scholarly journals Geochemical, Mineralogical, and Lithofacies Characterizations of Lacustrine Shale: A Case Study From the Cangdong Sag, Bohai Bay Basin, China

2021 ◽  
Vol 9 ◽  
Author(s):  
Xianzheng Zhao ◽  
Xiugang Pu ◽  
Lihong Zhou ◽  
Wenzhong Han ◽  
Bixiao Xin ◽  
...  

The study of lithofacies identification and its distribution characterizations of shales is essential for the geological evaluation of shale oil exploration and development. In this study, core description, optical microscope, total organic carbon (TOC) content, whole-rock X-ray diffraction (XRD), Rock-Eval pyrolysis, X-ray fluorescence (XRF), scanning electron microscope (SEM), and well logging data were used in the qualitative analyses of the geochemical and mineralogical characteristics of shales. Since the work of detailed lithofacies identification is still lacking in the previous studies, based on TOC, sedimentary structure, and ternary diagram of siliceous minerals, carbonate minerals, and clay minerals, eight predominant lithofacies were identified in the shale of the second member of the Kongdian Formation (Ek2): ① low to moderate organic matter content (referred to as “low to moderate TOC”) massive calcareous mudstone (C-1); ② low to moderate TOC laminated calcareous mudstone (C-2); ③ low to moderate TOC layered mixed calcareous mudstone (C-3); ④ moderate to high organic matter content (referred to as “moderate to high TOC”) laminated calcareous siliceous mudstone (S-1); ⑤ moderate to high TOC massive mixed siliceous mudstone (S-2); ⑥ moderate to high TOC laminated clayey siliceous mudstone (S-3); ⑦ low to moderate TOC massive mixed mudstone (M-1); ⑧ moderate to high TOC layered calcareous/siliceous mixed mudstone (M-2). The favorability of lithofacies was investigated based on TOC, pyrolysis parameters, pore structures, and specific mineral contents. S-1 was currently considered as the most favorable lithofacies with excellent hydrocarbon potential, high amount of free hydrocarbon, and abundant organic pores; S-2, S-3, and M-2 were considered as favorable lithofacies, while C-1 and M-1 were ranked as the least-promising lithofacies in the research area. The lateral distribution of the shale is quite different, and Ek23 contains the most favorable lithofacies for shale oil exploration.

2016 ◽  
Vol 95 (3) ◽  
pp. 269-281 ◽  
Author(s):  
M. Koenen ◽  
J. Griffioen

AbstractSamples from Rupel Clay across the Netherlands were analysed for the assessment of its heterogeneity in geochemistry and mineralogy. X-ray fluorescence (XRF) and bulk and clay fraction X-ray diffraction (XRD) analyses of 152 samples from 17 different cores are presented and statistically interpreted. The results show a wide variation in the quartz, feldspar, clay mineral and carbonate content between the different samples. Factor analysis showed that the main variance between the samples can be explained by the clay mineral and quartz concentration, the carbonate content and pyrite plus organic matter. In the south of the Netherlands, the Rupel Clay is more quartz-rich and coarse grained. In addition, the clay is heterogeneous, varying with location and depth, consistent with observations for Belgium Boom Clay. Towards the north, the Rupel Clay becomes more clay-rich, finer grained and more homogeneous, both laterally and with depth. In addition, the clay has a relatively high carbonate and organic matter content. The pyrite content does not show any trends with location and depth. The differences between north and south are explained by the variations in depositional setting within the southern North Sea Basin.


2022 ◽  
Vol 28 ◽  
pp. e00461
Author(s):  
Alvaro José Gomes de Faria ◽  
Sérgio Henrique Godinho Silva ◽  
Renata Andrade ◽  
Marcelo Mancini ◽  
Leônidas Carrijo Azevedo Melo ◽  
...  

2016 ◽  
Vol 46 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Maria Regina de Miranda Souza ◽  
Paulo Roberto Gomes Pereira ◽  
Ivan de Paiva Barbosa Magalhães ◽  
Maria Aparecida Nogueira Sediyama ◽  
Sanzio Mollica Vidigal ◽  
...  

ABSTRACT Considering that nitrogen is directly related to leaf protein content, the nitrogen fertilization in Pereskia aculeata plants may affect the protein content and increase its nutritional potential. This study aimed at assessing the effect of nitrogen fertilization on mineral, protein and nitrate contents, as well as the yield of P. aculeata leaves. A randomized blocks design was used, with three replications and five treatments, consisting of increasing topdressing nitrogen doses (0-400 kg ha-1), in soil with organic matter content of 4.0 dag kg-1. Three harvests were performed for leaf analysis. No significant effect was observed for mineral and protein content or leaf fresh mass yield. The mean values for mineral composition were: 3.52 dag kg-1 of N, 0.47 dag kg-1 of P, 4.65 dag kg-1 of Ca, 0.71 dag kg-1 of Mg, 0.25 dag kg-1 of S, 36.64 mg kg-1 of Zn and 174.13 mg kg-1 of Fe. The mean content for protein was 21.86 % and the leaf fresh mass yield was 0.971 kg plant-1. K levels decreased from 50 kg ha-1 of N. Nitrate increased linearly with the nitrogen fertilization, reaching a maximum value of 78.2 mg kg-1 of fresh mass, well below the health risk threshold. It was concluded that a soil with high organic matter content does not require nitrogen fertilization. However, doses up to 400 kg ha-1 of nitrogen ensure adequate leaf yield and protein and mineral contents within the desired range for the species, being a food rich in proteins, iron and calcium.


2018 ◽  
Vol 36 (1) ◽  
pp. 174
Author(s):  
Π. Τσαουσίδου ◽  
Α. Τσαγκαλίδης ◽  
Ε. Γκάρτζος ◽  
Κ. Χαϊντούτη ◽  
Δ. Γασπαράτος ◽  
...  

The distribution of Fe, Al, Cu, Co, Cr, Ni, Zn was examined in two soil profiles of cultivated Alfisols developed from gabbro in the area of Chamilo in Kilkis. The main features of the studied soils were the accumulation of clay in the argilic horizons, the low pH and organic matter content, the absence of CaC03, and the high sand content, with differences in the drainage class and the degree of development. The optical microscope observations have demonstrated the presence of residual pyroxenes, altered plagioclases and muscovite. X-ray diffraction data of the clay fraction show the same clay minerals for the two soil profiles with the presence of kaolinite, illite, vermiculite and interstratified minerals of montmorillonite-vermiculite. The distribution of elements for both soil profiles depends primary from the pedogenetic processes. The illuvial translocation of clay in the argilic horizon seems to play an important role in the behavior of these elements in the studied soils. The significant correlations between the clay fraction, the Fe - Al oxides and the studied elements support the previous hypothesis. The use of ratio of elements concentration between the A and C horizons (index to assess the relative mobility of elements in the soil profile) which have values < 0.90 confirms the influence of the clay fraction at the distribution of elements. The low pH, the particle size distribution, and the drainage class of the soils influence also the dynamics of the studied elements in the soil profiles while the organic matter content seems to have no effect.


Author(s):  
O. A. Lipatnikova

The study of heavy metal speciation in bottom sediments of the Vyshnevolotsky water reservoir is presented in this paper. Sequential selective procedure was used to determine the heavy metal speciation in bottom sediments and thermodynamic calculation — to determine ones in interstitial water. It has been shown that Mn are mainly presented in exchangeable and carbonate forms; for Fe, Zn, Pb и Co the forms are related to iron and manganese hydroxides is played an important role; and Cu and Ni are mainly associated with organic matter. In interstitial waters the main forms of heavy metal speciation are free ions for Zn, Ni, Co and Cd, carbonate complexes for Pb, fulvate complexes for Cu. Effects of particle size and organic matter content in sediments on distribution of mobile and potentially mobile forms of toxic elements have been revealed.


Author(s):  
Amita M Watkar ◽  

Soil, itself means Soul of Infinite Life. Soil is the naturally occurring unconsolidated or loose covering on the earth’s surface. Physical properties depend upon the amount, size, shape, arrangement, and mineral composition of soil particles. It also depends on the organic matter content and pore spaces. Chemical properties depend on the Inorganic and organic matter present in the soil. Soils are the essential components of the environment and foundation resources for nearly all types of land use, besides being the most important component of sustainable agriculture. Therefore, assessment of soil quality and its direction of change with time is an ideal and primary indicator of sustainable agricultural land management. Soil quality indicators refer to measurable soil attributes that influence the capacity of a soil to function, within the limits imposed by the ecosystem, to preserve biological productivity and environmental quality and promote plant, animal and human health. The present study is to assess these soil attributes such as physical and chemical properties season-wise.


2020 ◽  
Vol 117 (3) ◽  
pp. 351-365
Author(s):  
J. Pijlman ◽  
G. Holshof ◽  
W. van den Berg ◽  
G. H. Ros ◽  
J. W. Erisman ◽  
...  

Agronomy ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1326
Author(s):  
Calvin F. Glaspie ◽  
Eric A. L. Jones ◽  
Donald Penner ◽  
John A. Pawlak ◽  
Wesley J. Everman

Greenhouse studies were conducted to evaluate the effects of soil organic matter content and soil pH on initial and residual weed control with flumioxazin by planting selected weed species in various lab-made and field soils. Initial control was determined by planting weed seeds into various lab-made and field soils treated with flumioxazin (71 g ha−1). Seeds of Echinochloa crus-galli (barnyard grass), Setaria faberi (giant foxtail), Amaranthus retroflexus (redroot pigweed), and Abutilon theophrasti (velvetleaf) were incorporated into the top 1.3 cm of each soil at a density of 100 seeds per pot, respectively. Emerged plants were counted and removed in both treated and non-treated pots two weeks after planting and each following week for six weeks. Flumioxazin control was evaluated by calculating percent emergence of weeds in treated soils compared to the emergence of weeds in non-treated soils. Clay content was not found to affect initial flumioxazin control of any tested weed species. Control of A. theophrasti, E. crus-galli, and S. faberi was reduced as soil organic matter content increased. The control of A. retroflexus was not affected by organic matter. Soil pH below 6 reduced flumioxazin control of A. theophrasti, and S. faberi but did not affect the control of A. retroflexus and E. crus-galli. Flumioxazin residual control was determined by planting selected weed species in various lab-made and field soils 0, 2, 4, 6, and 8 weeks after treatment. Eight weeks after treatment, flumioxazin gave 0% control of A. theophrasti and S. faberi in all soils tested. Control of A. retroflexus and Chenopodium album (common lambsquarters) was 100% for the duration of the experiment, except when soil organic matter content was greater than 3% or the soil pH 7. Eight weeks after treatment, 0% control was only observed for common A. retroflexus and C. album in organic soil (soil organic matter > 80%) or when soil pH was above 7. Control of A. theophrasti and S. faberi decreased as soil organic matter content and soil pH increased. Similar results were observed when comparing lab-made soils to field soils; however, differences in control were observed between lab-made organic matter soils and field organic matter soils. Results indicate that flumioxazin can provide control ranging from 75–100% for two to six weeks on common weed species.


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