Comprehensive Evaluation for Protective Coatings: Optical, Electrical, Photoelectrochemical, and Spectroscopic Characterizations

Numerous efficient semiconductors suffer from instability in aqueous electrolytes. Strategies utilizing protective coatings have thus been developed to protect these photoabsorbers against corrosion while synergistically improving charge separation and reaction kinetics. Recently, various photoelectrochemical (PEC) protective coatings have been reported with suitable electronic properties to ensure low charge transport loss and reveal the fundamental photoabsorber efficiency. However, protocols for studying the critical figures of merit for protective coatings have yet to be established. For this reason, we propose four criteria for evaluating the performance of a protective coating for PEC water-splitting: stability, conductivity, optical transparency, and energetic matching. We then propose a flow chart that summarizes the recommended testing protocols for quantifying these four performance metrics. In particular, we lay out the stepwise testing protocols to evaluate the energetics matching at a semiconductor/coating/(catalyst)/liquid interface. Finally, we provide an outlook for the future benchmarking needs for coatings.

Phytoremediation of PAHs in Contaminated Soils: A Review

Polycyclic aromatic hydrocarbons (PAHs), which are also part of persistent organic pollutants (POPs), are considered to be especially toxic to humans (carcinogenic), likewise to plants, microorganisms and other living organisms. PAHs soil contamination occurs by storage leaking, transport loss, the land disposal of petroleum waste, and accidental or intentional spills. Due to their ubiquitous occurrence, recalcitrance, bioaccumulation potential and carcinogenic activity, PAHs are a significant environmental concern. The methods of controlling and repairing PAH-contaminated soils mainly include physical remediation, chemical remediation and phytoremediation. However, there was an increasing focus on phytoremediation technologies as a result of their unique advantages, including low cost, lack of secondary pollution and large-area application. Phytoremediation is therefore one of the soil remediation technologies with the greatest potential.

Simulating energetic particle losses in JET plasmas with a reverse integration biasing scheme

An integrated energetic particle transport model has been constructed in JET plasmas constrained by experimental fast ion loss measurements. The model incorporates a synthetic fast ion loss detector identical to JET's thin-foil Faraday cup fast ion loss detector array. The loss model combines analyses from the TRANSP and ORBIT-kick codes with enhanced features for producing the synthetic diagnostic. Extensions to the ORBIT code framework allow a full-orbit representation within the vacuum region that can map particles directly to an installed detector geometry. Since synthetic fast ion loss detectors are plagued by weak loss statistics, a novel reverse integration biasing scheme has been implemented to boost computational efficiency. The model is validated against experimental loss measurements induced by long-lived kink modes and is found to be in good agreement. This confirms the development of a fully integrated transport/loss model which can be quantitatively verified against experiment allowing for future validation and predictive studies. The model is particularly useful for more complicated plasma scenarios that involve multiple fast ion species such as JET's 2021 DT-campaign.

Analysis of AC Transport Loss in Conductor on Round Core Cables

The conductor on round core (CORC) cable wound with second-generation high-temperature superconducting (HTS) tapes is a promising cable candidate with superiority in current capacity and mechanical strength. The composing superconductors and the former are tightly assembled, resulting in a strong electro-magnetic interaction between them. Correspondingly, the AC loss is influenced by the cable structure. In this paper, a 3D finite-element model of the CORC cable is first built, and it includes the complex geometry, the angular dependence of critical current and the periodic settings. The modelling is verified by the measurements conducted for the transport loss of a two-layer CORC cable. Subsequently, the simulated results show that the primary transport loss shifts from the former to the superconductors as the current increases. Meanwhile, the loss exhibited in the outer layer is larger than that of the inner layer, which is caused by the shielding effect among layers and the former. This also leads to the current inhomogeneity in CORC cables. In contrast with the two-layer case, the simulated single-layer structure indicates stronger frequency dependence because the eddy current loss in the copper former is always dominant without the cancellation of the opposite-wound layers. The core eddy current of the single structure is denser on the outer surface. Finally, the AC transport losses among a straight HTS tape, a two-layer cable and a single-layer cable are compared. The two-layer structure is confirmed to minimise the loss, meaning an even-numbered arrangement makes better use of the cable space and superconducting materials. Having illustrated the electro-magnetic behaviour inside the CORC cable, this work is an essential reference for the structure design of CORC cables.

A Comparative Study of Using Polarization Curve Models in Proton Exchange Membrane Fuel Cell Degradation Analysis

In this paper, a systematic study is carried out to compare the performance of various V-I models at both normal and faulty conditions, in terms of simulating proton exchange membrane fuel cell (PEMFC) behavior and analyzing the corresponding degradation process. In the analysis, the simulation accuracy of V-I models, including overall behavior simulation and the simulation of different PEMFC losses, is investigated. Results show that compared to the other V-I models, the V-I model using exponential function for mass transport loss and considering open circuit voltage (OCV) at zero current can provide the best simulation performance, with an overall root mean square error (RMSE) of about 0.00279. Furthermore, the performance of these V-I models in analyzing PEMFC degradation process is also studied. By investigating the evolution of PEMFC losses during the degradation, the effectiveness of these models in interpreting PEMFC degradation mechanisms can be clarified. The results show that, besides the simulation accuracy, different interpretations may be provided from different models; this further confirms the necessity of comparative study. Moreover, the effectiveness of different V-I models in identifying PEMFC abnormal performance at two faulty scenarios is investigated. The results demonstrate that, among different V-I models, the model using an exponential function for mass transport loss and considering OCV at zero current can provide more accurate simulation and reasonable interpretation regarding PEMFC internal behavior.