Colorants in coatings

The aim of this chapter is to provide a compact overview of colorants and their use in coatings including a brief introduction to paint technology and its raw materials. In addition, it will focus on individual colorants by collecting information from the available literature mainly for their use in coatings. Publications on colorants in coatings applications are in many cases standard works that cover the wider aspects of color chemistry and paint technology and are explicitly recommended for a more detailed study of the subject [1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18]. Articles or information on paint formulation using coatings which contain colorants are rare [19]. This formulation expertise is often company property as it is the result of many years of effort built up over very long series of practical “trial-and-error” optimization tests and, more recently, supported by design of experiment and laboratory process automation [20, 21]. Therefore, it is protected by rigorous secrecy agreements. Formulations are in many ways part of a paint manufacturer’s capital, because of their use in automotive coatings, coil coatings, powder coatings, and specialist knowledge is indispensable to ensure their successful industrial use [22]. An important source to learn about the use of pigments in different coating formulations are guidance or starting formulations offered by pigment, additive, and resin manufacturers. These are available upon request from the technical service unit of these companies. Coating formulations can also be found scattered in books on coating and formulation technology [4, 5, 18, 23,24,25,26,27]. This overview can in no way claim to be complete, as the literature and relevant journals in this field are far too extensive. Nevertheless, it remains the author’s hope that the reader will gain a comprehensive insight into the fascinating field of colorants for coatings, including its literature and current research activities and last but not least its scientific attractiveness and industrial relevance.

Study of the Adhesion of Silicate-Based Coating Formulations on a Wood Substrate

Silicate coatings are environmentally friendly inorganic-based products that have long been used for mineral substrates and protection of steel against corrosion. The development and acceptance of these coatings in the wood sector require some adjustments in formulations or special preparation of the surface to be coated to obtain durable finishes. In this work, the adhesion of various silicate-based formulations to a beech wood substrate (Fagus sylvatica L.), was assessed with the main objective to study relevant parameters and potential improvements. Adhesion strength was determined by pull-off and cross-cut tests. Other coating properties such as scratch, impact, and water resistance were also determined. Surface roughness and interface were analyzed using confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM), and coating curing was studied by attenuated total reflection-infrared spectroscopy (ATR FTIR). The results showed that adhesion was highly dependent on formulation, penetration of the coatings into wood, and mechanical anchoring. Increasing the content of solid particles in the coating formulations or adding a polyol (glycerol, xylose), which probably acted as a coalescent, considerably decreased the adhesion strength, probably by blocking penetration into the wood by forming aggregates. Adhesion was improved by pre-mineralization of the surface, and substitution of a part of the potassium silicate binder with potassium methyl siliconate reduced the formation of cracks caused by dimensional instability of the wood.

Improvement of Andean Blueberries Postharvest Preservation Using Carvacrol/Alginate-Edible Coatings

Edible coatings are attractive strategies for blueberries postharvest preservation. In this work, carvacrol/alginate coatings were developed for application on Andean blueberries. Coating formulations were prepared based on blends of sodium alginate (2% w/v), carvacrol (0%, 0.03%, 0.06% or 0.09%), glycerol, and water and applied to the fruits by dip-coating. Then, the fruits were immersed in a calcium batch to induce a crosslink reaction. Changes in the physicochemical and microbiological characteristics of the blueberries were monitored during 21 days of storage at 4 °C. Coated blueberries were better preserved throughout the 21 days of storage because of their lower respiration rate and water loss, in comparison with the uncoated ones. Besides, the coatings enhanced the appearance and the gloss of the fruits. Control fruits showed a significant decrease in the firmness, while, in the coated fruits, this critical postharvest quality was preserved during the entire storage. Coating formulations with 0.09% of carvacrol was the most effective in preventing mesophilic aerobic bacteria and molds/yeasts growth on the fruits during the storage. Edible carvacrol/alginate coatings can be considered as a useful alternative to complement the benefits of refrigerated storage by delaying post-harvest spoilage of Andean blueberries.