Selective Flotation of Elemental Sulfur from Pressure Acid Leaching Residue of Zinc Sulfide

An efficient flotation process was developed to selectively recover elemental sulfur from a high-sulfur pressure acid leaching residue of zinc sulfide concentrate. The process mineralogy analysis showed that the sulfur content reached 46.21%, and 81.97% of the sulfur existed as elemental sulfur which was the major mineral in the residue and primarily existed as pellet aggregate and biconical euhedral crystal. An elemental sulfur concentrate product with 99.9% of recovery and 83.46% of purity was obtained using the flotation process of one-time blank rougher, two-time agent-added roughers, and two-time cleaners with Z-200 as collector and Na2S + ZnSO4 + Na2SO3 as depressant. The flotation experiment using return water indicated that the cycle use of return water had no adverse effect on the flotation performance of elemental sulfur. The process mineralogy analysis manifested that main minerals in the residue directionally went into the flotation products. Most of elemental sulfur entered the concentrate while other minerals almost completely went into the tailing. Main valuable elements lead, zinc, and silver entered the tailing with sulfides and could be recovered by lead smelting. The proposed process can realize the comprehensive recovery of valuable components in the high-sulfur residue and thus it has wide industrial application prospect.

Alkalinity of Irrigation Return Water Influences Nutrient Removal Efficacy of Floating Treatment Wetland Systems1

Water quality concerns often prevent reuse of captured irrigation return water for irrigation of specialty crops. Prior research indicated alkalinity of specialty crop operation irrigation varies from 0 to >500 mg.L−1 ( >0.06 oz.gal−1) CaCO3 across the United States. Floating treatment wetlands (FTWs) are an option for remediation of nutrients in irrigation return water, but effects of variable alkalinity on nutrient removal efficiency of FTWs are unknown. An experimental FTW system was developed to quantify the effect of alkalinity on the growth and nutrient uptake capacity of three plant species. ‘Rising Sun' Japanese iris (Iris ensata ‘Rising Sun’ Thunb.), upright sedge (Carex stricta Lam.);, and switchgrass (Panicum virgatum L.). were grown for 6 weeks at one of five alkalinity treatment levels, representing the alkalinity range of nursery and greenhouse irrigation runoff: 0, 100, 200, 300, and 400 mg.L−1 CaCO3 (0, 0.01, 0.02, 0.04, 0.05 oz.gal−1 CaCO3). Overall, Japanese iris demonstrated consistent remediation across each alkalinity treatment for both nutrient load reduction and plant accumulation. Species of iris warrant greater consideration and use in bioremediation systems. Both upright sedge and switchgrass could be used in systems with appropriate alkalinity levels. Future work should consider assessing novel plants at different points within their growth cycle, extended exposure durations, and decreased hydraulic retention time. Index words: Aquatic plant, nitrogen, phosphorus, sodium bicarbonate, nitrogen speciation. Species Used in this study: ‘Rising Sun' Japanese iris (Iris ensata ‘Rising Sun' Thunb.); upright sedge (tussock sedge) (Carex stricta Lam.); switchgrass (Panicum virgatum L.).

Description of biological wastewater treatment plants of city of Odesa as sources of marine environment nutrient pollution in current period

Biological wastewater treatment plants (the BTPs) of city of Odesa (Northern and Southern Plants) are the most powerful permanent sources of nutrient pollution of coastal waters of Odesa Region of the north-western part of the Black Sea (the NWPBS) and the Khadzhybei Liman. The article includes a comparative analysis of changes, taking place since the beginning of the 21st century, related to the qualitative composition of return water of the Northern and Southern BTPs and the amount of nutrients reaching the marine environment together with such water, as well as the analysis of possible influence of such changes on eutrophication of coastal waters of Odesa Region of the NWPBS and the Khadzhybei Liman. It was established that despite significant decrease (by 1.7 - 2 times) of return water discharged from the BTPs the amount of nitrates and nitrites reaching the marine environment together with such water increased by 4-6 times. At the same time the reduced inflow of organic matter, ammonium nitrogen and phosphates can be observed. Treatment facilities of Odesa were put into operation back in the 1970s. They use a then typical technology of biological cleaning of wastewater from nutrient compounds in aeration tanks providing aerobic conditions. The technology is considered as incomplete in terms of nitrogen compounds treatment since its final product includes nitrate nitrogen in large quantities. When reaching the marine environment it is absorbed by algae at the stage of primary production of organic matter and thus is transformed in organic nitrogen again. It was noted that since the coastal waters of Odesa Region of the NWPBS and the Khadzhybei Lyman have a high level of trophicity and currently there is a disbalance between mineral nitrogen and phosphorus concentrations in the water towards insufficiency of mineral nitrogen reserves (as compared with the standard Redfield stoichiometric ratio), additional inflow of nitrates and nitrites in the marine environment together with return water from the BTPs would, in certain circumstances, lead to algal bloom and aggravation of negative eutrophication-related consequences. The research allowed making a conclusion that a modern flow sheet of advanced biological cleaning (treatment) of wastewater from nitrogen compounds should be implemented at the Northern and Southern BTPs in order to reduce the inflow of nitrates in the marine environment. Such flow sheet should ensure both nitrification and denitrification processes.

Analysis of water-ecological problems of Khmelnytsk region

At the present stage, in the conditions of growing scale of anthropogenic impact on water resources, shortage of quality drinking water and climate change, priority measures should be their rational use and comprehensive conservation. The article analyzes the environmental problems of surface waters of river basins, analyzed the existing potential of water resources and the state of water use, qualitative and quantitative indicators of surface waters of river basins of the Dnieper, Southern Bug and Dniester within Khmelnytsky region. The main problems of water resources of the region are highlighted and proposals for their effective use are formulated. A feature of the Khmelnytsky region is its location in three river basins – the rivers Dniester, Southern Bug and Dnieper. The main share of water intake in the region comes from surface objects, and s unevenly distributed throughout its territory. The study shows that in the sectoral structure of general use of water in Khmelnytsky region, the largest consumer is industry (58.6 %), and among industries electricity sector is the main and largest consumer. The main environmental problem of the region is the pollution of surface water bodies with untreated and insufficiently treated return water. In the territory of Khmelnytsky region, 80 water users discharge return water into water bodies. The average annual concentrations of manganese (2–6 times), copper (4–7 times) and nitrites (2–5 times) were exceeded in all control samples from water bodies of Khmelnytsky region. There is also an increase in the total amount of discharges of pollutants, including petroleum products, suspended solids, sulfates, total iron, and copper. In addition to pollution, the problem is the current structure of land within river basins. Excessive plowing is one of the main negative factors that contributes to the deterioration of the water regime and leads to pollution of water bodies. Within the Khmelnytsky region, arable land is the dominant form of land use, their share is 50–70 %. Restoration of the quality of water bodies involves the implementation of measures to reduce the environmental risk of deterioration based on the analysis of the impact of anthropogenic factors and a set of water protection measures.