Identification and Prioritisation of Mine Pollution Sources in a Temperate Watershed Using Tracer Injection and Synoptic Sampling

Identifying and prioritising mine sites for remediation is challenging due to inherently complex hydrological systems and multiple potential sources of mine pollution dispersed across watersheds. Understanding mine pollution dynamics in wet temperate watersheds is particularly challenging due to substantial variability in precipitation and streamflows, which increase the importance of diffuse sources. A tracer dilution and synoptic sampling experiment was conducted in a mined watershed in Scotland to identify the main sources of mine pollution, the relative importance of point and diffuse sources of pollution, and the potential benefits of mine site remediation to stream water quality. Using high spatial resolution metal loading datasets, the major Zn and Cd source areas were identified as point sources of mine water predominantly located in the upper part of the watershed. In contrast, the main sources of Pb were diffuse sources of mine tailings and wastes located in the lower part of the watershed. In the latter case, mobilisation of Pb occurred primarily from a section of braided wetland and an uncapped tailings area. Importantly, diffuse sources of mine pollution were found to be the dominant source of Pb, and an important source of Zn and Cd, even under steady-state streamflow conditions. Mass balance calculations suggest that treatment of the main mine water sources in the upper watershed and capping of the tailings deposit in the lower watershed could reduce stream trace metal concentrations by approximately 70%. These data support the development of conceptual models of mine pollution dynamics in wet temperate watersheds. These conceptual models are important as they: (1) help prioritise those mine sites and features for remediation that will deliver the most environmental and socio-economic benefit, and; (2) provide a means to quantify the importance of diffuse pollution sources that may increase in importance in the future as a result of changes in precipitation patterns in temperate watersheds.

The SPLASH Action Group – Towards standardized sampling strategies along the soil-to-hydrosystems continuum in permafrost landscapes

<p><span>The Action Group called ‘Standardized methods across Permafrost Landscapes: from Arctic Soils to Hydrosystems’ (SPLASH), funded by the International Permafrost Association, is a community-driven effort aiming to provide a suite of standardized field strategies for sampling mineral and organic components in soils, sediments, surface water bodies and coastal environments across permafrost landscapes. This unified approach will allow data to be shared and compared, thus improving our understanding of the processes occurring during lateral transport in circumpolar Arctic watersheds. This is an international and transdisciplinary effort aiming to provide a fieldwork “tool box” of the most relevant sampling schemes and sample conservation procedures for mineral and organic permafrost pools.</span></p><p><span>With climate change, permafrost soils are undergoing drastic transformations. B</span><span>oth localized abrupt thaw (thermokarst) and gradual ecosystem shifts (e.g., active layer thickening, vegetation changes) drive changes in hydrology and biogeochemical cycles (carbon, nutrients, and contaminants). Mineral and organic components interact along the “lateral continuum” (i.e., from soils to aquatic systems) changing their composition and reactivity across the different interfaces. The circumpolar Arctic region is characterized by high spatial heterogeneity (e.g., geology, topography, vegetation, and ground-ice content) and large inter-annual and seasonal variations in local climate and biophysical processes. Common sampling strategies, applied in different seasons and locations, could help to tackle the spatial and temporal complexity inextricably linked to biogeochemical processes. </span><span>This unified approach developed in permafrost landscapes will allow us to overcome the following challenges: (1) identifying interfaces where detectable changes in mineral and organic components occur; (2) allowing spatial comparison of these detectable changes; and (3) capturing temporal (inter-/intra-annual) variations at these interfaces. </span><span>In order to build on the great effort to better assess the permafrost feedback to climate change, there is an urgent need for a set of community-based protocols to capture changes the dynamics of organics and minerals during their lateral transport. </span></p><p><span>Here, we present the first results from an online survey recently conducted among researchers from different disciplines. The survey inputs provide valuable information about the common approaches currently applied along the “soil-to-hydrosystems” continuum and the specific challenges associated with permafrost studies. These results about the ‘WHAT, WHERE, WHEN, and HOW’ of field sampling (e.g., sample collection, filtration, conservation...) allow for identifying the most relevant sampling strategies and also the current knowledge gaps. Finally, we present examples of the protocols available to investigate organic and mineral components from soils to marine environments,</span> on which a synoptic sampling strategy can be built. <span>A</span><span>ll forthcoming contributions from our community are still welcome, helping the SPLASH team </span><span>to</span> <span>fill</span><span> up the most adapted tool box to Arctic permafrost landscapes</span><span>.</span></p>

Tracing Heavy Metals at Nantymwyn, Wales

<p>Wales has a long history of coal and metal mining, with over 1,300 abandoned metal mines across the country. These mines pollute a number of rivers and lead to the failure of Water Framework Directive (WFD) standards for heavy metals. This includes Nantymwyn, an abandoned lead mine, which has two streams that flow into the River Tywi, and metal loads can be traced downstream for 65km. Nantymwyn, in common with many of Wales’ lead mines, has complex and poorly understood underground workings, which have degraded in the 90 years since closure. The mine is believed to have been worked during pre-Roman times and, is noted historically from AD 1530. The Nant y Bai stream flows through extensive spoil heaps, as well as over old workings, and has inflows from adits, over ground and subterranean inputs. Consequentially, conventional spot sampling of the metal concentrations as has been historically carried out by government agencies does not accurately convey the problems caused by the mine.</p><p>Tracer dilution and synoptic sampling was determined at Nantymwyn in July 2019 to calculate stream flow and heavy metal loadings and their variation downstream. Sodium bromide was injected upstream of the mine site, and once it reached a ‘plateau state’ in the stream it was sampled at 34 points over the 2km of stream. These samples were analysed for metal and bromide concentrations using Inductively coupled plasma mass spectrometry (ICP-MS), which allowed One-Dimensional Transport with Inflow and Storage (OTIS) modelling to predict pollutant flows. Additionally, monthly sampling and salt dilution flow gauging at 12 sites along the stream has been conducted since February 2019. The second, smaller stream at Nantymwyn is monitored monthly at six points.</p><p>Preliminary results show a large temporal variation in flows and concentrations across both streams, with varying loads of lead, but a consistent zinc load in the smaller stream. Initial results from the synoptic sampling show flows consistent with the salt gauging carried out after the stream had been sampled. This research will determine the extent of unseen inflow and outflows upon metal pollution on the River Tywi and allow mitigation strategies to be evaluated.</p>

Investigating the Effective Bioclimatic Factors on Tourism Industry (Case of Study: Zanjan, Iran)

<p>The tourism industry is one of the largest and fastest growing economic factors in the contemporary worlds. Many factors affect the tourism industry; one of the most important of them is climate. Unfortunately, tourism literature has not paid much attention to the effect of climatic factors on the industry as it worth. Therefore, in order to develop this area of global economic, it is necessary to recognize the capabilities and limitations of the climate area. In this research, in order to evaluate environmental conditions in there, indicators of effective temperature (ET), temperature-humidity (THI), Baker Index (CP), and physiological stress indicators, (P_phs) by using monthly statistic parameters of temperature, relative humidity wind and synoptic sampling stations during the period 2005 – 1955 are used. Results show that based on the parameters of ET, the maximum temperature in April, the minimum temperature in July and August and the average temperature can be seen in May. About THI index comfort conditions can be seen just in March and November and CP index indicates total bioclimatic comfort in summer. Index) also found that only the months of June, September and has been neutral in terms of biological stress. </p>

Using geochemical and isotopic chemistry to evaluate glacier melt contributions to the Chamkar Chhu (river), Bhutan

Water stored as ice and snow at high elevations is a resource that plays an important role in the hydrologic cycle, particularly in the timing and volume of downstream discharge. Here we use geochemical and isotopic values of water samples to evaluate relative contributions of melting glacier ice and groundwater to discharge in Bhutan. River water samples were collected between 3100 and 4500 m in the Chamkar Chhu (river) watershed of central Bhutan's Himalaya. Glacier ice and snow were sampled in the ablation zone of Thanagang glacier. Groundwater was parameterized from spring water at elevations of 3100 and 3600 m. Synoptic sampling was carried out in separate expeditions in July, August and late September 2014, to characterize monsoon and post-monsoon conditions. Results from a two-component hydrologic mixing model using isotopic and geochemical (sulphate) values show that the glacier outflow contributions decrease from ∼76% at 4500 m to 31% at 3100 m. A four-component hydrologic mixing model using end-member mixing analysis shows glacier ice melt increasing as a proportion of discharge over the 3 month sampling period, and consistently decreasing with distance downstream of Thanagang glacier terminus. These results indicate that isotopic and geochemical tracers can provide a quantitative evaluation of the source water contributions to streamflow in Bhutan.