scholarly journals Alkali-Activated Stainless Steel Slag as a Cementitious Material in the Manufacture of Self-Compacting Concrete

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3945
Author(s):  
Julia Rosales ◽  
Francisco Agrela ◽  
José Luis Díaz-López ◽  
Manuel Cabrera

This work develops the manufacture of self-compacting concrete (SCC) with 50% cement reduction. As an alternative binder to cement, the viability of using an alkali-activated combination of stainless steel slag (SSS) and fly ash (FA) has been demonstrated. SSS was processed applying three different treatments. Binders were manufactured mixing 35% SSS with 65% FA, as precursors, and a hydroxide activating solution. This binder was replaced by the 50% cement for the manufacture of SCC. The results obtained show good mechanical properties and durability. The study shows a reduction in the use of cement in the manufacture of SCC reusing two wastes.

Author(s):  
Yeong-Nain Sheen ◽  
Duc-Hien Le ◽  
My Ngoc-Tra Lam

Recently, stainless steel slag -a byproduct of manufacturing stainless steel is accepted as a cementitious material, the chemical characteristics of which are highly variant. This study reuses two types of stainless steel reducing slag with specific surface area of 1766 cm2/g (S1) and 7970 cm2/g (S2) in developing self-compacting concrete (SCC). Particularly, two S2-blended SCCs incorporating with S1 and fly ash as fillers (calling as S-mix and F-mix) were prepared for a comparative investigation. In both SCCs, ordinary Portland cement was replaced by S2 with various ratios (from 0 % to 50 %, increment 10 %). Testing results show that in fresh state, the F-mix exhibits higher workability and longer initial setting time than those of S-mix. In hardened state, 10 % compressive strength loss was realized as increasing S2 content up to 30 % in the both SCCs; the strength of F-mix is up to 1.9 times of S-mix at the same rate of S2 replacement. Water absorption of the F-mix was below 3 %, suggested as a “good” quality concrete; whilst the S-mix could be longs to an “average” one. Resistivity and sulfate resistance of F-mix are considerably higher than those of S-mix. Moreover, based on the obtained data, compressive strength and electrical resistivity are correlated well with a logarithmic form.


Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3307 ◽  
Author(s):  
Jinyan Liu ◽  
Cheng Yi ◽  
Hongguang Zhu ◽  
Hongqiang Ma

In order to compare the properties of alkali-activated carbon steel slag (CSS) and stainless steel slag (SSS), the effects of sodium hydroxide/sodium silicate solution mass ratio (NH/NS), liquid/solid ratio and blast furnace slag (BFS) dosage on the compressive strength, hydration products and hydration degree of CSS and SSS were studied. Furthermore, a combination of X-ray diffraction (XRD), thermo-gravimetric analysis coupled with differential thermal analysis (TGA-DTA), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope-energy dispersive spectrometer (SEM-EDS) were used to characterize the morphology and structure of alkali-activated CSS-BFS and SSS-BFS cementitious materials. As the results revealed, the primary hydrate of alkali-activated CSS and SSS is C-(A)-S-H with Q2 [SiO4] units, which has a low Ca/Si ratio and includes inert phases like a CaO-FeO-MnO-MgO solid solution (RO) in CSS while cuspidine, magnesiochromite etc. in SSS. More active C3S and β-C2S promote the alkali activation of CSS, whereas the less active γ-C2S hinders the depolymerization of SSS. The incorporation of BFS does not change the hydrate, whose seed effect is helpful for accelerating the depolymerization and polycondensation of CSS and SSS, especially for SSS, and makes the hydrate increase significantly. Owing to the high SiO2 and Al2O3 contents of SSS, the C-(A)-S-H chain length is increased, thus facilitating the polycondensation effect. In this study, the optimal NH/NS of CSS and SSS is NH/NS= 1:2, and the optimal liquid/solid ratio is 0.29. Compared to CSS–BFS, the C-(A)-S-H gel produced by SSS–BFS has lower Ca/Si and Al/Si ratios. Unlike CSS, pure SSS is inappropriate as an alkali-activated precursor and needs to be co-activated with BFS.


Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2049
Author(s):  
Julia Rosales ◽  
Francisco Agrela ◽  
José Antonio Entrenas ◽  
Manuel Cabrera

The volume of slags generated from the steel industry is a source of possible resources which is constantly increasing. Specifically, in the production of stainless steel, specific and singular slags with unique characteristics are obtained, which allows considering an approach aimed at their use in new recycling ways. This work shows the feasibility of using stainless steel slag as a substitute for limestone filler in the manufacture of self-compacting concrete. The influence of different treatments applied to slags on physical and chemical properties was studied. On the other hand, the mechanical behaviour, as well as the durability acquired in self-compacting concrete, has been analysed. Very encouraging results were obtained, since this research demonstrates the possible application of this stainless steel slag as a construction material, improving sustainability and promoting circular economy processes, which are achieved through the minimisation of the waste disposal and accumulation.


2019 ◽  
Vol 23 (9) ◽  
pp. 3875-3888 ◽  
Author(s):  
Anant Lal Murmu ◽  
Anamika Jain ◽  
Anjan Patel

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 495
Author(s):  
Mingkai Zhou ◽  
Xu Cheng ◽  
Xiao Chen

The stability of steel-slag road materials remains a critical issue in their utilization as an aggregate base course. In this pursuit, the present study was envisaged to investigate the effects of fly ash on the mechanical properties and expansion behavior of cement-fly-ash-stabilized steel slag. Strength tests and expansion tests of the cement-fly-ash-stabilized steel slag with varying additions of fly ash were carried out. The results indicate that the cement-fly-ash-stabilized steel slag exhibited good mechanical properties. The expansion rate and the number of bulges of the stabilized material reduced with an increase in the addition. When the addition of fly ash was 30–60%, the stabilized material was not damaged due to expansion. Furthermore, the results of X-CT, XRD and SEM-EDS show that fly ash reacted with the expansive component of the steel slag. In addition, the macro structure of the stabilized material was found to be changed by an increase in the concentration of the fly ash, in order to improve the volumetric stability. Our study shows that the cement-fly-ash-stabilized steel slag exhibits good mechanical properties and volumetric stability with reasonable additions of fly ash.


2011 ◽  
Vol 105-107 ◽  
pp. 2204-2208 ◽  
Author(s):  
Run Xia Hao ◽  
Xiao Yan Guo

The properties of flue gas desulphurization (FGD) gypsum were analysized by Thermo-gravimetry/differential scanning calorimetry (TG/DSC), technical performance analysis, optical microscope and Scanning electron microscope (SEM). Mechanical properties of FGD gypsum-steel slag powder cementitious material were researched. The results revealed that FGD gypsum have similar moisture content, major component CaSO4·2H2O with natural gypsum, and has better technical performance than natural gypsum. The results of optical microscope and SEM of the FGD gypsum hydration support this further. When the dosage of steel slag powder is 15%, containing activator ,better mechanical properties can be obtained. Key words: FGD gypsum, Property, Cementitious material


2018 ◽  
Vol 761 ◽  
pp. 73-78 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Alkali-activated materials based on fly ash are widely developed and also produced on the present. Some of fly ashes are not suitable for production of alkali-activated materials because of their inconvenient chemical composition. Alumina-silicates are the most important components that are needed to accomplish the successful reaction. The proper content of amorphous phase of alumina-silicates and its proportion as well should be provided for the final composition of alkali-activated materials. The influence of pure aluminum oxide powder as well as raw milled natural perlite on mechanical properties and durability of alkali-activated mortars was investigated. These minerals were used as partial replacement of fly ash coming from black coal combustion. In addition, the mortars were prepared by using different alkali activators.


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