scholarly journals Study on denitration performance of multi element modified MIL-101 (Fe) at low temperature

2022 ◽  
Vol 355 ◽  
pp. 01023
Author(s):  
Shuqin Wang ◽  
Xiaoxue Li ◽  
Jinjin Wu

MIL-101 (Fe) was modified by amino group and doped by Cu and Co elements by microwave hydrothermal method. The effect of SCR denitrification at low temperature was investigated with high concentration of NOx as adsorption object. The results show that when the flue gas temperature is 200 °C and the NOx concentration is up to 1640 mg/m3, the removal efficiency of NOx can reach 86% under the optimal conditions, which is 1.5 times higher than that before modification. In addition, the characterization results indicated that the specific surface area of the modified catalyst increased, the thermal stability was good at low temperature, the selective adsorption capacity of NO was enhanced, and the doping played a synergistic catalytic role. It can be used for flue gas denitration in various industries.

2013 ◽  
Vol 448-453 ◽  
pp. 2777-2780 ◽  
Author(s):  
Yan Feng Liu ◽  
Shi Ping Li ◽  
Xiang Hong Li

A 215MW cogeneration B&W670/13.7-M type high-pressure natural circulation boilers, the exhaust gas temperature is set as 143 °C, while in the actual operation, the average exhaust gas temperature is 155 °C, and when the unit is running at full capacity in summer the highest exhaust gas temperature is 169.6 °C. In order to satisfy the normal operating temperature of bag filter in summer peak load, and recover low temperature waste heat of fule gas, low temperature economizer is added to the thermal system. Therefore, low-temperature economizers are respectively added in four flues which are between the outlet of the air preheater and the entrance of the bag filter, this will achieve the purpose of reducing flue gas temperature by transferring heat between condensate and flue gas, ensuring the units safe operating and improving the overall operating performance of the boiler.


2019 ◽  
Vol 4 (1) ◽  
pp. 21-29
Author(s):  
Natalia A. Gorbunova

The development of plasma technology is associated with the unique features of non-equilibrium low-temperature plasma: high electron energy and high concentration of chemically active excited and charged particles at low gas temperature, which allows to process thermolabile materials and biological objects in gentle conditions when high temperatures are not required. The biological effects of low-temperature plasma exposure are considered. It was established that during plasma treatment, a combined effect on cells and tissues of living systems from UV radiation, ions and chemically active particles occurs. Depending on the plasma type, the significance of each of the listed mechanisms for increasing the effectiveness of plasma treatment may vary. However, all these mechanisms interact with each other and have a synergistic effect. It was shown that the conducted studies confirm the ability of low-temperature plasma to inactivate pathogenic microorganisms upon contact with biological objects and foods. The results of the studies are presented, the purpose of which was to study the effect of plasma treatment on nitrite concentration in the water treated by this method and to assess the possibility of its use as a source of nitrite when curing meat products.


2013 ◽  
Vol 448-453 ◽  
pp. 3301-3305
Author(s):  
Zhen Yao Qu ◽  
Qiang Wang

Pulverizing system equipped by fan mills uses three medium (ie. low-temperature furnace smoke, high-temperature furnace smoke, hot air) for drying coal, especially in large-scale plants burning lignite. A constantly increasing unit capacity leads to a more complicated design for pulverizing system, with a heavier weight of furnace smoke tube. This paper focuses on a research of water-cooled membrane flue tube instead of traditional inner and outer insulation tube through experiments like changing water side parameters to replace the low-temperature flue pipe from three medium to two medium (ie. adjustable-temperature furnace smoke, hot air). This paper studies heat transfer coefficient of water-cooled furnace smoke pipe at different flow rate and flue gas temperature though a established water-cooled furnace smoke pipe test bed. It is using a certain mathematic method to obtain dimensionless relationship among Nu, Re, Pr and obtain the dimensionless rule equation of water-cooled furnace smoke tube.


2021 ◽  
Vol 271 ◽  
pp. 01022
Author(s):  
Qiudong Hu

At present, the exhaust gas temperature of coal-fired power plants is 125-150℃, and the emission of high-temperature flue gas causes the loss of excess heat and wastes. For this kind of phenomenon, the waste heat recovery system is researched and designed, combined with the combination of a low-temperature economizer in a coal-fired power plant in Dezhou. The heater, through the low-temperature economizer combined with the heater system, reduces coal consumption for power generation, reduces flue gas emissions, while reducing dust specific resistance, improving dust removal efficiency of electric dust removal, and reducing dust emissions. This project responds to national policy guidelines.


Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2174
Author(s):  
Marta Marczak-Grzesik ◽  
Stanisław Budzyń ◽  
Barbara Tora ◽  
Szymon Szufa ◽  
Krzysztof Kogut ◽  
...  

The research presented by the authors in this paper focused on understanding the behavior of mercury during coal combustion and flue gas purification operations. The goal was to determine the flue gas temperature on the mercury emissions limits for the combustion of lignites in the energy sector. The authors examined the process of sorption of mercury from flue gases using fine-grained organic materials. The main objectives of this study were to recommend a low-cost organic adsorbent such as coke dust (CD), corn straw char (CS-400), brominated corn straw char (CS-400-Br), rubber char (RC-600) or granulated rubber char (GRC-600) to efficiently substitute expensive dust-sized activated carbon. The study covered combustion of lignite from a Polish field. The experiment was conducted at temperatures reflecting conditions inside a flue gas purification installation. One of the tested sorbents—tire-derived rubber char that was obtained by pyrolysis—exhibited good potential for Hg0 into Hg2+ oxidation, resulting in enhanced mercury removal from the flue. The char characterization increased elevated bromine content (mercury oxidizing agent) in comparison to the other selected adsorbents. This paper presents the results of laboratory tests of mercury sorption from the flue gases at temperatures of 95, 125, 155 and 185 °C. The average mercury content in Polish lignite was 465 μg·kg−1. The concentration of mercury in flue gases emitted into the atmosphere was 17.8 µg·m−3. The study analyzed five low-cost sorbents with the average achieved efficiency of mercury removal from 18.3% to 96.1% for lignite combustion depending on the flue gas temperature.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1738
Author(s):  
Saeid Vafaei ◽  
Alexander Wolosz ◽  
Catlin Ethridge ◽  
Udo Schnupf ◽  
Nagisa Hattori ◽  
...  

SnO2 nanoparticles are regarded as attractive, functional materials because of their versatile applications. SnO2 nanoaggregates with single-nanometer-scale lumpy surfaces provide opportunities to enhance hetero-material interfacial areas, leading to the performance improvement of materials and devices. For the first time, we demonstrate that SnO2 nanoaggregates with oxygen vacancies can be produced by a simple, low-temperature sol-gel approach combined with freeze-drying. We characterize the initiation of the low-temperature crystal growth of the obtained SnO2 nanoaggregates using high-resolution transmission electron microscopy (HRTEM). The results indicate that Sn (II) hydroxide precursors are converted into submicrometer-scale nanoaggregates consisting of uniform SnO2 spherical nanocrystals (2~5 nm in size). As the sol-gel reaction time increases, further crystallization is observed through the neighboring particles in a confined part of the aggregates, while the specific surface areas of the SnO2 samples increase concomitantly. In addition, X-ray photoelectron spectroscopy (XPS) measurements suggest that Sn (II) ions exist in the SnO2 samples when the reactions are stopped after a short time or when a relatively high concentration of Sn (II) is involved in the corresponding sol-gel reactions. Understanding this low-temperature growth of 3D SnO2 will provide new avenues for developing and producing high-performance, photofunctional nanomaterials via a cost-effective and scalable method.


2021 ◽  
Vol 13 (8) ◽  
pp. 4591
Author(s):  
Shuanglei Huang ◽  
Daishe Wu

The tremendous input of ammonium and rare earth element (REE) ions released by the enormous consumption of (NH4)2SO4 in in situ leaching for ion-adsorption RE mining caused serious ground and surface water contamination. Anaerobic ammonium oxidation (anammox) was a sustainable in situ technology that can reduce this nitrogen pollution. In this research, in situ, semi in situ, and ex situ method of inoculation that included low-concentration (0.02 mg·L−1) and high-concentration (0.10 mg·L−1) lanthanum (La)(III) were adopted to explore effective start-up strategies for starting up anammox reactors seeded with activated sludge and anammox sludge. The reactors were refrigerated for 30 days at 4 °C to investigate the effects of La(III) during a period of low-temperature. The results showed that the in situ and semi in situ enrichment strategies with the addition of La(III) at a low-concentration La(III) addition (0.02 mg·L−1) reduced the length of time required to reactivate the sludge until it reached a state of stable anammox activity and high nitrogen removal efficiency by 60–71 days. The addition of La(III) promoted the formation of sludge floc with a compact structure that enabled it to resist the adverse effects of low temperature and so to maintain a high abundance of AnAOB and microbacterial community diversity of sludge during refrigeration period. The addition of La(III) at a high concentration caused the cellular percentage of AnAOB to decrease from 54.60 ± 6.19% to 17.35 ± 6.69% during the enrichment and reduced nitrogen removal efficiency to an unrecoverable level to post-refrigeration.


2012 ◽  
Vol 455-456 ◽  
pp. 284-288
Author(s):  
Wei Li Gu ◽  
Jian Xiang Liu

this paper studies the typical irreversible processes such as combustion and heat transfer with temperature difference based on the theory of thermodynamics, analyzes the influencing factors on exergy loss in irreversible processes, on the basis of this analysis, proposes the energy-saving optimization measures on design and operation management of the organic heat transfer material heater, and specially points out that in the design process, objective function can be constructed with the exergy loss as evaluation index to determine the outlet flue gas temperature of furnace and the flue gas temperature, and provides theoretical basis for the determination of design parameters.


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