Explosion prevention and mitigation in plants which process, generate and store combustible dusts

Combustible dusts which are present in workplaces are a significant hazard which cannot be ignored by the plant owners, managers and workers. Combustible dust deflagrations and explosions have caused large numbers of deaths and catastrophic property damages in various industries, ranging from pharmaceutical plants to sugar factories. One may say that dust explosions in process industries always start inside process equipment such as mills, dryers, filters. Such events may occur in any process in which a combustible dust is handled, produced or stored, and can be triggered by any energy source, including static electricity, friction and hot surfaces. For any combustible dust type, several important parameters have to be taken into account when designing and using protective systems: i.e. the ease with which dust clouds ignite and their burning rates, maximum explosion pressure, maximum rate of explosion pressure rise. These parameters vary considerably depending on the dust type, their knowledge being a first step for carrying out a proper explosion risk assessment in installations which circulate combustible dusts. The paper presents the main aspects concerning explosion protection which have to be taken into account when designing protective systems intended to be used in explosive atmospheres generated by combustible dusts and the importance of selecting the proper explosion protection technique.

THERMAL AND EMISSION CHARACTERISTICS OF CARBONISED AND UNCARBONISED RICE HUSK BRIQUETTE, A COMPARATIVE APPROACH

Production of briquettes from carbonized and uncarbonized rice husk using a locally fabricated hydraulic press was studied. Proximate and Fourier Transform Infrared Spectroscopy (FTIR) analyses, thermal characteristics, and emission properties of the briquettes were determined. Thermal and emission characteristics were determined in real-time measurements during Water Boiling Test (WBT) using Laboratory Emissions Monitoring System (LEMS) equipment. The burning rates of the uncarbonized and carbonized briquettes were 14.35541g/min and 6.478456g/min respectively. The specific fuel consumptions of the briquettes were 96.5502g/L and 80.12107g/L for uncarbonized and carbonized respectively.The energy consumption rate of uncarbonized briquette was 203.4046KJ/min while that of carbonized was 157.6007KJ/min. It took uncarbonized sample average cooking power of 1.598235KW and 0.543518KW for thecarbonized briquette. High power particulate matter of uncarbonized briquette was 13.20391mg/MJ while that of carbonized was 0.510256mg/MJ. High power carbonmonoxide of uncarbonized and carbonized briquette were 0.443276g/MJ and -0.00964g/MJ respectively. Both briquettes were categorized as tier four in line with the International Workshop Agreement (IWA), International Organization for Standardization (ISO) standard specification for stove testing. Keywords: Briquette, Carbon Monoxide, Carbonization, Cassava Starch, Rice Husk

Thermal and mechanical characteristics of local firewood species and resulting charcoal produced by slow pyrolysis

The main source of fuel for domestic cooking applications in Sub-Saharan Africa is either locally available firewood species or charcoal produced by slow pyrolysis of these species. However, very few studies exist that characterize and quantify physical properties, burning rates, peak temperatures, and calorific values of typical firewood species and resulting charcoal fuels produced by slow pyrolysis. This study evaluated the mechanical and thermal properties of firewood and charcoal from five tree species namely: Dichrostachys cinerea, Morus Lactea, Piliostigma thonningii, Combretum molle, and Albizia grandibracteata. Characterization was done by scanning electron microscopy, thermogravimetric analysis, bomb calorimetry, Fourier transform infrared spectroscopy, bulk density measurements, and durability, water boiling and absorption tests. SEM images showed the development of macropores on charcoal after slow pyrolysis. Peak temperatures during firewood and charcoal combustion ranged between 515.5–621.8 °C and 741.6–785.9 °C, respectively. Maximum flame temperatures ranged between 786.9–870.8 °C for firewood and 634.4–737.3 °C for charcoal. Bulk densities and calorific values of charcoal species were higher than those for firewood species. Drop strengths for firewood were all 100% while for charcoal were between 93.7 and 100%. Water boiling tests indicated that firewood fuel performed better that charcoal fuel for low amounts of water due to higher maximum flame temperatures obtained during combustion of firewood.

Combustion Characteristics of Nanoaluminium-Based Composite Solid Propellants: An Overview

The nanosized powders have gained attention to produce materials exhibiting novel properties and for developing advanced technologies as well. Nanosized materials exhibit substantially favourable qualities such as improved catalytic activity, augmentation in reactivity, and reduction in melting temperature. Several researchers have pointed out the influence of ultrafine aluminium (∼100 nm) and nanoaluminium (<100 nm) on burning rates of the composite solid propellants comprising AP as the oxidizer. The inclusion of ultrafine aluminium augments the burning rate of the composite propellants by means of aluminium particle’s ignition through the leading edge flames (LEFs) anchoring above the interfaces of coarse AP/binder and the binder/fine AP matrix flames as well. The sandwiches containing 15% of nanoaluminium solid loading in the binder lamina exhibit the burning rate increment of about 20–30%. It was noticed that the burning rate increment with nanoaluminium is around 1.6–2 times with respect to the propellant compositions without aluminium for various pressure ranges and also for different micron-sized aluminium particles in the composition. The addition of nano-Al in the composite propellants washes out the plateaus in burning rate trends that are perceived from non-Al and microaluminized propellants; however, the burning rates of nanoaluminized propellants demonstrate low-pressure exponents at the higher pressure level. The contribution of catalysts towards the burning rate in the nanoaluminized propellants is reduced and is apparent only with nanosized catalysts. The near-surface nanoaluminium ignition and diffusion-limited nano-Al particle combustion contribute heat to the propellant-regressing surface that dominates the burning rate. Quench-collected nanoaluminized propellant residues display notable agglomeration, although a minor percentage of the agglomerates are in the 1–3 µm range; however, these are within 5 µm in size. Percentage of elongation and initial modulus of the propellant are decreased when the coarse AP particles are replaced by aluminium in the propellant composition.

An analysis of the WTC fires using CIB correlations and simple modeling

CIB correlations for compartment burning rates and average gas temperatures are examined for accuracy, utility, and generality. The results are applied to modeling the fire on 9/11 in WTC 1. Specific information is used from the NIST investigation. It is demonstrated that simple heat transfer modeling can predict the truss steel rod temperatures for the E119 tests of WTC done by NIST. The CIB temperature correlation and steel truss modeling are used to predict burning conditions for the WTC 1 96th floor fire and compared to the NIST results. Here a consideration of fuel loads from 20 to 40 kg/m2 was considered compared to just 20 used by NIST. The results suggest that the fully insulated truss bar temperatures would achieve higher values for higher fuel loads. A critical steel truss temperature of 650°C could support failure of the trusses as a theory for the collapse of the towers.