Methodology for Testing High-Energy Materials Under Low Temperature Conditions

The methodology developed for testing gun propellants at low temperatures according to PN-EN ISO 604:2006 is presented in the paper. Brief characteristics are given of the materials tested and the most important static compression test conditions, such as specimen dimensions, deformation velocity and temperature range for selected propellants, i.e. JA-2 and SC. To verify the methodology developed, preliminary strength tests were performed at selected temperatures (25, 0, -25 and -50°C). Tests were carried out on specimens fabricated by shortening the propellant grain to the dimensions required by the reference standard. The results obtained confirmed the expected strength properties for both propellants (tensile strength and brittleness). Due to its chemical composition, the JA-2 propellant is a material of low brittleness even at -50°C. It does not crack completely and only its yield point increases. The results obtained for the JA-2 propellant were consistent with those published in reference literature. The SC propellant proved to be very brittle even at room temperature. At temperatures below 0°C, it fractures completely after reaching the desired deformation. The results obtained confirm that the adopted strength test conditions and the way the tests were prepared and performed enable acquisition of comparable and reliable results. It can be seen by analysing the results for the JA-2 propellant, which are consistent with the data in the available references. In contrast, the tests on the SC propellant proved the validity of strength tests on this type of material. Brittleness of propellant grains is a very undesirable phenomenon. A change in the combustion surface of low explosives caused by the process of propellant grain fracturing can adversely affect the magnitude and course of the pressure pulse, leading to failure of a cartridge chamber or gun barrel.

On Influence of Mechanical Properties of Gun Propellants on Their Ballistic Characteristics Determined in Closed Vessel Tests

The geometric burning law of gun propellants is widely used in computer codes used for the simulations of the internal ballistics of guns. However, the results of closed vessel tests prove that the burning process of some propellants deviates from the geometric law. Validation of the hypothesis that observed deviations can be attributed to the cracking of propellant grains was the aim of this work. In order to verify the hypothesis, three types of gun propellants were chosen with considerably differing mechanical strengths: a single-base propellant, a double-base propellant, and a composite propellant. The mechanical properties of the gun propellants were tested using a quasi-static compression method with strain rate values of the order of 0.001 s−1 and the Split Hopkinson Pressure Bar technique with the strain rate in the range of 1000–6000 s−1. The mechanical responses of the propellants were assessed on the basis of the true stress–strain curves obtained and from the point of view of the occurrence of cracks in the propellant grains specimens. Moreover, closed vessel tests were performed to determine experimental shape functions for the considered gun propellants. Juxtaposition of the stress‒strain curves with the experimental shape functions proved that the observed deviations from the geometrical burning law can be attributed mainly to the cracking of propellant grains. The results obtained showed that the rheological properties of propellants are important not only from the point of view of logistical issues but also for the properly controlled burning process of propellants during the shot.

Experimental Study of Pyrolysis and Laser Ignition of Low-Vulnerability Propellants Based on RDX

Low-vulnerability propellants are propellants designed to resist unintended stimuli to increase safety during transport, storage and handling. The substitution of usual nitrocellulose-based gun propellants with these new materials allows maintaining interior ballistics performances while increasing the safety. In this paper, the pyrolysis, ignition and combustion of such propellants are investigated in order to study conditions leading to a safe and reproducible ignition. Low-vulnerability propellants studied are made of different ratios of hexogen (RDX) and nitrocellulose (NC). Three compositions are studied by varying weight percentages of RDX and NC: 95-5, 90-10 and 85-15 for respective weight percentages of RDX-NC. Pyrolysis of these propellants is studied with two different experimental setups: a flash pyrolysis device linked to a gas chromatograph coupled to a mass spectrometer (Py-GC-MS) and a closed-volume reactor coupled to a mass spectrometer. Different molecules, like NO2, CO, CH3COCH3 or CH2NCH2NCH2, are obtained during the decomposition of these propellants. Laser ignition of these propellants is studied in a cylindrical closed-volume reactor using a laser diode. Several combustion characteristics, such as ignition delays, maximal overpressures and combustion rates are given for the three propellants using the pressure signals. Moreover, ignition energies are also investigated. Obtained results are compared to the few available literature data. A particular behavior is noticed for the 90-10 propellant. The experimental data collected should serve in the future to have a better understanding of the chemical reactions driving the combustion process of these low-vulnerability propellants.

Conventional and alternative nitrocellulose stabilisers used in gun propellants

The European Union industry must adapt to the requirements of the REACH regulations, which aim to improve human health and to protect the environment by using less toxic chemicals. The technology for producing nitrocellulose propellants utilises stabilisers that bond volatile products with autocatalytic properties of nitroester degradation. During this process, N-nitroso derivatives are formed, which exhibit toxic/carcinogenic properties. Moreover, some of the impurities found in stabilisers are characterised by toxic properties (e.g. in diphenylamine). In recent years, intensive research has been carried out on alternative nitrocellulose stabilisers with properties similar to or better than conventional stabilisers. The published studies on this subject mainly present research on chromatographic analysis, evaluation of stability using various methods and thermochemical analysis.