Coincident Correlation between Vibrational Dynamics and Primary Relaxation of Polymers with Strong or Weak Johari-Goldstein Relaxation

The correlation between the vibrational dynamics, as sensed by the Debye-Waller factor, and the primary relaxation in the presence of secondary Johari-Goldstein (JG) relaxation, has been investigated through molecular dynamics simulations. Two melts of polymer chains with different bond length, resulting in rather different strength of the JG relaxation are studied. We focus on the bond-orientation correlation function, exhibiting higher JG sensitivity with respect to alternatives provided by torsional autocorrelation function and intermediate scattering function. We find that, even if changing the bond length alters both the strength and the relaxation time of the JG relaxation, it leaves unaffected the correlation between the vibrational dynamics and the primary relaxation. The finding is in harmony with previous studies reporting that numerical models not showing secondary relaxations exhibit striking agreement with experimental data of polymers also where the presence of JG relaxation is known.

Main and secondary relaxations of non-polymeric high-Tg glass formers as revealed by dielectric spectroscopy

Manifestation of β-relaxation depends on the position of the polar nitrile group, its distribution of activation energy varies along 19 < E/Tg < 35.

Distinguishing different classes of secondary relaxations from vapour deposited ultrastable glasses

Two groups of secondary relaxations: those becoming slower in the ultrastable state, in strong concordance with the structural relaxation, and those becoming faster.

ELECTRICAL AND DIELECTRIC PROPERTIES OF RUBBER

ABSTRACT This review describes electrical and dielectric measurements of rubbery polymers. The interest in the electrical properties is primarily due to the strong effect of conductive fillers, the obvious example being carbon black. Conductivity measurements can be used to probe dispersion and the connectivity of filler particles, both of which exert a significant influence on the mechanical behavior. Dielectric relaxation spectra are used to study the dynamics, including the local segmental dynamics and secondary relaxations, and for certain polymers the global chain modes. A recent development in the application of nonlinear dielectric spectroscopy is briefly discussed.