Metal-supported SOFC Fabricated by Tape Casting and Its Characterization: A Study of the Co-sintering Process

Metal-supported SOFC consists of metallic and ceramic multilayers. Since the cell has to be flat, interaction between the layers that results in a flat sintered layer needs to be studied. The method used here was changing the starting materials through several experiments. Here, we highlight the effects of pore former in metal slurry on the sintered half-cell multilayer of a 430L metallic support, an NiO-8YSZ anode, and an 8YSZ electrolyte. The results show that by changing the amount of pore former in the 430L metal slurry changed the sinterability of the metal layer. This change of the sinterability of the metal support affected the final warpage state of the cell. This study aid in explaining the sintering phenomena between layers of metal-supported SOFCs.

Investigation of Electromechanical Properties on 3-D Printed Piezoelectric Composite Scaffold Structures

Piezoelectric composites with 3-3 connectivity gathered attraction due to their potential application as an acoustic transducer in medical imaging, non-destructive testing, etc. In this contribution, piezoelectric composites were fabricated with a material extrusion-based additive manufacturing process (MEX), also well-known under the names fused deposition modeling (FDM), fused filament fabrication (FFF) or fused deposition ceramics (FDC). Thermoplastic filaments were used to achieve open and offset printed piezoelectric scaffold structures. Both scaffold structures were printed, debinded and sintered successfully using commercial PZT and BaTiO3 powder. For the first time, it could be demonstrated, that using the MEX processing method, closed pore ferroelectric structure can be achieved without pore-former additive. After ceramic processing, the PZT scaffold structures were impregnated with epoxy resin to convert them into composites with 3-3 connectivity. A series of composites with varying ceramic content were achieved by changing the infill parameter during the 3D printing process systematically, and their electromechanical properties were investigated using the electromechanical aix PES device. Also, the Figure of merit (FOM) of these composites was calculated to assess the potential of this material as a candidate for transducer applications. A maximum for the FOM at 25 vol.% of PZT could be observed in this study.

Selecting a Method for the Manufacture of Porous Powder Filter Products

The article considers three methods of increasing the distribution uniformity of properties over the filtration area of powder filter materials at different stages of their manufacturing. It is shown that granulation of metal powders with a pore former increases the uniformity of permeability distribution over the filtration area by a factor of 2.3–3.5. Dry radial isostatic pressing ensures high distribution uniformity of properties, while the coefficient of variation of local permeability does not exceed 0.17. Radial compression allows increasing the uniformity of permeability distribution over the filtration area by 15 ... 22 % compared to that for the original powder filter materials. The selection of the method used in practice is determined by the shape, size and properties of the manufactured products and initial powders. The considered methods can be used in petrochemical engineering for the manufacture of porous powder products for filtering purposes, used to trap catalyst particles, filters for fine and coarse fuel and oil purification.

Tamisolve® NxG as an Alternative Non-Toxic Solvent for the Preparation of Porous Poly (Vinylidene Fluoride) Membranes

Tamisolve® NxG, a well-known non-toxic solvent, was used for poly(vinylidene fluoride) (PVDF) membranes preparation via a non-solvent-induced phase separation (NIPS) procedure with water as a coagulation bath. Preliminary investigations, related to the study of the physical/chemical properties of the solvent, the solubility parameters, the gel transition temperature and the viscosity of the polymer–solvent system, confirmed the power of the solvent to solubilize PVDF polymer for membranes preparation. The role of polyvinylpyrrolidone (PVP) and/or poly(ethylene glycol) (PEG), as pore former agents in the dope solution, was studied along with different polymer concentrations (10 wt%, 15 wt% and 18 wt%). The produced membranes were then characterized in terms of morphology, thickness, porosity, contact angle, atomic force microscopy (AFM) and infrared spectroscopy (ATR-FTIR). Pore size measurements, pore size distribution and water permeability (PWP) tests placed the developed membranes in the ultrafiltration (UF) and microfiltration (MF) range. Finally, PVDF membrane performances were investigated in terms of rejection (%) and permeability recovery ratio (PRR) using methylene blue (MB) in water solution to assess their potential application in separation and purification processes.

The Reuse of Industrial By-Products for the Synthesis of Innovative Porous Materials, with the Aim to Improve Urban Air Quality

This works concerns the characterization and the evaluation of adsorption capability of innovative porous materials synthesized by using alginates and different industrial by-products: silica fume and bottom ash. Hydrogen peroxide was used as pore former to generate a porosity able to trap particulate matter (PM). These new materials are compared with the reference recently proposed porous SUNSPACE hybrid material, which was obtained in a similar process, by using silica fume. Structural, morphological, colorimetric and porosimetric analyses were performed to evaluate the differences between the obtained SUNSPACE typologies. The sustainability of the proposed materials was evaluated in terms of the Embodied Energy and Carbon Footprint to quantify the benefits of industrial by-products reuse. Adsorption tests were also performed to compare the ability of samples to trap PM. For this aim, titania suspension, with particles size about 300 nm, was used to simulate PM in the nanoparticle range. The results show that the material realized with bottom ash has the best performance.

Modified Clay Filters for Purification of Petroleum Products Contaminated Water

Some organic pollutants change the color, smell, and other characteristics of water leaving it undesirable for use. However, other organic pollutants do not change the physical properties of the water, yet, they make the water non-useful. This study was carried out to determine the characteristics of petroleum contaminated water and how it can be purified using economical filters for possible reuse in rural areas of the Niger Delta, of Nigeria. The filters were made from rice husk ash, and white clay, as main materials, while calcium carbonate and poly (propylene carbonate) were used as binders and pore former. The water samples were tested for conductivity, turbidity, pH, heavy metals, and total hydrocarbon contents. The results showed a significant decrease in the amount of petroleum/organic pollutants present in the water sample before purification. The filter candle made using poly (propylene carbonate) as a binder was found to be the most efficient in removing organic pollutants, but it was not very effective in the removal of heavy metals and also, the pH of the filtrate became more acidic. Filtrates from other filters, however, had pH in an acceptable range. Dodecanoic acid and hexadecanoic acid were found to be removed from the polluted water using the filters.

Microstructure characterization and properties of porous piezoceramics

In this paper, a comprehensive study of microstructure/properties interrelations for porous piezoceramics based on PZT composition was performed. Experimental samples of porous piezoceramics were fabricated using a modified method of burning-out a pore former. Porosity dependencies of elastic, dielectric, piezoelectric and electromechanical coefficients of the porous ceramics in the relative porosity range 0–50% were obtained and analyzed. As a result of microstructure analysis, it was found that at any connectivity type (3–0, 3–3) and porosity up to 50% the real structures of porous piezoceramics were close to the matrix medium structure with continuous piezoceramic skeleton. It was also revealed that the microstructural features of porous piezoceramics define the character of the dependences of the dielectric, piezoelectric and electromechanical properties of porous piezoelectric ceramics on porosity. In conclusion, microstructure/properties interrelations, as well as new applications of porous piezoceramics were discussed.

Dispersion characteristics of complex electromechanical parameters of porous piezoceramics

In this paper, the results of experimental study of dispersion characteristics of complex electromechanical parameters of ferroelectrically “hard” porous piezoceramics based on PZT composition were presented. Experimental samples of porous piezoceramics were fabricated using a modified method of burning-out a pore former. The complex constants of porous piezoceramics with relative porosity 16% and their frequency dependences were measured using the piezoelectric resonance analysis method. As a result of experimental studies, regions of elastic, piezoelectric and electromechanical dispersion, characterized by anomalies in the frequency dependences of the imaginary and real parts of the complex constants of porous piezoelectric ceramics were found. It was revealed also that the microstructural features of porous piezoceramics determine the character of frequency dependences of complex electromechanical parameters of porous piezoelectric ceramics. In conclusion, the microstructural and physical mechanisms of electromechanical losses and dispersion in porous piezoceramics were discussed.