Effects of Three Different Types of Aloin on Optical, Mechanical, and Antibacterial Properties of Waterborne Coating on Tilia europaea Surface

The microcapsules were prepared by using melamine-formaldehyde resin as the wall material and aloin as the core material. The aloin was dissolved in ethanol and water to prepare microcapsules. The aloin powder, the aloin microcapsules prepared with ethanol as the solvent, and the aloin microcapsules prepared with water as the solvent were, respectively, added to the waterborne coating with different contents and coated on the surface of Tilia europaea. The effects of different modifiers and contents on the coating’s optical properties, mechanical properties, and antibacterial properties were explored. The results showed that the aloin microcapsules prepared with ethanol as the solvent had good morphology and comprehensive properties. When the content was 7.0%, the color difference of the waterborne coating was small, the adhesion was grade 3, the impact resistance was 12 kg·cm, and the antibacterial rate was 87.8%. In terms of antibacterial properties, the uncoated aloin powder, the coated aloin microcapsules prepared with ethanol as the solvent, and the aloin microcapsules prepared with water all have certain antibacterial properties and the antibacterial rates reached 99.2%, 97.3%, and 67.3%, respectively. This study provides a certain reference for developing antibacterial wood furniture coatings.

Effect of Coating Process on Mechanical, Optical, and Self-Healing Properties of Waterborne Coating on Basswood Surface with MF-Coated Shellac Core Microcapsule

Self-repairing microcapsules prepared with melamine formaldehyde (MF) resin as wall material and shellac and waterborne coating as core material were added to waterborne coating to prepare a self-repairing coating. In order to explore the effect of the coating process on the performance of the waterborne coating on the basswood surface with microcapsules, the number of coating layers of primer and finish and the addition mode of the microcapsules were tested as influencing factors. The effects of different coating processes on the optical, mechanical, and liquid resistance of the basswood surface coating were investigated. The results showed that different coating processes had little effect on the color difference of the coating. When the coating process was two layers of primer and three layers of finish, and microcapsules were added to the finish, the minimum gloss of the basswood surface coating at 60° incident angle was 10.2%, and the best mechanical properties, liquid resistance, and comprehensive properties were achieved. Finally, the aging resistance and self-healing performance of the waterborne coating on the basswood surface prepared by this coating process were explored. The results showed that the waterborne coating had a certain repair effect on scratch damage. This paper lays a theoretical foundation for the practical application of self-healing microcapsules in wood-surface waterborne coatings.

Effect of Microcapsules with Waterborne Coating as Core Material on Properties of Coating for Tilia Europaea and Comparison with Other Microcapsules

Urea formaldehyde was used as wall material and waterborne coatings as a core material to prepare microcapsules. So as to explore the influence of mass ratio of core to shell, reaction temperature and standing time on the performance of microcapsules, the orthogonal test of three factors and two levels was put into effect. The orthogonal experimental results showed the mass ratio of core to shell was the most important factor. With the increase of the mass ratio of core to shell, the output and clad ratio of microcapsules increased first and then decreased. The microcapsule with the mass ratio of core to shell of 0.67:1 had better appearance, output, and encapsulation performance. The optical properties of waterborne wood coating with the microcapsules of waterborne coating as core materials did not decrease significantly, while the hardness, impact resistance, and toughness were improved. At the same time, the microcapsules have a certain self-repairing effect on coating micro-cracks. Compared with the properties of waterborne coatings with other microcapsules, the coating with waterborne coating as core material has better comprehensive performance. The results provide a new research idea for the performance enhancement and self-healing of wood waterborne coating.

Effect of Shellac Waterborne Coating Microcapsules on the Optical, Mechanical and Self-Healing Properties of Waterborne Primer on Tilia europaea L. Wood

Microcapsules of melamine formaldehyde-coated shellac and waterborne coating were prepared by in situ polymerization at 400, 600, 800 and 1000 rpm. The microcapsules prepared at four different stirring rates were added into the waterborne primer at a concentration of 5.0%, 10.0%, 15.0%, 20.0% and 25.0%. The effects of microcapsules prepared at different stirring rates and the concentration of microcapsules added into the paint film on the optical, mechanical and liquid resistance properties of the paint film were investigated. The results showed that the comprehensive performance of Tilia europaea L. waterborne primer film was the best when the concentration of microcapsules obtained at 600 rpm was 5.0%. On this basis, the aging resistance and self-healing performance of waterborne primer film on Tilia europaea L. with the best comprehensive performance were explored to lay the foundation for optimizing the preparation process of self-healing coating.