Numerical Analysis of Solidification Behavior during Laser Welding Nickel-based Single-crystal Superalloy Part III: Auspicious Control of Dendrite Tip Undercooling

Location-dependent dendrite tip undercooling is numerically elucidated to predict crystallography-assisted resistance to centerline grain boundary formation and morphology transition of stray grain formation ahead of dendrite tip in the ternary Nickel-Chromium-Aluminum molten pool during course of nonequilibrium solidification for explanation arduous solidification behavior control of microstructure melioration. Heat input is not so salient as welding configuration for auspicious solidification behavior and beneficial microstructure development. Advantageous symmetry of welding configuration efficiently lessens dendrite tip undercooling for prevalent dendrite morphology stability of planar interface with alleviation of columnar/equiaxed transition (CET) phenomenon. The bimodal distribution of undercooling ahead of dendrite tip is symmetrically dominant for (001)/[100] growth crystallography with capability of increasing morphology of interface kinetics for epitaxial growth and guarantees single-crystal potential. Alternatively, the distribution of undercooling ahead of dendrite tip is asymmetrically prevalent for (001)/[110] growth crystallography with inefficiency of nonhomologous solidification behavior for discontinuous intersection of solidification interface. Undercooling ahead of dendrite tip inside [010] growth region is not so wide as inside [100] growth region, where thermometallurgically initiates unstable solidification interface and inferior solidification behavior, with unfavorable crystallography in the case of asymmetrical (001)/[110] welding configuration. The smaller heat input is applied, the narrower undercooling ahead of dendrite tip is acquired to significantly mitigate microstructure anomalies with favorable solidification conditions, meliorate metallurgical properties and potentially improve weldability with viability of epitaxial columnar morphology and vice versa. Optimum heat input, especially low laser power and high welding speed together, is a viable and robust way to limit plethora of undercooling and easily decrease solidification behavior anomalies. When low laser power or rapid welding speed is chosen, low heat input not only lessens [100] dendrite growth region, where is spontaneously vulnerable to columnar/equiaxed transition, as ramification of prominent dendrite tip undercooling, but also metallurgically ameliorates [001] dendrite growth region, where morphologically aids epitaxial growth and activates stable planar interface, with achievable diminution of dendrite tip undercooling. Symmetrical (001)/[100] welding configuration, in which undercooling ahead of dendrite tip is preferably narrower than asymmetrical (001)/[110] welding configuration, is one of the most important ingredient for auspicious control of dendrite tip undercooling, once other welding conditions are similar. The main reason, why welding conditions (both low heat input and (001)/[100] welding configuration) is quite superior to welding conditions (both high heat input and (001)/[110] welding configuration), is attributable to favorable crystallography-dependent thermometallurgical factors to suppress inhomogeneous microstructure as long as solidification conditions within marginal stability range. Satisfying crack-free microstructure development is strongly interdependent on kinetics-related solidification behavior through scrupulous control of dendrite tip undercooling to balance between microstructure amelioration and weld depth requirement. The mechanism of columnar/equiaxed transition elimination, by which kinetic driving forces of abnormal microstructure development within high-undercooling region on either left or right side of weld pool is diminished through challenging method of crystallography-dependent dendrite tip undercooling control, is therefore proposed. Finally, there is reasonable consensus between numerical analysis results and experiment results. The numerical analysis provides credible insight into where is liable to microstructure anomalies and why dendrite tip undercooling suppresses stray grain formation for successful laser surface modification of Ni-based single-crystal superalloy.

Numerical Analysis of Stray Grain Formation during Laser Welding Nickel-Based Single-Crystal Superalloy Part II: Multicomponent Dendrite Growth

Multicomponent dendrite growth is theoretically predicted to optimize solidification cracking susceptibility during ternary Ni-Cr-Al nickel-based single-crystal superalloy weld pool solidification. The distribution of dendrite trunk spacing along the weld pool solidification interface is clearly symmetrical about the weld pool centerline in beneficial (001)/[100] welding configuration. The distribution of dendrite trunk spacing along the weld pool solidification interface is crystallography-dependent asymmetrical from bottom to top surface of the weld pool in detrimental (001)/[110] welding configuration. The smaller heat input is used, the finer dendrite trunk spacing is kinetically promoted by less solute enrichment and narrower constitutional undercooling ahead of solid/liquid interface with mitigation of metallurgical contributing factors for solidification cracking and vice versa. Vulnerable [100] dendrite growth region is predominantly suppressed and epitaxial [001] dendrite growth region is favored to spontaneously facilitate single-crystal columnar dendrite growth and reduce microstructure anomalies with further reduction of heat input. Optimum low heat input (both lower laser power and higher welding speed) with (001)/[100] welding configuration is the most favorable one to avoid nucleation and growth of stray grain formation, minimize both dendrite trunk spacing and solidification cracking susceptibility potential, improve resistance to solidification cracking, and ameliorate weldability and weld integrity through microstructure modification instead of inappropriate high heat input (both higher laser power and slower welding speed) with (001)/[110] welding configuration. The dendrite trunk spacing in the [100] dendrite growth region on the right side of the weld pool is considerably coarser and grows faster than that within the [010] dendrite growth region of the left side in the (001)/[110] welding configuration to deteriorate weldability, although the welding conditions are the same on the either side. Furthermore, the alternative mechanism of crystallography-dependent solidification cracking as consequence of asymmetrical microstructure development and diffusion-controlled dendrite growth of γ phase is therefore proposed. The theoretical predictions are comparable with experiment results. The reliable model is also useful for welding conditions optimization for crack-free laser processing.

Effects of Continuous and Pulsed Ultrasonic Treatment on Microstructure and Microhardness in Different Vertical Depth of ZL205A Castings

In this paper, in order to improve the performance of the ZL205A castings, continuous ultrasonic and pulsed ultrasonic treatments were applied to the melted alloy to study the effect of ultrasound propagation distance on microstructure and microhardness. The results indicated that ZL205A grains were significantly refined by ultrasonic vibration, but the refinement effect became weak gradually with the increase of sampling depth. The minimum grain sizes were 103.2 μm and 122.5 μm respectively in continuous and pulsed ultrasonic treatment. Grain boundary segregation also became more serious and coarser with the increase of vertical depth. In addition, microhardness and vertical depth are not positively correlated linearly. As the vertical depth increased, microhardness first decreased and then increased, the maximum hardnesses were 73.9 HV and 72.84 HV, respectively, in the two process modes. According to the experiment results and available studies, the mechanism of ultrasonic treatment maybe that: the cooling rate of solidification interface front increased by cavitation and streaming, thus changing the solute redistribution behavior of the ZL205A melt.

Initial Transfer Behavior and Solidification Structure Evolution in a Large Continuously Cast Bloom with a Combination of Nozzle Injection Mode and M-EMS

A three-dimensional numerical model combining electromagnetic field, fluid flow, heat transfer, and solidification has been established to study the effect of nozzle injection mode and mold electromagnetic stirring (M-EMS) on the internal quality of a continuously cast bloom. The model is validated by measured data of the magnetic flux density along the stirrer center line. According to the simulation and experimental results, M-EMS can introduce a horizontal swirling flow ahead of the solidification front, promoting the superheat dissipation of molten steel and columnar to equiaxed transition (CET). As the stirring current increases from 0 to 800 A, the superheat at the mold exit in the bloom center decreases by 1.9 K for the single-port nozzle case and 3.8 K for the five-port nozzle case. The resulting increase in the equiaxed crystal ratio is about 5.65% and 4.06%, respectively. In comparison, the injection mode shows a more significant influence on the heat transfer and solidification structure in the bloom under the present casting conditions. The superheat at the mold exit in the bloom center decreases by 5.1‒7.7 K as the injection mode changes from a single-port nozzle to a five-port nozzle, and the increase in the equiaxed crystal ratio ranges between 14.8% and 17%. It is found that the flow velocity of the molten steel in front of the solidification interface for the five-port nozzle is higher than that for the single-port nozzle regardless of the M-EMS power. The washing effect here reinforces both the heat exchange through the solidification interface and the dendrite re-melting or fragmenting, stimulating the formation of an equiaxed crystal at the bloom center. In addition, it is observed that both the central shrinkage and carbon segregation have decreased with the five-port nozzle plus M-EMS. This suggests that the combined application of a five-port nozzle and M-EMS can effectively improve the internal quality of large bloom castings.

Traveling Waves Induced by Sweeping Flows on Solidification Interfaces

Solidification of alloys in a thermal gradient usually involves the generation of flows by thermal or thermosolutal convection. We experimentally study their effects on the dynamics of a solidification interface by inducing a controlled sweeping flow in a directional solidification device. Flow is induced in the sample from an external thermosiphon. Downstream inclination of microstructures and downstream sidebranch development are observed. However, the major outcome is the evidence of large scale travelling waves on the solidification interface. They are induced by the coupling between solidification and flow and yield repetitive striations of the solid phase. Two waves are observed and characterized.