Structure of a seeded palladium nanoparticle and its dynamics during the hydride phase transformation

Palladium absorbs large volumetric quantities of hydrogen at room temperature and ambient pressure, making the palladium hydride system a promising candidate for hydrogen storage. Here, we use Bragg coherent diffraction imaging to map the strain associated with defects in three dimensions before and during the hydride phase transformation of an individual octahedral palladium nanoparticle, synthesized using a seed-mediated approach. The displacement distribution imaging unveils the location of the seed nanoparticle in the final nanocrystal. By comparing our experimental results with a finite-element model, we verify that the seed nanoparticle causes a characteristic displacement distribution of the larger nanocrystal. During the hydrogen exposure, the hydride phase is predominantly formed on one tip of the octahedra, where there is a high number of lower coordinated Pd atoms. Our experimental and theoretical results provide an unambiguous method for future structure optimization of seed-mediated nanoparticle growth and in the design of palladium-based hydrogen storage systems.

DETERMINING LIMIT DISPLACEMENTS IN SPACER PROPPING SINGLE BOLTING

Using the existing engineering methodology of designing bolt joints taking up shear loads of dimension chains with gap elements according to N. N. Streletski and other authors’ methodology give similar results, both for the analysis of single bolt joints accuracy and for that of multi-bolt joints. In this article there is considered the affect of gap elements number on the accuracy of multi-bolt joints. There is established the character of the intrinsic errors distribution functions interaction, particularly, limit displacements occurring when mounting single bolt joints, and errors distribution functions determining the accuracy of multi-bolt joints elements mutual orientation. There are considered theoretical schemes of forming setting errors for basic elements in the plane of formed joints for a more complicated case, when shearing forces cause element displacements not obligatory reaching limit values. An analysis of the revealed theoretical schemes for the formation of displacements of the installed elements in the plane of the formed bolted joints shows that the parameters of the displacement distribution are significantly different from the same parameters obtained when calculating dimensional chains with gap units.

Investigation of Beam Features of Unidirectional Rayleigh Waves Electromagnetic Acoustic Transducers (EMATs) by a Wholly Analytical Solution

Electromagnetic acoustic transducers (EMATs) are widely used in industries due to its non-contact nature. This paper investigates the beam features of unidirectional Rayleigh waves EMATs, especially the effect of the wire length on beam directivity. A wholly analytical model is developed to calculate the Lorentz force distribution and ultrasound displacement distribution. The modelling results indicate that, compared to the coil consists of shorter wires, the coil consists of longer wires results in a narrower bandwidth of main lobe of unidirectional Rayleigh waves, which means the ultrasound are more concentrated. This study can be used for unidirectional Rayleigh waves EMATs design and optimization.

Structure of a single palladium nanoparticle and its dynamics during the hydride phase transformation

Palladium absorbs large volumetric quantities of hydrogen at room temperature and ambient pressure, making the Pd-H system a promising candidate for hydrogen storage. Here, we use Bragg coherent diffraction imaging to map the strain associated with defects in three dimensions before and during the hydride phase transformation of an individual octahedral palladium nanoparticle, synthesized by using the seed-mediated approach. The displacement distribution imaging unveils the location of the seed nanoparticle in the final nanocrystal. By comparing our experimental results with a finite-element model, we verify that the seed nanoparticle causes a characteristic displacement distribution of the larger nanocrystal. During the hydrogen exposure, the hydride phase is predominantly formed on one tip of the octahedra, where there is a high number of lower coordinated Pd atoms. Our experimental and theoretical results provide an unambiguous method for future structure optimization of seed-mediated nanoparticles growth and in the design of palladium-based hydrogen storage systems.

Finite element simulation on the relationship between pressure and displacement for the waist of elastic pantyhose

PurposeObjective appraisal of pressure comfort is the key point of optimal designing of clothing. The purpose of this paper is to study a new method to provide pressure comfort for the waist of elastic pantyhose through the relationship between pressure and displacement using the finite element method (FEM).Design/methodology/approachThis paper presented a simulation model of the waist cross section consisting of three parts, namely skin, soft tissue and lumbar vertebrae, respectively, according to CT scan. The finite element the model of waist cross-section was established using Mimics software. The pressure–displacement quadratic equation can be obtained using ANSYS software and fitting curves. Meanwhile, we divide the waist cross-section into 12 equal regions according to angle, and then the area shrinkage mass of the waist cross-section can be calculated, respectively.FindingsIn this research work, we got the displacement distribution trend of elastic pantyhose at the waist cross section according to the area shrinkage mass of 12 regions, and this displacement could be used as an objective evaluation index for pressure comfort. All these solutions supply a theoretical reference for optimal design of the women's elastic pantyhose.Originality/valueThe paper analyzed the relationship between pressure and displacement for the waist of elastic pantyhose using FEM, and then got the displacement distribution trend of elastic pantyhose at the waist cross section according to the area shrinkage mass of different regions. It can supply a new method to appraise pressure comfort.