Transformation of Silver Nanoparticles (AgNPs) during Lime Treatment of Wastewater Sludge and Their Impact on Soil Bacteria

This study investigated the impact of lime stabilization on the fate and transformation of AgNPs. It also evaluated the changes in the population and diversity of the five most relevant bacterial phyla in soil after applying lime-stabilized sludge containing AgNPs. The study was performed by spiking an environmentally relevant concentration of AgNPs (2 mg AgNPs/g TS) in sludge, applying lime stabilization to increase pH to above 12 for two hours, and applying lime-treated sludge to soil samples. Transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS) were used to investigate the morphological and compositional changes of AgNPs during lime stabilization. After the application of lime stabilized sludge to the soil, soil samples were periodically analyzed for total genomic DNA and changes in bacterial phyla diversity using quantitative polymerase chain reaction (qPCR). The results showed that lime treatment effectively removed AgNPs from the aqueous phase, and AgNPs were deposited on the lime molecules. The results revealed that AgNPs did not significantly impact the presence and diversity of the assessed phyla in the soil. However, lime stabilized sludge with AgNPs affected the abundance of each phylum over time. No significant effects on the soil total organic carbon (TOC), heterotrophic plate count (HPC), and percentage of the live cells were observed.

The Effects of Geocell Height and Lime Stabilization on Unpaved Road Settlements at Different Water Contents

In this study, lime stabilization and geocell reinforcement methods were investigated for a clayey subgrade of unpaved road at different water contents. This study is especially important in terms of determining the soil improvement method for road construction on wet lands. The effects of the geocell height (50, 100, 150, and 200 mm) and lime content (3, 6, and 12%) on the settlement of the subgrade soil at different water contents (25, 28, 30, 32, and 35%) were analyzed. Accordingly, a large scale plate loading test was designed, and it is utilized to achieve loading-settlement curves. The bearing capacity and modulus of subgrade (k) of soil were determined. It was detected that the geocell height and lime content have different effects at different water contents, and the modulus of subgrade reaction became stable beyond a constant height of the geocell. It was understood that none of these two improvements did not meet the Highways Technical Specifications. It is detected that at least these two improvement techniques are needed to be applied together to meet the specifications for the soil examined in this study.

Evaluating the Durability of Lime-Stabilized Soil Mixtures using Soil Mineralogy and Computational Geochemistry

Lime stabilization is a common technique used to improve the engineering properties of clayey soils. The process of lime stabilization can be split into two parts. First, the mobilization and crowding of [Formula: see text] ions or [Formula: see text]molecules from hydrated lime at net negative surface charge sites on expansive clay colloids. Second, the formation of pozzolanic products including calcium-silicate-hydrate (C-S-H) because of reactions within lime-soil mixtures. The pozzolanic reaction is generally considered to be more durable, while the [Formula: see text] adsorption has been associated with more easily reversible consistency changes. This study offers a protocol to assess whether the stabilization process is dominated by durable C-S-H (pozzolanic) reactions or a combination of cation exchange and pozzolanic reactions. Expansive clays with plasticity indices >45% from a major highway project in Texas are the focus of lime treatment in this study. The protocol consists of subjecting lime-soil mixtures to a reasonable curing period followed by a rigorous but realistic durability test and investigating the quality and quantity of the pozzolanic reaction product. Mineralogical analyses using quantitative X-ray diffraction (XRD) and thermogravimetric analysis (TGA) indicates the formation of different forms of C-S-H. In addition, geochemical modeling is used to simulate the lime-soil reactions and evaluate the effect of pH on the stability of C-S-H. The results indicate C-S-H with Ca/Si ratio of 0.66 as most the stable form of C-S-H among other forms with Ca/Si ratio ranging from 0.66 to 2.25. The effect of reducing equilibrium pH on C-S-H is also evaluated. A reduction in pH favored dissolution of all forms of C-S-H indicating the need to maintain a pH ≥ 10.

Utilization of Phosphoric Acid and Lime for Stabilizing Laterite for Lateritic Bricks Production

This study investigates the use of phosphoric acid (H3PO4) and lime in stabilizing lateritic soil for lateritic bricks production. Varying percentages (0, 2, 4 and 6%) of 1 M H3PO4, 5% lime and their combinations were mixed with lateritic soil for stabilization purpose. Hollow bricks were produced from the different mixes. The bricks were cured for 7, 14 and 28 days under ambient air condition. The compressive strength (fc), bulk density (pb), dry density (pd) and water absorption rate were determined at each of the curing days while the modulus of rupture (fr) and pH were determined after 28 days. The results show a maximum fc of 0.93 N/mm2 and 0.87 N/mm2 were obtained at 5% and 4% H3PO4 stabilization. The maximum pb and pd of 15.2 kN/m3 and 14.9 kN/m3 respectively were obtained at 4% H3PO4 stabilization. The maximum fr of 0.2 N/mm2 was obtained at combined 4% H3PO4 and 5% lime stabilization while none of the bricks passed the water absorption test.