Black Agates from Paleoproterozoic Pillow Lavas (Onega Basin, Karelian Craton, NE Russia): Mineralogy and Proposed Origin

The present study provides the first detailed investigation of black agates occurring in volcanic rocks of the Zaonega Formation within the Onega Basin (Karelian Craton, Fennoscandian Shield). Three characteristic texture types of black agates were identified: monocentric concentrically zoning agates, polycentric spherulitic agates, and moss agates. The silica matrix of black agates is only composed of length-fast and zebraic chalcedony, micro- and macro-crystalline quartz, and quartzine. In addition to silica minerals, calcite, chlorite, feldspar, sulphides, and carbonaceous matter were also recognised. The black colour of agates is related to the presence of disseminated carbonaceous matter (CM) with a bulk content of less than 1 wt.%. Raman spectroscopy revealed that CM from black agates might be attributed to poorly ordered CM. The metamorphic temperature for CM from moss and spherulitic agates was determined to be close to 330 °C, whereas CM from concentrically zoning agates is characterised by a lower temperature, 264 °C. The potential source of CM in moss and spherulitic agates is associated with the hydrothermal fluids enriched in CM incorporated from underlaying carbon-bearing shungite rocks. The concentrically zoning agates contained heterogeneous CM originated both from the inter-pillow matrix and/or hydrothermal fluids.

P–T CONDITIONS, U/Pb AND 40Ar/39Ar ISOTOPIC AGES OF UHT GRANULITES FROM CAPE KALTYGEI, WESTERN BAIKAL REGION

The study is focused on metapelitic granulites of Cape Kaltygei (Western Baikal region) that contain a diagnostic mineral assemblage of ultrahigh temperature (UHT) metamorphic rocks (orthopyroxene+sillimanite+quartz). The pseudosection-based thermobarometry yields peak metamorphic temperature and pressure values (T=950 °C, P=~9 kbar) and suggests near-isobaric cooling (IBC) conditions during the retrograde evolution of the granulites. The U/Pb zircon age estimates for metamorphism (~1.87 Ga) support the data published by other researchers. The SHRIMP-II U-Pb dating of zircon cores yields a minimum protolith age of 1.94–1.91 Ga. Biotites and amphiboles from granulites of Cape Kaltygei show the 40Ar/39Ar isotopic ages that are close to the Early Paleozoic accretion-collision system of the Western Baikal region.

XRD graphitization degrees: a review of the published data and new calculations, correlations, and applications

A system for transformation, correlation, and unification of subordinations between d002 (Å) of semi-graphite and graphite, graphitization degrees and metamorphic temperature was created. The existing equations in the literature were analyzed and new equations, which determine correlation relationships between these parameters, were formulated. The effect of factors that control graphitization processes (temperature, general pressure and tectonic stress, structure and origin of primary carbon matter, orientation of carbon formations, fluids, mineral and chemical composition, and duration of processes) was also considered. It was concluded that the structural state of semi-graphite and graphite is reversible, and this can be used for facies diagnostics and studying of metamorphic history of graphite-bearing metamorphic rocks. A new scale for graphitization degrees was proposed.

Metamorphic Temperatures and Pressures across the Eastern Franciscan: Implications for Underplating and Exhumation

The Eastern Belt of the Franciscan Complex in the northern California Coast Ranges consists of coherent thrust sheets predominately made up of ocean floor sediments subducted in the Early Cretaceous and then accreted to the overriding plate at depths of 25-40 km. Progressive packet accretion resulted in the juxtaposition of a series of thrust sheets of differing metamorphic grades. This study utilizes laser Raman analysis of carbonaceous material to determine peak metamorphic temperatures across the Eastern Belt and phengite barometry to determine peak metamorphic pressures. Locating faults that separate packets in the field is difficult, but they can be accurately located based on differences in peak metamorphic temperature revealed by Raman analysis. The Taliaferro Metamorphic Complex in the west reached 323-336°C at a minimum pressure of ~11 kbar; the surrounding Yolla Bolly Unit 215–290°C; the Valentine Springs Unit 282-288°C at 7.8±0.7 kbar; the South Fork Mountain Schist 314–349°C at 8.6–9.5 kbar, a thin slice in the eastern portion of the SFMS, identified here for the first time, was metamorphosed at ~365°C and 9.7±0.7 kbar; and a slice attributed to the Galice Formation of the Western Klamath Mountains at 281±13°C. Temperatures in the Yolla Bolly Unit and Galice slice were too low for the application of phengite barometry. Microfossil fragments in the South Fork Mountain Schist are smaller and less abundant than in the underlying Valentine Springs Unit, providing an additional method of identifying the boundary between the two units. Faults that record a temperature difference across them were active after peak metamorphism while faults that do not were active prior to peak metamorphism, allowing for the location of packet bounding faults at the time of accretion. The South Fork Mountain Schist consists of two accreted packets with thicknesses of 300 m and 3.5 km. The existence of imbricate thrust faults both with and without differences in peak metamorphic temperature across them provides evidence for synconvergent exhumation.

U–Pb zircon geochronology and phase equilibria modelling of HP-LT rocks in the Ossa-Morena Zone, Portugal

The Ossa-Morena Zone (OMZ) has a complex geological history including both Cadomian and Variscan orogenic events. Therefore, the OMZ plays an important role in understanding the geodynamic evolution of Iberia. However, the P–T–t evolution of the OMZ is poorly documented. Here, we combine structural and metamorphic analyses with new geochronological data and geochemical analyses of mafic bodies in Ediacaran metasediments (in Iberia known as Série Negra) to constrain the geodynamic evolution of the OMZ. In the studied mafic rocks, two metamorphic stages were obtained by phase equilibria modelling: (1) a high-pressure/low-temperature event of 1.0 ± 0.1 GPa and 470–510 °C, and (2) a medium-pressure/higher-temperature event of 0.6 ± 0.2 GPa and 550–600 °C. The increase in metamorphic temperature is attributed to the intrusion of the Beja Igneous Complex (around 350 Ma) and/or the Évora Massif (around 318 Ma). New U–Pb dating on zircons from the mafic rocks with tholeiitic affinity yields an age between 815 and 790 Ma. If the zircons crystallised from the tholeiitic magma, their age would set a minimum age for the pre-Cadomian basement. The ca. 800 Ma protolith age of HP-LT tholeiitic dykes with a different metamorphic history than the host Série Negra lead us to conclude that: (1) the HP-LT mafic rocks and HP-LT marbles with dykes were included in the Ediacaran metasediments as olistoliths; (2) the blueschist metamorphism is older than 550 Ma (between ca. 790 Ma and ca. 550 Ma, e.g., Cadomian).

Contact metamorphism of the Tethyan Sedimentary Sequence, Upper Mustang region, west-central Nepal

The Upper Mustang region of west-central Nepal contains exposures of metamorphosed Tethyan Sedimentary Sequence rocks that have been interpreted to reflect either contact metamorphism related to the nearby Mugu pluton or regional metamorphism associated with the North Himalayan domes. New monazite geochronology results show that the Mugu leucogranite crystallized at c. 21.3 Ma, while the dominant monazite age peaks from the surrounding garnet ± staurolite ± sillimanite schists range between c. 21.7 and 19.4 Ma, generally decreasing in age away from the pluton. Metamorphic temperature estimates based on Ti-in-biotite and garnet–biotite thermometry are highest in the specimens closest to the pluton (648 ± 24°C and 615 ± 25°C, respectively) and lowest in those furthest away (578 ± 24°C and 563 ± 25°C, respectively), while pressure estimates are all within uncertainty of one another, averaging 5.0 ± 0.5 kbar. These results are interpreted to be consistent with contact metamorphism of the rocks in proximity to the Mugu pluton, which was emplaced at c. 18 ± 2 km depth after local movement across the South Tibetan detachment system had ceased. While this new dataset helps to characterize the metamorphic rocks of the Tethyan Sedimentary Sequence and provides new constraints on the thickness of the upper crust, it also emphasizes the importance of careful integration of metamorphic conditions and inferred processes that may affect interpretation of currently proposed Himalayan models.

Linking Alpine deformation in the Aar Massif basement and its cover units – the case of the Jungfrau–Eiger mountains (Central Alps, Switzerland)

The northwest (NW) rim of the external Aar Massif was exhumed from ∼ 10 km depth to its present position at 4 km elevation above sea level during several Alpine deformation stages. Different models have been proposed for the timing and nature of these stages. Recently proposed exhumation models for the central, internal Aar Massif differ from the ones established in the covering Helvetic sedimentary units. By updating pre-existing maps and collecting structural data, a structural map and tectonic section were reconstructed. Those were interpreted together with microstructural data and peak metamorphic temperature estimates from collected samples to establish a framework suitable for both basement and cover. Deformation temperatures range between 250 and 330 °C, allowing for semi-brittle deformation in the basement rocks, while the calcite-dominated sedimentary rocks deform in a ductile manner at these conditions. Although field data allow to distinguish multiple deformation stages before and during Aar Massif's exhumation, all related structures formed under similar P, T conditions at the investigated NW rim. In particular, we find that the exhumation occurred during two stages of shearing in Aar Massif's basement, which induced in the sedimentary rocks first a phase of folding and then a period of thrusting, accompanied by the formation of a new foliation.

Linking Alpine deformation in the Aar Massif basement and its cover units – the case of the Jungfrau-Eiger Mountains (Central Alps, Switzerland)

The NW rim of the external Aar Massif was exhumed from ~ 10 km depth to its present position at 4 km elevation above sea level during several Alpine deformation stages. Different models have been proposed for the timing and nature of these stages. Recently proposed exhumation models for the central, internal Aar Massif differ from the ones established in the covering Helvetic sedimentary units. By updating pre-existing maps and collecting structural data, a structural map and tectonic section was reconstructed. Those were interpreted together with micro-structural data and peak metamorphic temperature estimates from collected samples to establish a framework suitable for both basement and cover. Temperatures at deformation ranged from 250 °C to 330 °C allowing for semi-brittle deformation in the basement rocks, while the calcite dominated sediments deform ductile at these conditions. Although field data allows to distinguish multiple deformation stages before and during the Aar Massifs rise, all related structures formed under similar P, T conditions at the investigated NW rim. We find that the exhumation occurred during 2 stages of shearing in the Aar Massif basement, which induced in the sediments first a phase of folding and then a period of thrusting, accompanied by the formation of a new foliation. We can link this uplift and exhumation history to recently published large-scale block extrusion models.