Development and Evaluation of Ultra-High Temperature Resistant Preformed Particle Gels for Conformance Control in North Sea Reservoirs

Preformed particle gels (PPGs), a type of hydrogel, have been widely applied to control the conformance of reservoirs owing to their robust gel chemistries. Traditional PPGs are polyacrylamide-based hydrogel compositions which can withstand neither higher temperatures nor high salinity conditions. There are many deep oilfield reservoirs worldwide which demand PPG products with a long term hydrolytic and thermal stability at the temperatures of higher than 120 °C. Current PPGs neither remain hydrated nor retain polymer integrity at these temperatures. A unique high temperature-resistant hydrogel composition (HT-PPG) was developed with exceptional thermal stability for greater than 18 months in North Sea formation temperature (~130 °C) and formation water environments. HT-PPG described herein can swell up to 30 times its initial volume in brines of different salinity for North Sea. The effects of salinity and temperature on swelling, swelling rate, and rheological behavior was studied. These HT-PPGs exhibit excellent strength with storage modulus (G’) of over 3,000 Pa at the swelling ratio of 10. Thermostability evaluations were performed in North Sea brines with variable salinity at temperatures of 130 °C and 150 °C and found to be stable for 18 months with no loss of molecular integrity at the higher temperature. Laboratory core flooding tests were conducted to test its plugging efficiency to fracture. HT-PPGs showed good plugging efficiency by reducing the permeability of open fracture and did not wash out during waterflooding. Overall, HT-PPG is a novel product with excellent hydrothermal stability that make it an ideal candidate for conformance problems associated with reservoirs of high temperature and salinity conditions.

Experimental Study of Microgel Conformance-Control Treatment for a Polymer-Flooding Reservoir Containing Superpermeable Channels

SummaryPolymer flooding has been widely used to improve oil recovery. However, its effectiveness would be diminished when channels (e.g., fractures, fracture-like channels, void-space conduits) are present in a reservoir. In this study, we designed a series of particular sandwich-like channel models and tested the effectiveness and applicable conditions of micrometer-sized preformed particle gels (PPGs, or microgels) in improving the polymer-flooding efficiency. We studied the selective penetration and placement of the microgel particles, and their abilities for fluid diversion and oil-recovery improvement. The results suggest that polymer flooding alone would be inefficient to achieve a satisfactory oil recovery as the heterogeneity of the reservoir becomes more serious (e.g., permeability contrast kc/km > 50). The polymer solution would vainly flow through the channels and leave the majority of oil in the matrices behind. Additional conformance-treatment efforts are required. We tried to inject microgels in an attempt to shut off the channels. After the microgel treatment, impressive improvement of the polymer-flooding performance was observed in some of our experiments. The water cut could be reduced significantly by as high as nearly 40%, and the sweep efficiency and overall oil recovery of the polymer flood were improved. The conditions under which the microgel-treatment strategy was effective were further explored. We observed that the microgels form an external impermeable cake at the very beginning of microgel injection and prevent the gel particles from entering the matrices. Instead, the microgel particles could selectively penetrate and shut off the superpermeable channels under proper conditions. Our results suggest that the 260-µm microgel particles tested in this study are effective to attack the excessive-water-production problem and improve the oil recovery when the channel has a high permeability (>50 darcies). The gels are unlikely to be effective for channels that are less than 30 darcies because of the penetration/transport difficulties. After the gels effectively penetrate and shut off the superpermeable channel, the subsequent polymer solution is diverted to the matrices (i.e., the unswept oil zones) to displace the bypassed oil. Overall, this study provides important insights to help achieve successful polymer-flooding applications in reservoirs with superpermeable channels.

Profile control performance and field application of preformed particle gel in low-permeability fractured reservoir

Water well profile control is the main way to control water channeling in low-permeability fractured reservoirs, and preformed particle gels (PPGs) are commonly used. A preformed particle gel was prepared and the synthesis conditions were optimized. The temperature and salt resistant performance, plugging performance were investigated and the field application was tested. The results showed PPGs exhibited good temperature and salt resistant performance. PPGs with larger particle size showed greater plugging strength but shorter valid period. Field tests suggested that multiple rounds of profile control should be employed using PPGs with different particle sizes to achieve deep profile control.