Heavy Metals, Proximate Analysis and Brine Shrimp Lethality of Vernonia amygdalina and Ocimum gratissimum Growing in Crude Oil-Rich Delta State, Nigeria

Vernonia amygdalina (VA) and Ocimum gratissimum (OG) are among the most frequently consumed vegetables in Kokori and Abraka communities of Delta State, Nigeria. However, the continuous crude oil exploration and spillages in Kokori may threaten their safety for use as food and medicine. Twelve samples of VA and OG obtained from crude oil-rich and crude oil-free communities were comparatively analysed for proximate composition, heavy metals, and cytotoxicity. Data obtained were subjected to various multivariate statistical techniques, including principal component analysis (PCA), biplot, and analysis of variance (ANOVA), to investigate the correlations between the vegetables from the different communities and the effect of crude oil exploration and spill on plant biomass. Results obtained indicate a significant difference (p < 0.05) in the proximate composition of VA and OG and higher heavy metal content for VA from the crude oil-spill Kokori. Two VA collections from Kokori were exceptionally toxic to cellular crustaceans.

A Critical Evaluation of South Sudan’s Policy Framework for Health and Safety Management in the Oil and Gas Industry in Paloich- Melut County: A Case Study of Dar Petroleum Operating Company

The paper conducted a critical evaluation of South Sudan’s policy framework for health and safety management in the oil and gas industry in Paloich- Melut County with interests in Dar Petroleum Operating Company. Specifically, the study assessed the effect of government policy, the organizational practices that affects the health and safety management of community and to explore the challenges affecting the implementation of policy frameworks for health and safety management practices by Dar Petroleum Operating Company. Descriptive survey research design was used to collect quantitative and qualitative data thus following mixed method approach. Quantitative data was collected using questionnaires while Qualitative data was obtained from in-depth interviews. Quantitative data was analyzed using descriptive and inferential statistics. Qualitative data was analyzed using thematic analysis. The results revealed that government policy and organizational practices are positively and significantly related to health and safety management practices among oil exploration companies. However, organizational challenges and health and safety management practices among oil exploration companies is negatively and significantly related. The main challenges were lack of resources, poor leadership and corruption. The study concluded that an increase in adoption of Government Policy and organizational practices led to a significant increase on safety management practices among oil exploration companies. The study recommended that the oil and gas exploring companies strengthen the capacities of all concerned to achieve the sound management intellectual capital, exploration and production waste minimization, sound management of oil fields and hazardous wastes at all levels. Keywords: Health and Safety Management Practices, Government Policy, Company Policy, Organizational Practices & South Sudan

Geochemical, Mineralogical, and Lithofacies Characterizations of Lacustrine Shale: A Case Study From the Cangdong Sag, Bohai Bay Basin, China

The study of lithofacies identification and its distribution characterizations of shales is essential for the geological evaluation of shale oil exploration and development. In this study, core description, optical microscope, total organic carbon (TOC) content, whole-rock X-ray diffraction (XRD), Rock-Eval pyrolysis, X-ray fluorescence (XRF), scanning electron microscope (SEM), and well logging data were used in the qualitative analyses of the geochemical and mineralogical characteristics of shales. Since the work of detailed lithofacies identification is still lacking in the previous studies, based on TOC, sedimentary structure, and ternary diagram of siliceous minerals, carbonate minerals, and clay minerals, eight predominant lithofacies were identified in the shale of the second member of the Kongdian Formation (Ek2): ① low to moderate organic matter content (referred to as “low to moderate TOC”) massive calcareous mudstone (C-1); ② low to moderate TOC laminated calcareous mudstone (C-2); ③ low to moderate TOC layered mixed calcareous mudstone (C-3); ④ moderate to high organic matter content (referred to as “moderate to high TOC”) laminated calcareous siliceous mudstone (S-1); ⑤ moderate to high TOC massive mixed siliceous mudstone (S-2); ⑥ moderate to high TOC laminated clayey siliceous mudstone (S-3); ⑦ low to moderate TOC massive mixed mudstone (M-1); ⑧ moderate to high TOC layered calcareous/siliceous mixed mudstone (M-2). The favorability of lithofacies was investigated based on TOC, pyrolysis parameters, pore structures, and specific mineral contents. S-1 was currently considered as the most favorable lithofacies with excellent hydrocarbon potential, high amount of free hydrocarbon, and abundant organic pores; S-2, S-3, and M-2 were considered as favorable lithofacies, while C-1 and M-1 were ranked as the least-promising lithofacies in the research area. The lateral distribution of the shale is quite different, and Ek23 contains the most favorable lithofacies for shale oil exploration.

Effect of Soil Contamination with Crude Petroleum on Cowpea: An Insight into the Prospects of Crop Production in Nigerian Frontier Basins

Petroleum hydrocarbon contamination remains a major challenge confronting soil health, environmental sustainability, and food security in oil exploration areas. In this study, the effect of Bonny Light crude oil on cowpea (Vigna unguiculata L. Walp.) was investigated with a view to assessing its toxicity to plant growth and performance. Pristine soil samples were collected in different pots and contaminated with crude oil to achieve 0.0%, 2.5%, 5.0%, 7.5% and 10.0% v/w contamination levels. Viable seeds of cowpea were planted and monitored for the emergence and subsequent growth for a period of 12 weeks. Results showed that the crude oil extended the period of seed germination and delayed the emergence of sprouts by 2 days at a rate of 96.7%, 80.0%, 50.0%, 96.7%, and 73.3% emergence respectively. The plants’ shoots, roots, and leaves lengths were longer in control than in the contaminated soil. Phytotoxicity study showed that shoots, roots and leaves lengths of the plants were significantly reduced by ≥ 50% of the control. The relative plants' weights, chlorophyll, and the number of leaves were worst affected especially in plants grown in higher crude oil concentrations where fewer or absence of leaves was observed at the end of the experiments. No yield parameter was observed in all plants grown in contaminated soil as opposed to the control where flowers, fruits, and seeds were produced. The findings illustrated that the growth rate of V. unguiculata was severely affected due to hydrocarbon contamination in a concentration-dependent manner. It further demonstrated the imminent danger to food security especially in frontier basins with impending oil exploration activities. Therefore, there is a need to identify and integrate effective measures that minimize or prevent oil spillage in the course of oil exploration activities with a view to avoiding the repeat of persistent pollution problems disturbing host communities.