In this study, the safe distance in the case of a hydrogen vehicle fire was analyzed according to the temperature distribution around a hydrogen gas jet flame formed by the thermally activated pressure relief device operation of a hydrogen storage container. The experiment was conducted while 70 MPa hydrogen gas was released from a 1.8-mm-diameter nozzle to a 1.8- × 1.8 m fire-resistant structure wall for distances of 2 and 4 m between the nozzle output and the wall. To analyze the temperature around the hydrogen gas jet flame, five fire-fighting heat-protective hood test samples, certified by the Korea Fire Institute, and temperature sensors were installed every 1 m from the center of the jet flame in the vertical direction to the direction of the flame. In the experiment, the temperature around the jet flame was measured to observe the safe distance for firefighters. The results show that the safe distances at 70°C or less, which is harmless to firefighters, were 5 m without a heat-protective hood and 3 m with a heat-protective hood. In addition, it was confirmed that the direction of the jet flame and blocking by obstacles affect the safe distance during fire-fighting and rescue activities by firefighters.