Genesis of the Weizigou Au Deposit, Heilongjiang Province, NE China: Constraints from LA-ICP-MS Trace Element Analysis of Magnetite, Pyrite and Pyrrhotite, Pyrite Re-Os Dating and S-Pb Isotopes

The Weizigou Au deposit in Heilongjiang Province, NE China, located in the southern Jiamusi Massif, shows similarities to IOCG deposits. To determine the mineralization age, sources of ore-forming materials and genetic type, pyrite Re-Os dating, S-Pb isotopic analysis, in situ sulfur analysis and LA-ICP-MS analysis of trace elements in magnetite, pyrite and pyrrhotite were conducted. Four pyrite samples yielded a Re-Os isochron age of 197 ± 11 Ma, implying the occurrence a metallogenic event in the Early Jurassic. The δ34S values of sulfides display a relatively narrow range from 4.70‰ to 12.83‰ (mainly 9.90‰ to 12.83‰), which may be accounted for the extensively exposed granitic gneiss and meta-gabbro, with δ34S values of 7.44‰ to 8.44‰ and 4.37‰ to 10.54‰, respectively. Sulfide lead isotopic compositions have 206Pb/204Pb = 18.605–20.136, 207Pb/204Pb = 15.637–15.710 and 208Pb/204Pb = 38.534–39.129, indicating that the lead was derived from a mixed source. Magnetite has the characteristics of a lower Ti content and higher Zn content, indicating that it should be of hydrothermal origin, which may be related to IOCG-type mineralization. Pyrite and pyrrhotite have a Co/Ni ratio greater than 1 and a lower As content, indicating that they are of magmatic hydrothermal origin. Integrating the above analysis results, we inferred that the Weizigou Au deposit experienced the IOCG-type mineralization in the Middle-Late Permian, associated with magmatic-hydrothermal mineralization in the Early Jurassic.

Geochemical characteristics of the Toplika manganese- and iron-bearing ore occurrence, central part of the Srednogorie Zone, Bulgaria: Preliminary results

The growing demand on mineral resources stimulated our interest on manganese- and iron-bearing occurrences as a potential source of Mn, Cu, Ni, Co, Mo, REY, etc. Here we focus on the mineralization of the Toplika ore occurrence, which is located in the central part of the Srednogorie Zone, Bulgaria. We present preliminary data on its field relationships, mineralogy and geochemistry and discuss the possible hydrothermal origin of the metalliferous sediments that should be further studies as source of critical elements.

Recovery of Hydrothermal Wustite-Magnetite Spherules from the Central Indian Ridge, Indian Ocean.

Not many studies have reported the hydrothermal-related origin of the magnetite-bearing spherules, and hardly any literature discusses the hydrothermal-related origin of wustite-magnetite-bearing spherules. A sediment sample with high abundance (19 spherules in ~85 g) of spherules is recovered from Central Indian Ridge (CIR) segment S2 (70°54′E, 25°14′S to 70°50′E, 24°41′S), ~85 km north of Rodrigues triple junction (RTJ). On the external surface of the spherules, magnetite appears as crystals, whereas wustite mostly appears as a homogenous glass phase. These spherules are composed of wustite and magnetite hosting Mn, unlike micrometeorites which essentially hosts Ni. Mn is more heterogeneously distributed with a relatively higher concentration in the wustite phase than the magnetite, suggesting hydrothermal origin. Furthermore, the presence of sulfide nano-particles in the wustite phase and a minor quantity of Pb and S in the ferrihydrite matrix points to the fact that CIR spherules are of hydrothermal origin. We propose that the CIR spherules originated by the interaction of the reduced hydrothermal fluids with the ultramafic/basaltic rocks or silica-undersaturated magmatic melts. The finding of Mn hosting wustite-magnetite assemblage suggests an active hydrothermal system in the near vicinity and can be considered as an additional proxy for locating hydrothermal vents.

Massive Southern Ocean phytoplankton bloom fed by iron of possible hydrothermal origin

Primary production in the Southern Ocean (SO) is limited by iron availability. Hydrothermal vents have been identified as a potentially important source of iron to SO surface waters. Here we identify a recurring phytoplankton bloom in the high-nutrient, low-chlorophyll waters of the Antarctic Circumpolar Current in the Pacific sector of the SO, that we argue is fed by iron of hydrothermal origin. In January 2014 the bloom covered an area of ~266,000 km2 with depth-integrated chlorophyll a > 300 mg m−2, primary production rates >1 g C m−2 d−1, and a mean CO2 flux of −0.38 g C m−2 d−1. The elevated iron supporting this bloom is likely of hydrothermal origin based on the recurrent position of the bloom relative to two active hydrothermal vent fields along the Australian Antarctic Ridge and the association of the elevated iron with a distinct water mass characteristic of a nonbuoyant hydrothermal vent plume.