hardened state, 10 % compressive strength loss was realized as increasing S2 content up to 30 % in the both SCCs; the strength of F-mix is up to 1.9 times of S-mix at the same rate of S2 replacement. Water absorption of the F-mix was below 3 %, suggested as a “good” quality concrete; whilst the S-mix could be longs to an “average” one. Resistivity and sulfate resistance of F-mix are considerably higher than those of S-mix. Moreover, based on the obtained data, compressive strength and electrical resistivity are correlated well with a logarithmic form.


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